Petrology and geochemistry of greywackes from Goa-Dharwar sector,western Dharwar Craton: Implications for volcanoclastic origin

Late Archaean Supracrustals of the Goa-Dharwar sector (GDS) are composed of a thick sequence of greywacke sequence with narrow intercalations of quartzite, BIF and carbonates. Mafic volcanics occupy the base of the sequence. The greywackes are predominantly tuffacious containing chlorite-sericite and hornblende. Arkosic variations containing biotite dominate the western part of the sector. Fine-grained variations occur as isolated narrow lenses within other types of greywackes. The conglomeratic greywackes are localized along the western and the eastern margins of the sector. All of the greywackes are all typically immature containing coarser clasts of mostly plagioclase (18–23%) and quartz (32–34%). Lithic fragments of felsic volcanic rocks are common. The matrix is dominated by mafic material. Biotite and amphibole are related to metamorphic recrystallization. Chlorite, sericite, epidote, carbonate and chert are products of the interplay of diagenesis and low-grade metamorphism. Fe-Ti oxide, sphene, apatite and zircon are usual accessories. But for slight enrichment in K₂O, the major element chemistry of the GDS greywackes is similar to the chemistry of Late Archaean greywackes. They also compare in respect of V, Co, Hf contents, K₂O/Na₂O, SiO₂/Al₂O₃, Na₂O/Al₂O₃, Ba/Rb, Th/U, La/Th, Sm/Nd ratios, steep REE patterns with distinct LREE enrichment and HREE depletion. The GDS greywackes however are distinctly enriched in Rb, Ba, Sr, Th, U, Cu, Zr, Ce/Ce* and depleted in Cr, Ni, and Zn. The conglomeritic and biotite bearing verities contain considerable proportions of clasts derived from the basement tonalitic/granitic terrain. The common tuffacious greywackes containing hornblende and biotite-sericite however include only volcanic clasts and bear evidence of derivation from submarine weathering of predominantly felsic volcanics erupted on a large scale to form a magmatic arc in the later stages of geosynclinal deposition. Geochemical data suggest that the GDS greywackes were laid down in progressively changing basin geometry from a passive to active continental margin and island arc setting.     

Imbalance in the carbonate budget of surficial sediments in the North Atlantic Ocean: variations over the last millenium?

Fluxes contributing to the particulate carbonate system in deep-sea sediments were investigated at the BENGAL site in the Porcupine Abyssal Plain (Northeast Atlantic). Deposition fluxes were estimated using sediment traps at a nominal depth of 3000 m and amounted to 0.37±0.1 mmol C m⁻² d⁻¹. Dissolution of carbonate was determined using flux of total alkalinity from in situ benthic chambers, is 0.4±0.1 mmol C m⁻² d⁻¹. Burial of carbonate was calculated from data on the carbonate content of the sediment and sedimentation rates from a model age based on ¹⁴C dating on foraminifera (0.66±0.1 mmol C m⁻² d⁻¹). Burial plus dissolution was three times larger than particle deposition flux which indicates that steady-state is not achieved in these sediments. Mass balances for other components (BSi, ²¹⁰Pb), and calculations of the focusing factor using ²³⁰Th, show that lateral inputs play only a minor role in this imbalance. Decadal variations of annual particle fluxes are also within the uncertainty of our average. Long-term change in dissolution may contribute to the imbalance, but can not be the main reason because burial alone is greater than the input flux. The observed imbalance is thus the consequence of a large change of carbonate input flux which has occured in the recent past. A box model is used to check the response time of the solid carbonate system in these sediments and the time to reach a new steady-state is in the order of 3 kyr. Thus it is likely that the system has been perturbed recently and that large dissolution and burial rates reflect the previously larger particulate carbonate deposition rates. We estimate that particulate carbonate fluxes have certainly decreased by a factor of at least 3 and that this change has occurred during the last few centuries.     

