Model of Formation and Development of Spring Thermal Bar

A mathematical model simulating the thermo- and hydrodynamic processes near the thermal bar in the period of lake warming in spring is considered. A closed system of Reynolds type equations is constructed based on the Navier–Stokes nonlinear system of equations using the Boussinesq approximation and a special technique for isolating large-scale structures in turbulent medium. The turbulent viscosity coefficient is evaluated in the course of problem solution. The results of calculations are shown to agree well with field observation data.     

Brine evolution in two inland evaporative environments: influence of microbial mats in mineral precipitation

This paper gives new insight into the precipitation sequences in six playa basins that host microbial mats. The study basins are distributed across two evaporitic endorheic drainage systems located in the Central part of Spain with markedly different hydrochemistry and mineralogy. One group, in the north, consists of highly alkaline, brackish to saline lakes containing a high concentration of chloride with dominant carbonate over sulphates. A second group of lakes are mesosaline to hypersaline, with sulphate the dominant anion over chloride. Mineral assemblages identified in both contain several phases that provide evidence for mixed carbonate-sulphate precipitation pathways, in the north, and sulphate-dominated pathways in the south. Regardless of their ionic composition, saline lakes support thin veneers of microbial mats which, by integrating several lines of evidence (hydrochemical and physical analyses, statistical analyses of ions, mineralogical assemblages, textural relationships among mineral phases and microbial mats) are shown to modify the chemical behavior of the evaporitic sediment and promote the formation of carbonates and sulphates from Ca-poor waters with high Mg/Ca ratios. Geochemical changes induced in the environment surrounding the microorganism favor the nucleation of hydrated Mg-carbonates (hydromagnesite and nesquehonite), calcite and dolomite. Simultaneously, the microbial mats provide nucleation sites for gypsum crystals, where they are subjected to episodic stages of growth and dissolution due to saturation indices close to zero. In addition, the bubbles produced by the metabolic activities of microorganisms are shown to promote the precipitation of hydrated Mg-sulphates, despite permanent subsaturation levels. Although common in the studied playa basins, this effect has not been previously reported and is key to understanding sulphate behavior and distribution. Modern and natural evaporitic microbial environments are important analogs for understanding brine evolution and mineral precipitation pathways in shallow water settings that have existed since the Archean on Earth and perhaps on Mars.     

Geochemical characterization of surface waters and groundwater resources in the Managua area (Nicaragua,Central America)

This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or anthropogenic origin. The effect of active thermalism on both surface waters (e.g., saline volcanic lakes) and groundwaters, as a result of mixing with variable proportions of hyper-saline geothermal Na–Cl brines (e.g., Momotombo geothermal plant), accounts for the high salinities and high concentrations of many environmentally-relevant trace elements (As, B, Fe and Mn) in the waters. At the same time the active extensional tectonics of the Managua area favour the interaction with acidic, reduced thermal fluids, followed by extensive leaching of the host rock and the groundwater release of toxic metals (e.g., Ni, Cu). The significant pollution in the area, deriving principally from urban and industrial waste-water, probably also contributes to the aquatic cycling of many trace elements, which attain concentrations above the WHO recommended limits for the elements Ni (∼40 μg/l) and Cu (∼10 μg/l) limiting the potential utilisation of Lake Xolotlan for nearby Managua.     

Efficient generation of conditional simulations by chebyshev matrix polynomial approximations to the symmetric square root of the covariance matrix

