Cluster–subcluster mergers and the formation of narrow-angle tailed radio sources

We examine the ROSAT PSPC X-ray properties of a sample of 15 Abell clusters containing 23 narrow-angle tailed (NAT) radio galaxies. We find that clusters with NATs show a significantly higher level of substructure than a similar sample of radio-quiet clusters, indicating that NAT radio sources are preferentially located in dynamically complex systems. Also, the velocity distribution of the NAT galaxies is similar to that of other cluster members; these velocities are inadequate for producing the ram pressure necessary to bend the radio jets. We therefore propose a new model for NAT formation, in which NATs are associated with dynamically complex clusters undergoing merger events. The U -shaped NAT morphology is produced in part by the merger-induced bulk motion of the ICM bending the jets.     

Integer least-squares theory for the GNSS compass

Global navigation satellite system (GNSS) carrier phase integer ambiguity resolution is the key to high-precision positioning and attitude determination. In this contribution, we develop new integer least-squares (ILS) theory for the GNSS compass model, together with efficient integer search strategies. It extends current unconstrained ILS theory to the nonlinearly constrained case, an extension that is particularly suited for precise attitude determination. As opposed to current practice, our method does proper justice to the a priori given information. The nonlinear baseline constraint is fully integrated into the ambiguity objective function, thereby receiving a proper weighting in its minimization and providing guidance for the integer search. Different search strategies are developed to compute exact and approximate solutions of the nonlinear constrained ILS problem. Their applicability depends on the strength of the GNSS model and on the length of the baseline. Two of the presented search strategies, a global and a local one, are based on the use of an ellipsoidal search space. This has the advantage that standard methods can be applied. The global ellipsoidal search strategy is applicable to GNSS models of sufficient strength, while the local ellipsoidal search strategy is applicable to models for which the baseline lengths are not too small. We also develop search strategies for the most challenging case, namely when the curvature of the non-ellipsoidal ambiguity search space needs to be taken into account. Two such strategies are presented, an approximate one and a rigorous, somewhat more complex, one. The approximate one is applicable when the fixed baseline variance matrix is close to diagonal. Both methods make use of a search and shrink strategy. The rigorous solution is efficiently obtained by means of a search and shrink strategy that uses non-quadratic, but easy-to-evaluate, bounding functions of the ambiguity objective function. The theory presented is generally valid and it is not restricted to any particular GNSS or combination of GNSSs. Its general applicability also applies to the measurement scenarios (e.g. single-epoch vs. multi-epoch, or single-frequency vs. multi-frequency). In particular it is applicable to the most challenging case of unaided, single frequency, single epoch GNSS attitude determination. The success rate performance of the different methods is also illustrated.     

Covariations in oceanic dimethyl sulfide,its oxidation products and rain acidity at Amsterdam Island in the Southern Indian Ocean

Simultaneous measurements of rain acidity and dimethyl sulfide (DMS) at the ocean surface and in the atmosphere were performed at Amsterdam Island over a 4 year period. During the last 2 years, measurements of sulfur dioxide (SO₂) in the atmosphere and of methane sulfonic acid (MSA) and non-sea-salt-sulfate (nss-SO₄ ^2-) in rainwater were also performed. Covariations are observed between the oceanic and atmospheric DMS concentrations, atmospheric SO₂ concentrations, wet deposition of MSA, nss-SO₄ ^2-, and rain acidity. A comparable summer to winter ratio of DMS and SO₂ in the atmosphere and MSA in precipitation were also observed. From the chemical composition of precipitation we estimate that DMS oxidation products contribute approximately 40% of the rain acidity. If we consider the acidity in excess, then DMS oxidation products contribute about 55%.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Roughness length in the turbulent Ekman layer above the sea bed

Roughness lengths were determined from average current profiles in the logarithmic boundary layer at a site in the southern North Sea. Grab samples indicated that the bed configuration controlling the bed roughness was unlikely to change even at maximum spring tides, but the measured roughness lengths were found to decrease as the speed of the flow 10 m above the bed increased. This has been qualitatively interpreted in terms of the size of the turbulent eddies within the flow and their effectiveness at “feeling” the size of the elements forming the bed roughness. It is also shown that the dependence of the observed drag coefficient on the Rossby number follows closely the theoretical form when the roughness length decreases with increasing flow speed.     

