GEOCHEMICAL RECOGNITION OF SPILLED SEDIMENTS USED IN NUMERICAL MODEL VALIDATION

A fixed link (tunnel and bridge, in total 16 km) was constructed between Sweden and Denmark during 1995-2000. As part of the work, approximately 16 million tonnes of seabed materials (limestone and clay till) were dredged, and about 0.6 million tonnes of these were spilled in the water. Modelling of the spreading and sedimentation of the spilled sediments took place as part of the environmental monitoring of the construction activities. In order to verify the results of the numerical modelling of sediment spreading and sedimentation, a new method with the purpose of distinguishing between the spilled sediments and the naturally occurring sediments was developed. Because the spilled sediments tend to accumulate at the seabed in areas with natural sediments of the same size, it is difficult to separate these based purely on the physical properties. The new method is based on the geo-chemical differences between the natural sediment in the area and the spill. The basic propertiesused are the higher content of calcium carbonate material in the spill as compared to the natural sediments and the higher Ca/Sr ratio in the spill compared to shell fragments dominating the natural calcium carbonate deposition in the area. The reason for these differences is that carbonate derived from recent shell debris can be discriminated from Danien limestone, which is the material in which the majority of the dredging took place, on the basis of the Ca/Sr ratio being 488 in Danien Limestone and 237 in shell debris. The geochemical recognition of the origin of the sediments proved useful in separating the spilled from the naturally occurring sediments. Without this separation, validation of the modelling of accumulation of spilled sediments would not have been possible. The method has general validity and can be used in many situations where the origin of a given sediment is sought.     

Aklimaite, Ca4[Si2O5(OH)2](OH)4 · 5H2O, a new natural hydrosilicate from Mount Lakargi, the Northern Caucasus, Russia

A new mineral aklimaite, Ca₄[Si₂O₅(OH)₂](OH)₄ · 5H₂O, has been found near Mount Lakargi, Upper Chegem caldera, Kabardino-Balkaria, the Northern Caucasus, Russia, in the skarnified limestone xenolith in ignimbrite. This hydrothermal mineral occurs in a cavity of altered larnite skarn and is associated with larnite, calcium humite-group members, hydrogarnets, bultfonteinite, afwillite, and ettringite. Aklimaite forms transparent, colorless (or occasionally with pinkish tint) columnar or lath-shaped crystals up 3 × 0.1 × 0.01 mm in size, flattened on {001} and elongated along {010}; they are combined in spherulites. The luster is vitreous; the cleavage parallel to the {001} is perfect. D _calc = 2.274 g/cm³. The Mohs’ hardness is 3–4. Aklimaite is optically biaxial, negative, 2V _meas > 70°, 2V _calc = 78°, α = 1.548(2), β = 1.551(3), γ = 1.553(2). The IR and Raman spectra are given. The chemical composition (wt %, electron microprobe) is as follows: 0.06 Na₂O, 0.02 K₂O, 45.39 CaO, 0.01 MnO, 0.02 FeO, 24.23 SiO₂, 0.04 SO₃, 3.22 F, 27.40 H₂O_(calc.), ?1.36 -O=F₂; the total is 99.03. The empirical formula calculated on the basis of 2Si apfu with O + OH + F = 16 is as follows: (Ca_4.02Na_0.01)_Σ4.03[Si_2.00O_5.07(OH)_1.93][(OH)_3.16F_0.84] _Σ4.00 · 5H₂O. The mineral is monoclinic, space group C2/m, a = 16.907(5), b = 3.6528(8), c = 13.068(4) Å, β = 117.25(4)·, V= 717.5(4) ų, Z = 2. Aklimaite is representative of the new structural type, the sorosilicate with disilicate groups [Si₂O₅(OH)₂]. The strongest reflections in the X-ray powder patterns [d, Å (hkl)] are: 11.64(100)(001), 2.948(32)(310, 203), 3.073(20) ( $\bar 404$ , $\bar 311$ ), 2.320(12)(005, 510), 2.901 (11)(004), 8.30(10) $\left( {\bar 201} \right)$ . The type specimen is deposited in the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow.     

