Modeling an atypical petroleum system: A case study of hydrocarbon generation,migration and accumulation related to igneous intrusions in the Neuquen Basin,Argentina

In the Altiplanicie del Payún area (Neuquen Basin, Argentina), immature source rock sections intruded by up to 600 m thick Tertiary laccoliths show full spectrum maturity aureoles over hundreds of meters from the contacts. Commercial oil accumulations (20–33°API) and oil shows are located along the entire column, both in sandstone/carbonate and fractured igneous reservoirs. A challenging numerical model that included the emplacement of the intrusive bodies, with extreme temperature ranges and unusually short calculation time steps, has been done with the aim to better understand hydrocarbon generation and migration processes related to these thermal anomalies.     

Biometric,microstructural, and high-resolution trace element studies in Crassostrea gigas of Cantabria (Bay of Biscay,Spain): Anthropogenic and seasonal influences

Living Crassostrea gigas oysters of different ages and sizes were collected in three estuaries of Cantabria (Bay of Biscay, Spain): San Vicente de la Barquera Estuary, Santander Bay, and Marismas de Santoña Estuary. The main objective was to determine different shell responses to variable environmental parameters. A shell morphological study, based on three biometric indices, indicates that oysters of Santander Bay have two significant shell anomalies: abnormal thickening of the right valve and loss of vital cavity volume. These shell abnormalities are related with the presence in these waters of the chemical tributyltin. In the other two estuaries, the oysters show no detectable anomalies. Four shell microstructures have been distinguished: Regular Simple Prismatic, Regular Foliated, cone-Complex Cross Foliated, and Chalk. In Santander Bay oysters, the Chalk forms a “root-type” framework, whereas in the other two estuaries it forms a more compact microstructure. It is proposed that exposure to tributyltin has produced this modification. High-spatial-resolution geochemical transects have been carried out on the Regular Foliated microstructure in the umbo region in order to evaluate the distribution of Mg, Sr, and Na. The elements analysed exhibit clear cyclic variations in San Vicente de la Barquera Estuary and Marismas de Santoña Estuary oysters, related with seasonal periods, and characterised by broad maxima during months in which the waters are warmer and have higher salinity. These patterns are buffered in Santander Bay oysters. Our results demonstrate that biometric, microstructural, and high-resolution trace element studies in oyster shells can provide information about contaminants and seasonal variations in the estuarine environment.     

The effect of a topographic high on the morphological stability of a two-inlet bay system

The cross-sectional stability of two tidal inlets connecting the same back-barrier lagoon to the ocean is investigated. The condition for equilibrium is the cross-sectional area tidal prism relationship. In an earlier study [Van de Kreeke, J., 1990. Can multiple inlets be stable? Estuarine, Coastal and Shelf Science 30: 261–273.], using the same equilibrium condition, it was concluded that where two inlets connect the same basin to the ocean ultimately one inlet will close. One of the major assumptions in that study was that the water level in the basin fluctuated uniformly. In hindsight this assumption might be too restrictive. For example, in the Wadden Sea the back barrier lagoon consists of a series of basins, rather than one single basin, separated by topographic highs. These topographic highs limit but do not exclude the exchange of water between the sub-basins. For this reason in the present study, a topographic high in the form of a weir was added, separating the back-barrier lagoon in two sub-basins. The water level in the sub-basins, rather than in the back-barrier as a whole, is assumed to fluctuate uniformly. For this schematization the hydrodynamic equations are solved using a finite difference method. The results, together with the equilibrium condition, yield the equilibrium flow curve for each of the inlets. The intersections of the two equilibrium flow curves represent combinations of cross-sectional areas for which both inlets are in equilibrium. The stability of the equilibriums was investigated using a non-linear stability analysis resulting in a flow diagram. Calculations were carried out for different inlet and weir characteristics. Sinussoidal tides were the same for both inlets. The results show that for relatively large wetted cross-sectional areas over the topographic high, approaching the situation of a single basin, there are no combinations of inlet cross-sectional areas for which both inlets are in a stable equilibrium. This supports the conclusion in the earlier study. For relatively small wetted cross-sectional areas over the topographic high there is one set of stable equilibriums. In that case the two-inlet bay system approaches that of two single-inlet bay systems.     

