Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.     

Analysis of the Seasonal Variation of CO<Subscript>2</Subscript> Concentration in China Based on GOSAT Satellite Data

Carbon dioxide (CO₂) is one of the major gases that contribute to the global warming. Therefore, studying the distribution of CO₂ can help people understand the carbon cycle. Based on the GOSAT retrieved CO₂ products, the temporal and spatial distribution and seasonal variation of CO₂ concentration were analyzed from 2011 to 2015. CO₂ concentration has obvious seasonal variation. It was low in summer, and was high in spring, and the annual increase was about 2 ppm. Nevertheless, the annual growth rate of CO₂ concentration in summer was higher than that in spring, it was 0.5425% in summer and was 0.46% in spring. CO₂ concentration was low in the northwest and was high in the southeast. The growth rate of CO₂ was 2.8 ppm in the northwest and was 3.42 ppm in the southeast. More human’s activities made CO₂ concentration higher in the southeast than that in other regions.     

Cloning of a chub metallothionein cDNA and development of competitive RT-PCR of chub metallothionein mRNA as a potential biomarker of heavy metal exposure

Metallothionein has been assayed in a range of aquatic animal tissues as an indicator of metal exposure. We sequenced chub (Leuciscus cephalus) metallothionein cDNA which showed over 90% homology to common carp, goldfish and stone loach and 77% homology to rainbow trout sequences for metallothionein. We then used the extended primer method to develop an accurate quantitative competitive RT-PCR assay for metallothionein mRNA. RT-PCR was used to measure metallothionein mRNA in feral chub from a range of field sites, with different levels of heavy metal pollution, in the West Midlands, UK. Measurements were complemented by analysis of liver and gill metallothionein protein by capillary electrophoresis. There was no significant difference in the metallothionein protein levels between fish of different rivers and there was no evidence of elevation of mRNA at the sites of highest metal exposure. The level of metal exposure (e.g. zinc, nickel and cadmium each ranging between 15 and 28 microg/l ) at the pH (7.5-8.5) of these rivers appears insufficient to elevate hepatic or gill metallothionein in chub. A lack of elevation of hepatic metallothionein mRNA in chub exposed to zinc, copper and manganese for 24 h and 10 days in the laboratory also suggests a non-responsiveness of this species.     

Investigation of waste disposal areas using electrical methods: a case study from Chania,Crete, Greece

A geophysical investigation of a landfill area was conducted as inextricable phase of a preliminary geotechnical, geological and hydrogeological study of the area under investigation. Electrical resistivity tomography (ERT), one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modeling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The survey site is located in Akrotirion Peninsula, about 7 km east of Chania city in Crete I. The geological setting comprises Trypalion limestones, marly limestones and a clayed weathered layer. Cavities are also identified at various scales which are recent tectono-karstic voids. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out. Specifically, seven geoelectrical tomographies were conducted reaching the prospecting depth of 36 m. The resulted images conduced, to overcome geotechnical problems since the spatial distribution of karstic voids was determined, to plan the future sites for waste disposal as the geological conditions were studied in detail and to reliably estimate the thickness of the already deposited wastes. The resulted images were confirmed using available borehole logs and ambient noise measurements.     

Some observations from the data taken in and around Kharagpur during the onset of the monsoon, 1990

During MONTBLEX 1990, various observational platforms were operated at Kharagpur and the nearby Kalaikunda Air Base. Using the data from all the platforms, one can draw the following conclusions. The temperature and wind data obtained from various sensors have overall compatibility. Sodar wind data indicate the presence of a low level jet at around 300 m above ground. The inversion height may be evaluated from the vertical profile of the sodar back-scatter echo intensity. The sub-synoptic or synoptic scale convergence modulates the inversion height and the presence of cloud-base within the inversion height in turn modulates the sensible heat and momentum fluxes.     