Bedrock morphology and structures within overlying sediments,Start Bay,Southwest England,determined by continuous seismic profiling,side-scan sonar,and core sampling

The bedrock morphology of Start Bay, Southwest England, and the Structures within overlying sediments have been determined by a combined geophysical and geological survey. It has been established that the Skerries Bank consists of a drape of possibly coarse, unconsolidated material (bank deposits) overlying medium- to fine-grained silty sand (bay deposits). A break of slope in the bedrock surface, traced along the entire length of the Bay, and a step profile in the southern part of the Bay, may be either a legacy of submerged topography produced by vigorous tidal action, or alternatively the product of subaerial and marine processes. Other significant geological features in the Bay include infilled valleys, and “terraces” possibly pertaining to relict barrier beaches.     

Lagrangian measurements and modelling of fluid advection in the inner surf and swash zones

New laboratory and field data are presented on fluid advection into the swash zone. The data illustrate the region of the inner surf zone from which sediment can be directly advected into the swash zone during a single uprush, which is termed the advection length. Experiments were conducted by particle tracking in a Lagrangian reference frame, and were performed for monochromatic breaking waves, solitary bores, non-breaking solitary waves and field conditions. The advection length is normalised by the run-up length to give an advection ratio, A, and different advection ratios are identified on the basis of the experimental data. The data show that fluid enters the swash zone from a region of the inner surf zone that can extend a distance seaward of the bore collapse location that is approximately equal to half of the run-up length. This region is about eight times wider than the region predicted by the classical swash solution of Shen and Meyer [Shen, M.C., Meyer, R.E., 1963. Climb of a bore on a beach. Part 3. Runup. Journal of Fluid Mechanics 16, 113–125], as illustrated by Pritchard and Hogg [Pritchard, D., Hogg, A.J., 2005. On the transport of suspended sediment by a swash event on a plane beach. Coastal Engineering 52, 1–23]. Measured advection ratios for periodic waves show no significant trend with Iribarren number, consistent with self-similarity in typical swash flows. The data are compared to recent characteristic solutions of the non-linear shallow water wave (NLSW) equations and both finite difference and finite volume solutions of the NLSW equations.     

Incrustations and fumarolic condensates at kilauea volcano, Hawaii: field, drill-hole and laboratory observations

Hawaiian volcanoes characteristically have but few of the many types of minerals found in incrustations of other volcanic areas. In Hawaii sulfates resulting from air oxidation of volatiles predominate, and fluorides produced during rock alteration by fumarolic gases are prominent. Halides are generally found where reducing conditions exist in fumaroles and lava lake drill holes. The most common mineral types are sulfur, opaline silica, gypsum, ralstonite, and thenardite. Minerals from the same deposit are found to vary markedly in the content of the less abundant components. Condensates from vapor issuing from fumaroles show little quantitative relationship in component content to incrustations deposited at the same fumaroles. It is believed that an energetically favorable isomorphic substitution of some elements in the crystal lattice of a depositing mineral may lead to the build-up of a high concentration of an element from a lean vapor. Equilibrium calculations applied to condensate studies give a good quantitative approximation to the concentrations of the elements found in natural systems, but when applied to incrustations they serve only to indicate general compositional relations. Laboratory studies have shown the important role of chlorides in metal transfer in the gas phase in high-temperature aqueous systems, but only in the absence of oxygen. These studies also demonstrated the important role of HF in rock alteration and in the transfer of silica.     

Variations in statistical parameters of the <Emphasis Type="Italic">NmF</Emphasis>2 winter anomaly with latitude and solar activity

The maximal R ratios of the winter-to-summer NmF2 values of each ionosonde are calculated for a specified UT under daytime quiet geomagnetic conditions and at approximately equal levels of solar activity, based on foF2 measurement data of 98 ionosondes at mid- and low geomagnetic latitudes of the Northern and Southern hemispheres for 1957–2009. The P(R > 1) conditional probability of NmF2 winter anomaly observations, as well as the most probable RMP and average <R> of R values are calculated for low, moderate, and high solar activity on the base of foF2 measurements during the periods December 22 ± 30 days and June 21 ± 30 days. Variations in P(R > 1), RMP, and 〈R〉 with latitude and solar activity are analyzed.     

