Cryogenesis as a factor of methane distribution in layers of permafrost

The gas seeps in Kolyma lowland are associated with methane inclusions in permafrost. These inclusions are formed by methane squeezed by epigenetic freezing of methane saturated deposits. This is proved by the biological genesis of the methane, by the isotopic data and the lower radiocarbon age of the methane from the gas seep in comparison with the radiocarbon age of the host deposits. The experimental data and observations of methane distribution in permafrost indicate that the methane distribution in the stratum of frozen deposits is a result of methane migration during cryolithogenesis. The regularities of methane distribution in the deposits and formation of methane inclusions may change the idea of the character and volumes of emission of greenhouse gases into the atmosphere upon degradation of permafrost.     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

X-ray Raman scattering for structural investigation of silica/silicate minerals

We have performed X-ray Raman scattering (XRS) measurements on the oxygen K and silicon L absorption edges of four silica minerals: α-quartz, α-cristobalite, coesite, and stishovite. We have also calculated the partial electron densities of states (DOSs) and compared these with the XRS spectra. This study demonstrates that the short-range structure around the atom of interest strongly influences the XRS spectral features. Importantly, the oxygen K-edge XRS spectra are found to reflect the p-orbital DOS while the silicon L-edge spectra reflect the s- and d-orbital DOSs, even when a product of a momentum transfer and a mean radius of a electron orbit (1s for oxygen and 2p for silicon), Qr, is close to or larger than unity. Building on this, calculations of the partial DOSs for other silica phases are presented, including ultra-high-pressure phases, which provide a good reference for further XRS study of silica and silicate minerals. XRS measurements should be performed on not only either of oxygen or silicon but also on many kinds of constituent elements to reveal the structural change of glasses/melts of silicates under extreme conditions.     

Changing population concentration in India: a macro-regional scenario

There are great spatial variations in the distribution of the fast growing populations of India. About 70% of the 1981 population is concentrated in only 40% of the geographical area. Such a pattern of population concentration, with its spatio-temporal dimension, can be understood better if examined at the macro-regional level considering the physico-climatic and socio-economic diversity of the country. This is done by way of analyzing district level data for India as a whole and also for its various macro-regions. The study reveals that the Great Plains and Coastal Plains and Islands have a homogenous distribution and a higher population increase. The Deccan Plateau shows the most homogenous dispersion of population. The population is declining in the Northern Mountains and the Great Plains but accentuating in the Coastal Plains and Islands and the Deccan Plateau. The north and south of India are showing opposite trends in population concentration.     

Field and Laboratory Tests Investigating Settlements of Foundations on Weathered Keuper Marl

Measured settlements of buildings on the weathered Keuper Marl appeared to be much smaller than calculated settlements, which were based on stiffness modulus from standard oedometer tests. Therefore, both special triaxial K ₀-tests and oedometer tests were carried out for an accurate determination of stiffness moduli. Modulus obtained in the triaxial K ₀-tests were at least two to three times the values obtained in the oedometer tests. To verify observations from the laboratory tests, the loads and the settlements of two single footings on weathered Keuper mudstone have been measured during construction of a building over 1 year. Also, a large scale footing load test with measurements of deformations were conducted on the weathered Keuper mudstone. The measured settlements of the two single footings and the tested foundation were compared with the settlements based on conventional calculations with moduli from oedometer tests and triaxial K ₀-tests. Up to a foundation pressure of σ_v = 500 kN/m2 the calculated settlement based on E _S-modulus obtained from triaxial K ₀-tests was found to correspond well to the measured deformation. For foundation pressure beyond 500 kN/m2, the foundation response was highly non-linear and it could not be described any more with the linear-elastic model. Therefore the footing load test was also simulated by FEM analyses.     

