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31.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Abstract— It has now been about a decade since the first demonstrations that hypervelocity particles could be captured, partially intact, in aerogel collectors. But the initial promise of a bonanza of partially‐intact extraterrestrial particles, collected in space, has yet to materialize. One of the difficulties that investigators have encountered is that the location, extraction, handling and analysis of very small (10 μm and less) grains, which constitute the vast majority of the captured particles, is challenging and burdensome. Furthermore, current extraction techniques tend to be destructive over large areas of the collectors. Here we describe our efforts to alleviate some of these difficulties. We have learned how to rapidly and efficiently locate captured particles in aerogel collectors, using an automated microscopic scanning system originally developed for experimental nuclear astrophysics. We have learned how to precisely excavate small access tunnels and trenches using an automated micromanipulator and glass microneedles as tools. These excavations are only destructive to the collector in a very small area—this feature may be particularly important for excavations in the precious Stardust collectors. Using actuatable silicon microtweezers, we have learned how to extract and store “naked” particles—essentially free of aerogel—as small as 3 μm in size. We have also developed a technique for extracting particles, along with their terminal tracks, still embedded in small cubical aerogel blocks. We have developed a novel method for storing very small particles in etched nuclear tracks. We have applied these techniques to the extraction and storage of grains captured in aerogel collectors (Particle Impact Experiment, Orbital Debris Collector Experiment, Comet‐99) in low Earth orbit.  相似文献   
34.
Clear signature of non-gyrotropic energetic electron distributions was found by ISEE 1 and ISEE 2 spacecrafts just upstream of the Earth's bow shock and recently detected by in situ observations of the WIND plasma experiment. On the other hand, the appearance of non-gyrotropic ion velocity distributions is well established in the magnetotail providing evidence of magnetic reconnection processes. Motivated by these findings we introduce an analytical representation of non-Maxwellian/non-gyrotropic distribution functions, accurately fitting the characteristics of observations, where Maxwellians are recovered as special case of these highly general velocity space distributions. In particular, the analytical distribution function model can serve as basis of detailed wave-particle interaction analysis and of studies of the physical background of the evolution of both, non-gyrotropic electron and ion distributions, which is discussed for various space plasma environments.  相似文献   
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The surface digital photometry for NGC 5253 and NGC 2915 is given. The luminosity profiles and colour gradients are discussed and compared. It is concluded that NGC 2915 differs from NGC 5253, both in the extension and intensity of the star burst event because of the kinematical behaviour of the captured gas.CONICET, Buenos Aires, Visiting Astronomer, Cerro Tololo Inter-American Observatory, La Serena, Chile, operated by NSF  相似文献   
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文中所作的主要工作是为云南天文台十米抛物面设计、制造一付好的对数周期偶极子天线(LPDA)作馈源。工作有:(1)设计一对交叉的LP-DA;(2)分析LPDA特性;(3)估算抛物面的电特性;(4)讨论线极化向园极化转换的问题;(5)天线测量。LPDA的测量结果比较满意。该天线的方向图、平均输入阻抗、三分贝和十分贝波瓣宽度都在从0.5-1.5GHz的频率范围内比较一致和稳定,变化很小。天线理论上的许多成就都是与数子计算机有关的。在文中,我们充分利用了计算机的功能来设计天线,分析天线特性,并从测量所得的所有数据文件中计算天线的参数。所编FORTRAN程序使这一切工作变得容易。最后,我们还讨论了用功率合成器实现线极化向园极化转换的各种情况  相似文献   
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Morphological, seismic and lithostratigraphic investigations of a moraine deposit at Bleik (the Bleik moraine), northern Andøya, show short-distance transported till overlying long-distance transported predominantly glaciofluvial ice-marginal deposits. Consolidated glaciomarine sediments from a core at present sea-level, c . 400 m distally to the moraine complex, contain 31 species of foraminifera, among which Cassidulina reniforme, Islandiella helenae and Trifarina fluens dominate, and fragments of the molluscs Mya truncata and Astarte sp. and the echinoid Strongylocentrotus sp. Amino acid analyses of the foraminifera Cibicides lobatulus and the mollusc Mya truncata indicate ages between 22,000 and 16,000 BP. Radiocarbon dating of fragments of Mya truncata from the upper part of the core gave an age of 17,940 ± 245 BP, while a dating of unidentified shell fragments from the lower part gave an infinite age (>40,000 BP). The sediment was probably disturbed by icebergs beyond the end moraine zone, and the radiocarbon and amino acid dating of Mya truncata therefore represent a maximum age for this process. This new evidence indicates two phases with a higher relative sea-level than at present at Bleik, c . 18,000 and >40,000 BP. The Bleik moraine probably represents the early Late Weichselian glacial maximum ( c . 22,000 BP), while the underlying deglaciation deposit and associated beach-ridge (Bruvollen) is of pre-Late Weichselian age. Moraine ridges 3–4 km to the south of Bleik probably indicate advances of local glaciers between 22,000 and 18,000 BP.  相似文献   
40.
It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   
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