Fundamental study for morphodynamic modelling: Sand mounds in oscillatory flows

Experiments on sand mounds in oscillatory flow, undertaken in controlled, large-scale laboratory conditions, have produced well-defined data sets for model comparison. Three bathymetries with different levels of submergence, including a surface-piercing case, were tested. The maximum slope was about 1:5.5. Sediment transport is due to bed load with ripple formation. The principal time-dependent bulk parameters are the vertical distance of the centre of gravity above the base and the volume of the mound. A semi-implicit finite-volume depth-averaged hydrodynamic model is used to drive morphodynamics, using van Rijn's sediment flux model generalized to take account of bed slope, and some justification is given for depth-averaged modeling in these conditions. Starting the model runs with the conditions at the end of the first cycle avoided initial atypical physical behaviour. In general good predictions were obtained with an angle of repose reduced from the standard value of about 30° for stationary beds to 15°. For these situations, morphodynamics was largely unaffected by a hydrodynamic roughness height in the range 2.5D₅₀ to 51D₅₀, with larger values accounting for ripple roughness. The reduced angle of repose may be physically expected with mobile beds but this specific value is only expected to be suited to this form of bed motion. In one case an exaggerated ripple formed near the top of the mound reducing agreement with experiment. For the submerged case with normal ripple structure excellent predictions were obtained. For the initially surface-piercing mound, the time of submergence was better predicted with a 30° angle of repose, presumably due to the prominent influence of the near stationary bed near the wet/dry interface, although long term predictions were better predicted with 15°. The occurrence of vortex shedding in the first cycle modeled was in agreement with experimental observation.     

On the energy dissipation of jacket type offshore platforms with different pile–leg interactions

In recent years, considerable amount of effort has been made to design earthquake resistant offshore structures in seismic active areas. In order to achieve this objective, all components of a typical structure should function properly to dissipate seismically-induced energy within the members. Among components of an offshore installation, braces are of significant importance as they contribute substantially to total energy dissipation of the structure. Buckling in compression and yielding in tension assist the process of energy absorption. Nevertheless, the functionality of braces is dependent upon their joints where joint-cans are included to avoid any brittle fracture and unpredicted failure mechanisms.In this paper, special attention is being paid to energy dissipation of jacket type offshore platforms with two different pile–leg interactions. A case study representing an offshore platform is studied both analytically and experimentally. Analytical models are validated step by step based on available experimental tests and observations on individual members. Several parameters such as cyclic behavior, maximum bearing load and most importantly energy dissipation of two different 2D frames are investigated. Results provide promising insights into design and fabrication of fixed platforms with different pile–leg interactions.     

A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.     

Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.     

The Optimal Design of TMD for Offshore Structures

This paper presents the optimal design procedure of Tuned Mass Damper(TMD)for re-ducing vibration of an actual steel jacket offshore platform excited by random wave loading.In this study,a frequency domain is taken.The force on the structure is determined by use of the linearized Morisonequation for an input Power Spectral Density(PSD)of wave elevation.The sensitivity of optimum valuesof TMD to characteristic parameters of random wave spectrum is analyzed.An optimized TMD designfor the modeled platform is given based on design conditions and the findings of the study.     

Factors governing abundance of hydrolyzable amino acids in the sediments from the N.W. European Continental Margin (47–50°N)

Fifty-six samples representing 6 sediment cores taken along the N.W. European Continental Margin from the shelf, slope and abyssal plain of the Goban Spur and Meriadzek Terrace were quantitatively analysed for total hydrolyzable amino acids (THAA) and clay minerals. In descending order, the five most abundant amino acids making up more than 70% of the total were: aspartic acid, glycine, serine, alanine and glutamic acid. Clay mineral proportions were typical for the N.E. Atlantic, in order of descending abundance: illite, kaolinite, chlorite, smectite and mixed layers.The Meriadzek Terrace area is characterised by fine grain suspension sedimentation with a low pelagic carbonate input and the lowest content of THAA. In contrast, the Goban Spur transect is characterised by much higher carbonate inputs and more vigorous hydrodynamics as judged from granulometry and the high abundance of minerals of shelf and continental origin and a generally higher THAA content. The pelagic portion of THAA deposited at the sea floor is more readily mineralised during early diagenesis than the more ‘refractory', clay mineral-associated continental portion. Along this margin the average mineralization of THAA down to 25 cm in the sediment is about 54%. There is a significant affinity between chlorites and amino acids which we suggest may involve the formation of ionic bonds between the octahedral layers of the clay and the amino acids.     

In situ velocity profiles in gassy sediments: Kiel Bay

Acoustic behavior of gas-bearing sediments is significantly different from that of gas-free sediments. In situ velocity profiles and acoustic signal characteristics in gas-bearing sediments of the upper several meters of the sea floor in Kiel Bay are presented in this study. Observed velocities in gas-bearing sediments are both higher and lower than those of the gas-free sediments. Small amounts of gas appear to cause signal reverberation without much attenuation. whereas large amounts of gas cause substantial attenuation.