Storm surge mitigation through vegetation canopies

The paper of Reid and Whitaker (1976) on the effects of a vegetation canopy on flow of water is re-examined. Their assumptions on the equality of various drag coefficients are replaced by more realistic calculations. A new method for calculating wind stress on water is presented for the case when the vegetation extends above the water surface.For the case of vanishingly small water depth, it is shown that the horizontal stress is approximately constant in the vertical. This results in a diagnostic relationship for the water current as a function of the wind stress and bottom roughness.A new expression for the vertically averaged frictional force per unit mass is derived on the assumption that the friction velocity varies linearly with height. The vertical rate of change of friction velocity depends on the mean water current, the wind stress, the bottom roughness, and the water depth. This work has a possible application in the mitigation of storm surges.     

The Eastern Congo—a beauty spot,rediscovered from a geological point of view

In East Africa, the feedback between tectonic uplift, erosional denudation and associated possible climate changes is being studied by a multidisciplinary research group, ‘Riftlink’. The group's focus is the Albertine Rift, the northern part of the western branch of the East African Rift System, and in particular the rising Rwenzori Mountains that stretch along the border of the D.R. Congo and Uganda. Major questions relate to the timing of the formation of the Rwenzori Mountains, and whether the height of these mountains (> 5000 m) relates to rift movements in Neogene times, or represents an old basement block that formed a topographic high long before. Though, at first, research concentrated on the eastern (Ugandan) part of the Albertine Rift and Rwenzori Mountains, it has now moved further to the west to the D.R. Congo. A first field‐campaign, covering the area from northern Lake Edward along the rift shoulder up to the Blue Mountains at Lake Albert, was conducted in summer 2009, in cooperation with the Ruwenzori State University of Butembo. Here, we present a brief overview of the field‐campaign, with impressions gathered on the morphology and geology of the study area.     

Estimation of unrecorded groundwater abstractions in Jordan through regional groundwater modelling

Jordan suffers from water scarcity and groundwater covers the majority of Jordan’s water supply. Therefore, there is an urgent need to manage this resource conscientiously. A regional numerical groundwater flow model, developed as part of a decision support system for the country of Jordan, allows for quantification of the overexploitation of groundwater resources and enables determination of the extent of unrecorded agricultural groundwater abstraction. Groundwater in Jordan is abstracted from three main aquifers partly separated by aquitards. With updated geological, structural, and hydrogeological data available in the country, a regional numerical groundwater flow model for the whole of Jordan and the southernmost part of Syria was developed using MODFLOW. It was first calibrated for a steady-state condition using data from the 1960s, when groundwater abstraction was negligible. After transient calibration using groundwater level measurements from all aquifers, model results reproduce the large groundwater-level declines experienced in the last decades, which have led to the drying out of numerous springs. They show a reversal of groundwater flow directions in some regions, due to over-abstraction, and demonstrate that documented abstractions are not sufficient to cause the observed groundwater-level decline. Only after considering irrigation water demand derived from remote sensing data, the model is able to simulate these declines. Illegal abstractions can be quantified and predictive scenarios show the potential impact of different management strategies on future groundwater resources.

     

A computer program for interpreting vertical magnetic anomalies of spheres and horizontal cylinders

Summary A common computer program for the interpretation of vertical magnetic anomalies of spheres and horizontal cylinders has been developed. The input consists of the observed anomalies noted against their distances measured from an arbitrary point in the profile and a code number for each model. The program is written so that the positions and magnitudes of the maximum and minimum anomalies are located and their ratios and signs are used to define the initial parameters of the model under consideration. The errors resulting from these approximate values are derived and are solved for the increments to be given to the initial values. The process is repeated until the sum of the squares of the errors is less than 0.25% of the sum of the squares of the observed anomalies. The method has been tested on various theoretical examples and the results justify the validity of the programme.