Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.     

Marymia: an Archean, amphibolite facies-hosted, orogenic lode-gold deposit overprinted by Palaeoproterozoic orogenesis and base metal mineralisation, Western Australia

The Marymia gold deposit, comprising two orebodies, Keillor 1 and Keillor 2, is at the northern end of the Plutonic Well greenstone belt in the Marymia Inlier, in the southern Capricorn Orogen, just north of the Yilgarn craton. The Marymia Inlier is a discrete fault-bounded Archean gneiss-granitoid-greenstone domain surrounded by sedimentary basins that were formed and variably metamorphosed and deformed during several Palaeoproterozoic orogenic cycles. The greenstone sequence at Marymia is stratigraphically and geochemically similar to greenstone sequences in the Yilgarn craton, but was subjected to further deformation and metamorphism in the Palaeoproterozoic. Late Archean deformation (D1-D2) was ductile to brittle-ductile in style, whereas Palaeoproterozoic deformation was predominantly brittle. Equilibrium mineral assemblages indicate that peak amphibolite-facies metamorphism (540-575 °C, <3 kb) was overprinted by greenschist-facies metamorphism (300-360 °C). Petrographic textures indicate that prograde metamorphism was coeval with D1-D2, with peak metamorphism early to syn D2. Gold mineralisation at Marymia is hosted in metamorphosed tholeiitic basalts and banded iron formation. On a gross scale, the distribution of gold is controlled by D2 folds and shear zones. Lithological contacts with strong rheological or chemical contrasts provide local controls. Gold-related alteration comprises subtle millimetre- to centimetre-wide zones of silicification with variable amounts of quartz, hornblende, biotite, K-feldspar, plagioclase, calcite/siderite, scheelite, titanite, epidote, sulfide and telluride minerals. Quartz veins are generally narrow and discontinuous with low total volume of quartz. Gold is sited in the wall rock, at vein salvedges or within stringers of wall rock within veins. There are two distinct opaque-mineral assemblages: pyrite-pyrrhotite-chalcopyrite-galena and hessite-petzite-altaite-Bi-telluride-galena. Ore samples are variably enriched in Ag, Te, Pb, W, Cu, S and Fe reflecting heterogeneity of the ore mineralogy. Structural timing and temperature of formation of alteration and ore minerals support deposition of gold during late peak amphibolite-facies metamorphism from neutral to alkaline (pH=5-6), moderately oxidising (log P_O2,-21-22) and CO₂-bearing (X_CO2 Ƹ.2) fluids. The total sulfur content of the fluid is estimated at 1mDS. Lead isotope compositions support derivation of lead from within the local greenstone sequence. Gold lodes were deformed by faults and shear zones in the Palaeoproterozoic, with only limited remobilisation. Subeconomic, carbonate vein- and breccia-hosted base metal mineralisation is locally hosted within Palaeoproterozoic fault zones, which clearly cut gold lodes. Base-metal-related alteration is characterised by intense carbonatisation, chloritisation, and albitisation of the mafic host rocks. Mineral assemblages are consistent with formation at greenschist facies conditions. Lead isotope compositions support crystallisation at ca. 1.7 Ga from lead that is similar in composition to earlier gold-related galena.     

A summary of sulfur dioxide emission rate measuremnts from Guatemalan volcanoes

Measurements of the sulfur dioxide (SO₂) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO₂ emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO₂ emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO₂ emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO₂ emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO₂ emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO₂. Santiaguito and Pacaya, together, emit 6% of the total annual SO₂ emitted by continuously erupting volcanoes.Even though SO₂ measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO₂ emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society.     

