Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.     

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.     

Magnetotelluric investigations for imaging electrical structure of Garhwal Himalayan corridor,Uttarakhand, India

Magnetotelluric investigations have been carried out in the Garhwal Himalayan corridor to delineate the electrical structure of the crust along a profile extending from Indo-Gangetic Plain to Higher Himalayan region in Uttarakhand, India. The profile passing through major Himalayan thrusts: Himalayan Frontal Thrust (HFF), Main Boundary Thrust (MBT) and Main Central Thrust (MCT), is nearly perpendicular to the regional geological strike. Data processing and impedance analysis indicate that out of 44 stations MT data recorded, only 27 stations data show in general, the validity of 2D assumption. The average geoelectric strike, N70°W, was estimated for the profile using tensor decomposition. 2D smooth geoelectrical model has been presented, which provides the electrical image of the shallow and deeper crustal structure. The major features of the model are (i) a low resistivity (<50Ωm), shallow feature interpreted as sediments of Siwalik and Indo-Gangetic Plain, (ii) highly resistive (> 1000Ωm) zone below the sediments at a depth of 6 km, interpreted as the top surface of the Indian plate, (iii) a low resistivity (< 10Ωm) below the depth of 6 km near MCT zone coincides with the intense micro-seismic activity in the region. The zone is interpreted as the partial melting or fluid phase at mid crustal depth. Sensitivity test indicates that the major features of the geoelectrical model are relevant and desired by the MT data.     

Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.     

Temporal characteristics of aerosol physical properties at Visakhapatnam on the east coast of India during ICARB — Signatures of transport onto Bay of Bengal

Realizing the importance of aerosol physical properties at the adjoining continental and coastal locations in the airmass pathways onto the oceanic region, extensive measurements of aerosol physical properties were made at Visakhapatnam (17.7°N, 83.3°E), an eastern coastal location in peninsular India during the ICARB period. The temporal variations of aerosol optical depth, near surface aerosol mass size distributions and BC mass concentrations show significantly higher aerosol optical depth and near surface mass concentrations during the first and last weeks of April 2007. The mean BC mass fraction in the fine mode aerosol was around 11%. The aerosol back scatter profiles derived from Micro Pulse Lidar indicate a clear airmass subsidence on the days with higher aerosol optical depths and near surface mass fraction. A comparison of the temporal variation of the aerosol properties at Visakhapatnam with the MODIS derived aerosol optical depth along the cruise locations indicates a resemblance in the temporal variation suggesting that the aerosol transport from the eastern coastal regions of peninsular India could significantly affect the aerosol optical properties at the near coastal oceanic regions and that the affect significantly reduced at the farther regions.     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Aerosol mass loading over the marine environment of Arabian Sea during ICARB: Sea-salt and non-sea-salt components

Mass loading and chemical composition of atmospheric aerosols over the Arabian Sea during the pre-monsoon months of April and May have been studied as a part of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB). These investigations show large spatial variabilities in total aerosol mass loading as well as that of individual chemical species. The mass loading is found to vary between 3.5 and 69.2 μg m^?3, with higher loadings near the eastern and northern parts of Arabian Sea, which decreases steadily to reach its minimum value in the mid Arabian Sea. The decrease in mass loading from the coast of India towards west is estimated to have a linear gradient of 1.53 μg m^?3/° longitude and an e^?1 scale distance of ～2300 km. SO ₄ ^2? , Cl^? and Na⁺ are found to be the major ionic species present. Apart from these, other dominating watersoluble components of aerosols are NO ₃ ^? (17%) and Ca²⁺ (6%). Over the marine environment of Arabian Sea, the non-sea-salt component dominates accounting to ～76% of the total aerosol mass. The spatial variations of the various ions are examined in the light of prevailing meteorological conditions and airmass back trajectories.     

A technical note on seismic microzonation in the central United States

Microzonation is an effort to evaluate and map potential hazards found in an area, urban area in particular, that could be induced by strong ground shaking during an earthquake. These hazards include: ground motion amplification, liquefaction, and slope failure. The microzonation maps, depicting ground-motion amplification, liquefaction, and landslide potentials, can be produced if the ground motion on bedrock (input) and the site conditions are known. These maps, in combination with ground-motion hazard maps (on bedrock), can be used to develop a variety of hazard mitigation strategies such as seismic risk assessment, emergency response and preparedness, and land-use planning. However, these maps have certain limitations that result from the nature of regional mapping, data limitations, generalization, and computer modeling. These microzonations show that when strong ground shaking occurs, damage is more likely to occur, or be more severe, in the higher hazard areas. The zones shown on the hazard maps should not serve as a substitute for site-specific evaluations.