Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Aerosol mass loading over the marine environment of Arabian Sea during ICARB: Sea-salt and non-sea-salt components

Mass loading and chemical composition of atmospheric aerosols over the Arabian Sea during the pre-monsoon months of April and May have been studied as a part of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB). These investigations show large spatial variabilities in total aerosol mass loading as well as that of individual chemical species. The mass loading is found to vary between 3.5 and 69.2 μg m^?3, with higher loadings near the eastern and northern parts of Arabian Sea, which decreases steadily to reach its minimum value in the mid Arabian Sea. The decrease in mass loading from the coast of India towards west is estimated to have a linear gradient of 1.53 μg m^?3/° longitude and an e^?1 scale distance of ～2300 km. SO ₄ ^2? , Cl^? and Na⁺ are found to be the major ionic species present. Apart from these, other dominating watersoluble components of aerosols are NO ₃ ^? (17%) and Ca²⁺ (6%). Over the marine environment of Arabian Sea, the non-sea-salt component dominates accounting to ～76% of the total aerosol mass. The spatial variations of the various ions are examined in the light of prevailing meteorological conditions and airmass back trajectories.     

Urban effects of Chennai on sea breeze induced convection and precipitation

Doppler radar derived wind speed and direction profiles showed a well developed sea breeze circulation over the Chennai, India region on 28 June, 2003. Rainfall totals in excess of 100 mm resulted from convection along the sea breeze front. Inland propagation of the sea breeze front was observed in radar reflectivity imagery. High-resolution MM5 simulations were used to investigate the influence of Chennai urban land use on sea breeze initiated convection and precipitation. A comparison of observed and simulated 10m wind speed and direction over Chennai showed that the model was able to simulate the timing and strength of the sea breeze. Urban effects are shown to increase the near surface air temperature over Chennai by 3.0K during the early morning hours. The larger surface temperature gradient along the coast due to urban effects increased onshore flow by 4.0m s⁻¹. Model sensitivity study revealed that precipitation totals were enhanced by 25mm over a large region 150 km west of Chennai due to urban effects. Deficiency in model physics related to night-time forecasts are addressed.     

Seismic hazard assessment of Chennai city considering local site effects

Chennai city suffered moderate tremors during the 2001 Bhuj and Pondicherry earthquakes and the 2004 Sumatra earthquake. After the Bhuj earthquake, Indian Standard IS: 1893 was revised and Chennai city was upgraded from zone II to zone III which leads to a substantial increase of the design ground motion parameters. Therefore, a comprehensive study is carried out to assess the seismic hazard of Chennai city based on a deterministic approach. The seismicity and seismotectonic details within a 100 km radius of the study area have been considered. The one-dimensional ground response analysis was carried out for 38 representative sites by the equivalent linear method using the SHAKE91 program to estimate the ground motion parameters considering the local site effects. The shear wave velocity profile was inferred from the corrected blow counts and it was verified with the Multichannel Analysis of Surface Wave (MASW) test performed for a representative site. The seismic hazard is represented in terms of characteristic site period and Spectral Acceleration Ratio (SAR) contours for the entire city. It is found that structures with low natural period undergo significant amplification mostly in the central and southern parts of Chennai city due to the presence of deep soil sites with clayey or sandy deposits and the remaining parts undergo marginal amplification.     

Observations of unusual whistlers during daytime at Jammu

In this paper, we report observations of unusual whistlers recorded at Jammu (geomag. lat. = 22°26′N; L = 1.17), India on March 8, 1999 during the daytime. They are interpreted as one-hop ducted whistlers having propagated along higher L-values in closely spaced narrow ducts from the opposite hemispheres. After leakage from the duct, the waves might have propagated in the earth-ionosphere waveguide towards the equator in surface mode. Tentative explanation of the dynamic spectra of these events is briefly presented.     

高效液相色谱-等离子体质谱技术在溴元素形态分析中的应用

溴是一种在自然水体中都含有的元素,通常以B r-的形式存在。目前最常用的水净化方式就是向水中通入臭氧以杀灭细菌;而臭氧分解的副产物即为B r-转换成的B rO3-,这是一种公认的致癌物质。本实验室曾使用阴离子交换高效液相色谱(HPLC)与等离子体质谱(ICP-MS)联用分析B rO3-和B r-,方法虽能有效地将这两种溴形态分离,但分析每个样品需8 m in。本文试图建立新的方法缩短分析时间,并验证该方法应用于实际水样分析时测定其他含溴化合物的能力。1实验部分1.1高效液相色谱分析条件表1列出了等度淋洗和梯度淋洗两种模式下HPLC的分析条件,完成形态的分离。等度淋洗和梯度淋洗在分析中显示出不同     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

Gouging abrasion test for rock abrasiveness testing

Wear parts of many mineral processing and mining equipment are often subjected to high stress loads applied at high speeds and at varying angles of incidence, where the prevalent mode of wear is high-stress gouging/sliding impact abrasion. Examples include crusher liners, wear liners in hoppers and chutes, picks on roadheaders, discs on tunnel boring machines and ground engaging tools. Abrasion under these conditions is characterised by a high material removal rate and thus has a direct bearing on wear rates and service life of the equipment concerned. However, at present there appears to be no method for rock abrasiveness assessment under these conditions. This paper describes a new Gouging Abrasion method and apparatus for testing abrasivity of rocks under high-stress gouging/sliding impact wear. A Gouging Abrasion Index (Gi) is introduced, which can be used for prediction and assessment of component life expectancy and efficiency of mineral processing and materials handling equipment. Experimental data from Gouging Abrasion testing of numerous Australian rock types are presented. It is suggested that the results of Gi testing can be used for wear rate predictions for a variety of mineral processing and materials handling equipment working under high-stress gouging/sliding impact abrasion conditions.