Solar Microwave Bursts from Electron Populations with a 'Broken’ Energy Spectrum

Usually the gyrosynchrotron emission of microwave bursts from electron populations with a power-law (PL) energy distribution has been considered under the assumption that the spectral index of the distribution is constant over a wide range of energies. Meanwhile, there is strong evidence, in particular from hard X-ray and -ray, but also from cm/mm wavelength radio observations, that in many solar flare events the spectrum of the emitting electrons is characterized by a significant hardening at energies above 100–500 keV. We present some examples of calculated microwave burst spectra at cm/mm wavelengths taking into account the above evidence. It is shown that a break in the energy spectrum of the PL electrons can indeed result in a spectral hardening sometimes observed in microwave bursts at frequencies above 10–30 GHz.     

Non-point source pollution in Indian agriculture: Estimation of nitrogen losses from rice crop using remote sensing and GIS

The paper presents a detailed understanding of nitrogenous fertilizer use in Indian agriculture and estimation of seasonal nitrogen loosses from rice crop in Indo-Gangetic plain region, the ‘food bowl’ of the Indian sub-continent. An integrated methodology was developed for quantification of different forms of nitrogen losses from rice crop using remote sensing derived inputs, field data of fertilizer application, collateral data of soil and rainfall and nitrogen loss coefficients derived from published nitrogen dynamics studies. The spatial patterns of nitrogen losses in autumn or ‘kharif’ and spring or ‘rabi’ season rice at 1 × 1 km grid were generated using image processing and GIS. The nitrogen losses through leaching in form of urea-N, ammonium-N (NH₄-N) and nitrate-N (NO₃-N) are dominant over ammonia volatilization loss. The study results indicate that nitrogen loss through leaching in kharif and rabi rice is of the order of 34.9% and 39.8% of the applied nitrogenous fertilizer in the Indo-Gangetic plain region. This study provides a significant insight to the role of nitrogenous fertilizer as a major non-point source pollutant from agriculture.     

Karst groundwater protection in the Kupa River catchment area and sustainable development

One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km²) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about 6 m³/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway and that many settlements and a highly developed wood industry are present. The combination of protecting water resources with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment before the water passes into the karst underground system.     

Electron paramagnetic resonance,optical absorption,and magnetic circular dichroism studies of the CO 3 − molecular-ion in irradiated natural beryl

Room temperature X-irradiation of some natural beryls produced several new absorption lines in the electron paramagnetic resonance (EPR) spectrum, a known series of optical absorption lines in the 500–700 nm range, and a shift of the absorption edge to lower energies. Several of the new EPR lines and part of the irradiation-induced shift of the absorption edge disappeared after a few days at room temperature, and were not examined in detail. However, three of the paramagnetic centres responsible for the new EPR lines were stable at room temperature and two of these have previously been identified as atomic hydrogen and the methyl radical, CH₃. These species were stable to ～150 and ～450°C respectively. The third stable species, hitherto unreported, showed a single-line EPR spectrum of axial symmetry, with g∥=2.0051 and g⊥=2.0152. This spectrum was found to be intensity-correlated with the series of optical bands in the 500–700 nm range, after thermal bleaching at 175°C. The EPR and optical spectra are therefore assigned to the same species. It is argued that this species is the CO ₃ ^? molecular ion, located in the widest part of the structural channel and aligned with the plane of the molecule perpendicular to the c axis. The EPR spectrum is consistent with a ² A′₂ ground state of a CO ₃ ^? molecule with trigonal symmetry, and this requires that the optical transition has a ² A′₂ → ² E′ character. Most of the features in the optical spectrum can be assigned to coupling of a totally symmetric mode of frequency ～1020 cm^?1 onto a zero-phonon line at 14,490 cm^?1 and a second weaker line at 16,020 cm^?1. However, both of these two fundamental lines are structured, and the two components show strong temperature-dependent derivative-shaped magnetic circular dichroism (MCD). Furthermore, the overall sign of the MCD for the line at 16,020 cm^?1 is opposite to that at 14,490 cm^?1. The separation (～120 cm^?1) of the two components of the 14,490 cm^?1 line is much larger than that expected from spin-orbit interaction, and the origin of this splitting is not yet understood.