Consider the problem of generating a realization y₁ of a Gaussian random field on a dense grid of points ₁ conditioned on field observations y₂ collected on a sparse grid of points ₂. An approach to this is to generate first an unconditional realization y over the grid =_{1 2}, and then to produce y₁ by conditioning y on the data y₂. As standard methods for generating y, such as the turning bands, spectral or Cholesky approaches can have various limitations, it has been proposed by M. W. Davis to generate realizations from a matrix polynomial approximations to the square root of the covariance matrix. In this paper we describe how to generate a direct approximation to the conditional realization y₁, on ₁ using a variant of Davis' approach based on approximation by Chebyshev polynomials. The resulting algorithm is simple to implement, numerically stable, and bounds on the approximation error are readily available. Furthermore we show that the conditional realization y₁ can be generated directly with a lower order polynomial than the unconditional realization y, and that further reductions can be achieved by exploiting a nugget effect if one is present. A pseudocode version of the algorithm is provided that can be implemented using the fast Fourier transform if the field is stationary and the grid ₁ is rectangular. Finally, numerical illustrations are given of the algorithm's performance in generating various 2-D realizations of conditional processes on large sampling grids.     

Indirect tensile test assessments for rock materials using 3-D disc-type specimens

Indirect test methods are usually the preferred approach for determining the tensile strength of brittle and quasi-brittle materials such as ceramics, rocks, and concrete. In this paper, the tensile strength of a rock material (Iranian Harsin marble) was obtained indirectly by means of two disc type samples. The test samples were the well-known Brazilian disc and semi-disc specimen under three-point bend loading. Since the existing formula for determining the indirect tensile strength is based on 2-D stress assumption which ignores the effects of specimen thickness, a general 3-D tensile strength formulation was derived for each sample by employing finite element analysis. A series of tensile strength tests were conducted on Harsin white marble using disc and semi-disc specimens with different thicknesses in parallel to finite element analysis. The test results using 3-D formulation showed that the tensile strength of the tested marble depends on the thickness/diameter ratio of the specimen and generally decreases from 11.5 to 7 MPa on increasing the thickness of test samples. The average values of tensile strength were about 8.8 MPa for the Brazilian disc specimen and 9.8 MPa for the semi-disc specimen. The good agreement existing between the results of the two specimens suggests that the semi-disc specimen can also be used for determining the rock tensile strength in addition to using the conventional Brazilian test.     

Heavy rare gases from Rabbit Lake (Canada) and the Oklo mine (Gabon): natural spontaneous chain reactions in old uranium deposits

Xenon isotopic studies confirm natural spontaneous chain reactions at the Oklo mine site (Republic of Gabon) with an integrated neutron flux of approximately 4 × 10²⁰n/cm² and a duration between 14,000 and 70,000 years. Similar studies for the Rabbit Lake deposit (Saskatchewan), a slightly younger site with some evidence of continued geologic activity, shows no evidence of self-supporting reactions.     

Magnetic properties of basalts and geodynamics of the rift zone in the southern Red Sea

Magnetic properties of young rift basalts in the southern Red Sea are studied in detail. It is found that basalt samples dredged in the rift zone are characterized by a large spread in magnetic parameters. The magnetic properties of the basalts are shown to indicate a complex evolution of the Red Sea rift zone. Titanomagnetite grains of the basalts are mostly affected by single-phase oxidation processes and have preserved paleomagnetic information. However, basalts discovered near the rift axis yield evidence of multiphase oxidation of titanomagnetite grains, which is untypical of young oceanic basalts. These basalts have high Curie points and large values of the natural remanent magnetization and Koenigsberger parameter. The corresponding samples were taken in nontransform zones where rocks have experienced the action of significant tectonic forces and, moreover, anomalous geomagnetic field patterns correlate with the position of these zones. Using the magnetic properties of the basalts, the northern segment of the rift axis is relocated.     

Book reviews

Mineralium Deposita -     

The altitude dependence of the O2(A3Σu+) vibrational distribution in the terrestrial nightglow

A simple vibrational relaxation model which reproduces the observed altitude integrated vibrational distribution of the Herzberg I bands in the nightglow is used to derive the altitude profiles of the individual vibrational levels at 1 km intervals in the 85–115 km height range. The possible errors associated with using rocket-borne photometer measurements of a limited number of bands in the O₂(A³Σ_u⁺?X³Σ_g^?) system to infer the total Herzberg I emission profile are assessed.