Distribution analysis of salt affected soils under canal and non-canal command area in a part of Etah district,U. P., using remote sensing technique

A World Bank-aided project on sodic land reclamation in Uttar Pradesh is being executed by U.P. Bhumi Sudhar Nigam, Lucknow, and Remote Sensing Applications Centre, U.P., Lucknow has the responsibility of sodic land mapping for the execution of land reclamation programme at the cadastral level. Sodic lands are mainly concentrated in the Gangetic alluvial plains but the problem of sodicity is particularly acute in the canal-irrigated areas. A study of the distribution pattern of sodic lands in canal and noncanal command areas in a reclamation site (covering 60 villages out of which sodic lands were mapped in 51 villages) of Etah district in Uttar Pradesh, indicates that 18.39 per cent area of the canal command villages was barren sodic which was 13.41 per cent of the total geographical area of the site (15417 ha), however, 11.69 per cent area was recorded to be barren sodic in the non-canal command villages which was only 3.16 per cent of the geographical area of the site. The results of soil chemical analysis indicate that barren sodic lands of canal command area are saline-sodic with higher concentration of soluble salts (pH₂ >8.5, EC₂ >4 dSm⁻¹), however, those of non-canal command area are sodic (pH₂ >8.5, EC₂ <4 dSm⁻¹). The post-monsoon ground level in the canal-irrigated areas was in the critical and semicritical zone (< 3.0 mbgl) whereas it was well below the semi-critical zone in the non-canal command area, which indicates that the high ground water level is a major factor to higher the area under sodicity.     

Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.     

Seasonal drought effects on carbon sequestration of a mid-subtropical planted forest of southeastern China

Continuous measurement of carbon dioxide exchange using the eddy covariance (EC) technique is made at the Qianyanzhou mid-subtropical planted forest as part of the ChinaFLUX net-work. Qianyanzhou planted forest is affected by typical subtropical continental monsoon climate. It has plentiful water and heat resource but is in inconsistency of its seasonal distribution in the mid-subtropical region, thus seasonal drought frequently occurs in this planted forest. In this study, seasonal drought effect on ecosystem carbon sequestration was analyzed based on net ecosystem productivity (NEP), ecosystem respiration (RE) and gross ecosystem productivity (GEP) at the month scale in 2003 and 2004. In this drought-stressed planted forest, ecosystem carbon sequestration showed a clear seasonality, with low rates during seasonal drought and in winter. The declining degree of ecosystem carbon sequestration under the seasonal drought condition was determined by the accumulation of soil moisture deficits and a co-occurrence of high temperatures. Different drought effects are expected for RE and GEP. The net effect of ecosystem carbon balance depends on how these two quantities are affected relatively to each other. Summer drought and heat wave are two aspects of weather that likely play an important part in the annual NEP of forest in this region.     

Understanding and modeling basin hydrology: interpreting the hydrogeological signature

Basin landscapes possess an identifiable spatial structure, fashioned by climate, geology and land use, that affects their hydrologic response. This structure defines a basin's hydrogeological signature and corresponding patterns of runoff and stream chemistry. Interpreting this signature expresses a fundamental understanding of basin hydrology in terms of the dominant hydrologic components: surface, interflow and groundwater runoff. Using spatial analysis techniques, spatially distributed watershed characteristics and measurements of rainfall and runoff, we present an approach for modelling basin hydrology that integrates hydrogeological interpretation and hydrologic response unit concepts, applicable to both new and existing rainfall‐runoff models. The benefits of our modelling approach are a clearly defined distribution of dominant runoff form and behaviour, which is useful for interpreting functions of runoff in the recruitment and transport of sediment and other contaminants, and limited over‐parameterization. Our methods are illustrated in a case study focused on four watersheds (24 to 50 km²) draining the southern coast of California for the period October 1988 though to September 2002. Based on our hydrogeological interpretation, we present a new rainfall‐runoff model developed to simulate both surface and subsurface runoff, where surface runoff is from either urban or rural surfaces and subsurface runoff is either interflow from steep shallow soils or groundwater from bedrock and coarse‐textured fan deposits. Our assertions and model results are supported using streamflow data from seven US Geological Survey stream gauges and measured stream silica concentrations from two Santa Barbara Channel–Long Term Ecological Research Project sampling sites. Copyright © 2004 John Wiley & Sons, Ltd.