Hydraulic Conductivity Tests for Evaluating Compatibility of Lateritic Soil—Fly Ash Mixtures with Municipal Waste Leachate

Long term competent performance of liner systems is a critical issue in the design and construction of waste repositories due to adverse interactions associated with leachate generated by wastes. This study was conducted to verify the efficacy of fly ash stabilization in enhancing compatibility between lateritic soil and municipal waste leachate. Applications investigated include soil mixtures containing 0, 5, 10, 15, and 20% fly ash compacted at approximately 2% wet of optimum moisture content with modified proctor energy. Baseline hydraulic conductivity was first established at every level of fly ash content by permeating soil mixtures with tap water before permeation with leachate in a compaction mould permeameter using the falling head test method. Results show that the trend in hydraulic conductivity of specimen containing 0% fly ash was characterized by a gradual but erratic decrease which may suggests partial entry of the leachate cations into the double layer. Conversely, specimens containing fly ash showed a general trend consisting of an initial drop in k (up to an order of magnitude) that was followed by slight decrease sustained until k stabilized and later terminated. Above 10% fly ash content, the relatively high values of k observed was not connected with the reactivity of the soil mixtures with leachate, rather it may be attributed to excessive fly ash content that altered their textural and hydraulic properties. The result of this study is potentially significant in the assessment of fly ash as a compatibility enhancing agent which can be admixed in barrier materials that are susceptible to adverse reactions with the liquid to be contained.     

Determination of shear strength of conglomerates using a caterpillar D9 ripper and comparison with alternative methods

Summary A method of determining shear strength in Gila Conglomerates at Inspiration Mine (now Cyprus Miami Mine), Arizona, using Caterpillar D9H and D9L rippers is described. The results are compared with data obtained using laboratory direct shear tests — both large and small scale, back analysis and boulder modelling. The significance of scale, particularly relating to boulder size is discussed.     

The spatial implications of the functional proximity deriving from air passenger flows between European metropolitan urban regions

Until recently the traditional spatial configuration of the European geography was based upon the core-periphery model. The ‘pentagon’, broadly defined as lying between London, Paris, Milan, Munich and Hamburg, was seen as the core area characterised by having the highest concentration of economic development in the European Union (EU), with the remainder of the European territory viewed as peripheral, albeit to varying degrees. In a number of cases such peripheral areas equated with clear regional disparities. The elaboration of the European Spatial Development Perspective (ESDP) (CEC, European spatial development perspective, towards balanced and sustainable development in the territory of the European Union, 1999) challenged this core-periphery model. European spatial planning policies, aimed at encouraging social and economic, and with ever increasing importance, territorial cohesion, seek amongst other aspects to encourage the development of a balanced and polycentric urban system. This paper adopts a network analysis approach to the analysis of air passenger flows between some 28 principal European metropolitan urban regions. The evaluation of these flows contributes to an enhanced comprehension of the spatial dynamics of the European metropolitan territory which goes beyond that deriving from the more standard analyses of the individual components of the urban system. Several indicators are used, deriving from gravitational modelling techniques, to analyse the complexity of the air passenger flows. A multidimensional scaling (MDS) technique is introduced in order to interpret and visualise the resulting spatial configuration and positioning of the different metropolitan centres within the conceptual European ‘space of air passenger flows’, thereby contrasting with the more traditional map-based geographical image of Europe, based upon Cartesian coordinates.

Geochronology and geochemistry of Grenvillian igneous suites in the northern Oaxacan Complex, southern Mexico: tectonic implications

Chemical and U–Pb isotopic analyses of metaigneous rocks in the northern Oaxacan Complex in southern Mexico indicate that they form part of two granitic–gabbroic suites intruded at 1157–1130 and 1012 Ma, which were metamorphosed under granulite facies conditions between 1004 and 980 Ma. Although the older suite has both within-plate and arc geochemical signatures, the arc characteristics (enrichment of La and Ce relative to Nb, Ta, and Th) are inferred to result from crustal contamination, a conclusion consistent with their negative _Nd signatures. The younger suite is spatially associated with anorthosites (from which we were unable to acquire a protolith age), suggesting that collectively it forms part of anorthosite–mangerite–charnockite–granite (AMCG) suites. The tholeiitic nature of the mafic rocks along with the within-plate character of the felsic rocks suggests that they were intruded during extension related to either farfield backarc rifting, rifting above a slab window, or anorogenic intercontinental rifting. Potentially correlative AMCG suites are widespread in Mexico, the Grenville Province of eastern Canada and northeastern USA, and the Andean massifs of Colombia, however, Pb isotopic data most closely resemble those in South America. These data are consistent with published hypotheses that suggest Oaxaquia represents an exotic terrane derived from Amazonia.