“Basin scale” versus “localized” pore pressure/stress coupling - Implications for trap integrity evaluation

In petroleum industry, the difference between pore pressure (P_p) and minimum horizontal stress S_h (termed the seal or retention capacity) is of major consideration because it is often assumed to represent how close a system is to hydraulic failure and thus the maximum hydrocarbon column height that can be maintained. While S_h and P_p are often considered to be independent parameters, several studies in the last decade have demonstrated that S_h and P_p are in fact coupled. However, the nature of this coupling relationship remains poorly understood. In this paper, we explore the influences of the spatial pore pressure distribution on S_h/P_p coupling and then on failure pressure predictions and trap integrity evaluation. With analytical models, we predict the fluid pressure sustainable within a reservoir before failure of its overpressured shale cover. We verify our analytical predictions with experiments involving analogue materials and fluids. We show that hydraulic fracturing and seal breach occur for fluid pressure greater than it would be expected from conventional retention capacity. This can be explained by the impact of the fluid overpressure field in the overburden and the pressure diffusion around the reservoir on the principal stresses. We calculate that supralithostatic pressure could locally be reached in overpressured covers. We also define the retention capacity of a cover (RC) surrounding a fluid source or reservoir as the difference between the failure pressure and the fluid overpressure prevailing in shale at the same depth. In response to a localized fluid pressure rise, we show that the retention capacity does not only depend on the pore fluid overpressure of the overburden but also on the tensile strength of the cover, its Poisson’s ratio, and the depth and width of the fluid source.     

Geology and petroleum potential of the Fairway Basin in the Tasman Sea

The Fairway Basin is a large, generally north – south-trending, sediment-filled structure in water 1500 – 3000 m deep, on the eastern slope of the Lord Howe Rise in the Tasman Sea, and is partly within Australian jurisdiction. It was poorly known until a few years ago, when seismic profiling and piston coring cruises were carried out. The basin, about 1100 km long and 120 – 200 km wide, can be divided into three segments—north, central and south—that trend northwest, north and north-northwest, respectively. All three segments probably formed by thinning of continental crust during breakup of Lord Howe Rise and surrounding aseismic continental ridges in the Late Cretaceous and Paleocene. Normal faulting, large inputs of terrigenous sediment and subsidence to bathyal marine depths occurred during that time. A period of compression, perhaps related to overthrusting on New Caledonia, occurred in the Eocene, leading to uplift (and in parts, erosion) of northern Lord Howe Rise, and reversal of faulting in the basin. By the Oligocene, the area was again in bathyal depths, and pelagic ooze and some turbidites accumulated. The basinal sequence is generally 2000 – 4000 m thick, with 1200 – 3200 m of Cretaceous to Eocene sediment concentrated in depocentres, capped by 500 – 800 m of Oligocene and younger sediment. In the depocentres, numerous sedimentary diapirs pierce sedimentary sequences. The sedimentary diapirs appear to be fed by Cretaceous muds deposited during rifting. Often, these diapirs are overlain by faults extending to the seafloor, and hummocky bathymetry is possibly caused by fluid escape. The overall geology suggests that the Fairway Basin may be a large frontier hydrocarbon province. Seismic profiles display a bottom-simulating reflector above many depocentres, 500 – 700 m below the seafloor. The bottom-simulating reflector has positive polarity, which could result from a diagenetic phase transformation, a thin gas hydrate layer with a sharp top, or from the sharp base of a gas layer (probably beneath gas hydrates). Standard piston cores taken above diapirs and apparent fluid-escape features have recovered little gas. Other than drilling, the next steps in assessing petroleum potential are to clearly document fluid-escape structures, and to sample any fluids emitted for hydrocarbons.     

Comparison of Three Un-mixing Based Hyperspectral Image Fusion Techniques

With the availability of multi sensor data in many fields, such as remote sensing, medical imaging or machine vision, sensor fusion has emerged as a new and promising research area. It is possible to have several images of the same scene providing different information although the scene is the same. This is because each image has been captured with a different sensor. A non-negative matrix factorization (NNMF) un mixing based fusion technique with vertex component analysis (VCA) based end member initialization and simple multiplicative update to improve the spatial resolution and to preserve the spectral resolution of the hyper spectral image is proposed. Its performance is analyzed with different number of iterations and end member initializations. A Constrained Non Negative Matrix Factorization unmixing based fusion technique is developed by adding a regularization term to the objective function to preserve the spectral resolution of the hyper spectral image, and its performance is analyzed with different number of iterations and end members. A rank two NNMF and hierarchical clustering based end member initialization and block principal pivoting algorithm based abundance estimation technique, for fusing hyper spectral image and simulated multispectral image is proposed and its performance is analyzed for different overlapping and non overlapping group of multispectral and hyper spectral bands. The performance of the above three methods are compared and analyzed. The obtained results show that the performance of rank two NNMF hierarchical clustering based fusion technique is better than the other two constrained and unconstrained NNMF un mixing based techniques. Also, the performance of these three proposed multi sensor image fusion techniques are compared with an existing image fusion technique.     

Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Geochemical Changes in Metal and Nutrient Loading at Orplands Farm Managed Retreat Site, Essex, UK (April 1995–1997)

Salt marshes have recently been considered to be a major part of the coastal system and have played a key role in the development of the UK coastal management strategy. Managed Retreat (MR) is a process aimed to restore salt marshes by realignment of the seawalls allowing tidal inundation of low value agricultural land. The resultant marshes are expected to function both as an integral part of the flood defence system and as an ecological conservation area. We report on the effects of salt marsh restoration on metal and nutrient loading of the sediment at the Orplands Farm MR site, Essex, UK. Surficial grab and sediment cores were collected from the two fields that comprise the site. The heavy metals, Cd, Cr, Cu, Hg, Pb, Ni and Zn were analysed to determine changes in anthropogenic inputs to sediments. The major ions, Al, Ca, Fe, K, Mg, Mn and Na were also monitored to identify changes in sediment geochemistry. Analysis of the cored sediments after inundation for Na and Sr demonstrated that penetration of estuarine water had, within 2 yr of exposure, reached an average depth of 20 cm. The study observed that input of heavy metals had occurred to the sediments with the most significant being that of Pb, however increases were also observed for Cr and Cu. However, concentrations of Cd in the MR sediments decreased from 1995 to 1997. For the major metals within both fields it was found that the dominant changes were those of enrichment of marine associated metals, Ca, K, Mg and Na via inputs from tidal inundation. The concentration of Ca in the sediments was further enriched by the deposition of carbonates to the sediments. One field demonstrated a significant loss of Fe from sediments which corresponded to changes in redox potential of the sediments. Differences observed in geochemical profiles between the two fields of the site were attributed to differences in land use prior to flooding.     

Mineral zoning as a record of P,T history of Precambrian eclogites and schists in western Tasmania

Ferromagnesian minerals, particularly garnet but also phengite, omphacite and talc, from eclogites and surrounding schists from the Lyell Highway-Collingwood river area, western Tasmania are compositionally zoned.In rocks which have suffered little secondary alteration the Mg-value ($\text{100 Mg}\text{Mg+Fe}{}^{\mathrm{++}}$) of granets increases from core to rim, while the Mg-value of the most important coexisting ferromagnesian phases (clinopyroxene, phengite and talc in different assemblages) decreases from core to rim. CaO decreases from core to rim in garnet. MnO may show little or no variation in garnet, or decrease from core to rim.When compared with experimental data, the zoning of these minerals can be uniquely explained by growth during changing P,T conditions. The eclogites and the surrounding schists have the same prograde P,T history.When determining the K_D-values of garnet and its coexisting ferromagnesian phases it is important to consider secondary rim alterations as well as the prograde zoning of the mineral.     

A Case Study on the Effects of Heterogeneous Soil Moisture on Mesoscale Boundary-Layer Structure in the Southern Great Plains, U.S.A. Part II: Mesoscale Modelling

The importance of soil moisture inputs and improved model physics in the prediction of the daytime boundary-layer structure during the Southern Great Plains Hydrology Experiment 1997 (SGP97) is investigated using the non-hydrostatic fifth-generation Pennsylvania State University/National Center for Atmospheric Research (PSU/NCAR) Mesoscale Model MM5. This is Part II of a two-part study examining the relationship of surface heterogeneity to observed boundary-layer structure. Part I focuses on observations and utilizes a simple model while Part II uses observations and MM5 modelling. Soil moisture inputs tested include a lookup table based on soil type and season, output from an offline land-surface model (LSM) forced by atmospheric observations, and high-resolution ( 800 m) airborne microwave remotely sensed data. Model physics improvements are investigated by comparing an LSM directly coupled with the MM5 to a simpler force-restore method at the surface. The scale of land surface heterogeneities is compared to the scale of their effects on boundary-layer structure.The use of more detailed soil moisture fields allowed the MM5 to better represent the large-scale (hundreds of km) and small-scale (tens of km) horizontal gradients in surface-layer weather and, to a lesser degree, the atmospheric boundary-layer (ABL) height, which was evaluated against observations measured by differential absorption lidar (DIAL). The benefits of coupling an LSM to the MM5 were not readily evident in this summertime case, with the model having particular difficulty simulating the timing of maximum surface fluxes while underestimating the depth of the mixed layer.