Impact of reach geometry on stream channel sensitivity to extreme floods

Predicting spatial and temporal variations in bank erosion due to extreme floods presents a long‐standing challenge in geomorphology. We develop two methodologies for rapid, regional‐scale assessments of stream reaches susceptible to channel widening. The first proposes that channel widening occurs when unit stream power exceeds a critical threshold (300 W/m²). The second is motivated by the observation that widening often occurs at channel bends. We introduce a new metric, the bend stress parameter, which is proportional to the centripetal force exerted on a concave bank. We propose that high centripetal forces generate locally high bank shear forces and enhance channel bank erosion. We test both metrics using the geomorphic signature of Tropical Storm Irene (2011) on the White and the Saxtons Rivers, Vermont. Specifically, we test if reaches where significant channel widening occurred during Irene required one or both metrics to exceed threshold values. We observe two distinct styles of channel widening. Where unit stream power and bend stress parameter are high, widening is usually due to bank retreat. Elsewhere widening is usually due to the stripping of the upstream end of mid‐channel islands. Excluding widening associated with the stripping of the heads of mid‐channel islands, almost all the widening (> 98%) occurred along reaches identified as susceptible to widening. The combined metrics identify up to one‐quarter of the reaches lacking susceptibility to channel widening. Copyright © 2014 John Wiley & Sons, Ltd.     

Analyzing seismic imagery in the time–amplitude and time–frequency domains to determine fluid nature and migration pathways: A case study from the Queen Charlotte Basin,offshore British Columbia

Combining time–amplitude and time–frequency information from seismic reflection data sets of different resolutions allows the analysis of anomalous reflections from very-shallow to great subsurface depths. Thus, it can enhance the imaging of subsurface features which have a frequency-dependent reflectivity such as gas. Analysing seismic data of different resolution in the time–amplitude and time–frequency domains is a powerful method to determine hydrocarbon migration pathways from deep reservoirs to the seafloor. This interpretation method has been applied to the formerly-glaciated offshore Queen Charlotte Basin hosting several seafloor pockmarks and mounds associated with the leakage of underlying hydrocarbon reservoirs. Low-frequency shadows observed in the time–frequency domain provide evidence of different resolutions that several anomalous reflection amplitudes may be attributed to the occurrence of gas. The seismic imagery shows that gas uses a fault to migrate from deep reservoirs included in Upper Mesozoic strata towards secondary reservoirs located along the fault plane into Neogene layers. Once gas reaches a porous cut-and-fill succession, migration changes from structurally- to stratigraphically-controlled before gas leaks through unconsolidated Quaternary sediments forming the shallow subsurface to eventually seep at the seafloor where pockmarks and carbonate mounds are formed.     

The stratospheric sulfate aerosol layer: Processes,models, observations,and simulations

After briefly reviewing the observational data on the stratospheric sulfate aerosol layer, the chemical and physical processes that are likely to fix the properties of the layer are discussed. We present appropriate continuity equations for aerosol particles, and show how to solve the equations on a digital computer. Simulations of the unperturbed aerosol layer by various published models are discussed and the sensitivity of layer characteristics to variations in several aerosol model parameters is studied. We discuss model applications to anthropogenic pollution problems and demonstrate that moderate levels of aerospace activity (supersonic transport and space shuttle operations) will probably have only a negligible effect on global climate. Finally, we evaluate the possible climatic effect of a ten-fold increase in the atmospheric abundance of carbonyl sulfide.     

Silicic differentiates of abyssal oceanic magmas: Evidence for late-magmatic vapor transport of potassium

Massive, nearly holocrystalline dolerites from DSDP Hole 417D contain from 0.5 to 1.5% of granophyric patches composed mainly of Na-plagioclase and quartz. These patches are compositionally similar to other crystalline silicic rocks from oceanic spreading centers and differ from rarer abyssal silicic glasses. Crystalline varieties withSiO₂60wt.% generally haveNa/K>10, whereas silicic glasses have Na/K in the range 3–6. While crystal fractionation readily accounts for the Na₂O and K₂O contents of abyssal silicic glasses, both the 417D granophyres and other crystalline abyssal silicic rocks have much lower K₂O than that predicted by any reasonable crystal-liquid fractionation model. We propose that high-temperature vapor phase transport is responsible for removal of potassium during late-stage crystallization of these rocks. This allows for the formation of cogenetic silicic glassy and crystalline rocks with greatly different Na/K ratios. These observations and interpretations lead to a more confident assignment of high Na/K silicic rocks of oceanic and ophiolitic environments to a cogenetic origin with basaltic oceanic crust.