Hanford tank residual waste – Contaminant source terms and release models

Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy’s Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2–29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt.%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U–Na–C–O–P ± H phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)₂-saturated solution, or a CaCO₃-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO₃-saturated solution than with the Ca(OH)₂-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)₂-saturated solution than by the CaCO₃-saturated solution. In general, Tc is much less leachable (<10 wt.% of the available mass in the waste) than previously predicted. This may be due to the coprecipitation of trace concentrations of Tc in relatively insoluble phases such as Fe oxide/hydroxide solids.     

Fe3+ in shocked olivine crystals of the ALHA 77005 meteorite

ALHA 77005, a shocked achondrite of the shergottite group, is unique in containing cumulus olivine crystals which display a brownish color in thin section. Mössbauer, EPR, and optical spectroscopic studies show the presence of Fe³⁺ in the olivine. Approximately 4.5 wt.% of the total iron in the olivine (24 wt.% as FeO) is in the trivalent state. The Fe³⁺ ions preferentially occupy M2 lattice positions. Charge transfer between Fe³⁺ and Fe²⁺ as well as between Fe³⁺ and oxygen ligands causes a broad absorption band in the optical spectrum at high energies which is the reason for the olivine color. It is concluded that the color of the ALHA 77005 olivine is preterrestrial and may be the result of shock-induced oxidation of the olivine crystals on the meteorite parent body.     

TRACING BY GRAVITY OF A NARROW BURIED GRABEN STRUCTURE,DETECTED BY SEISMIC REFRACTION,FOR GROUND-WATER INVESTIGATIONS IN NORTH CHILE*

In the Andes mountains of North Chile seismic refraction measurements revealed the existence of a buried graben structure. The special geological environment permitted the deduction, by detailed analyses of diffraction patterns and delayed arrival times, of a low velocity layer underneath a high velocity ignimbritic sheet. The gravity method was chosen as an economic secondary aid to trace the course of the buried structure. This unusual combination of detailed gravity measurements following a general seismic survey was not only successful in detecting and tracing a buried structure, but also provided complementary data about the deeper subsurface conditions.     

The British Tertiary igneous province: palaeomagnetism of the dyke swarm along the Sleat coast of Skye

Summary. A palaeomagnetic investigation has been made of a swarm of more than 400 dykes along the south coast of Skye, Scotland, by the Sound of Sleat.
Seven red lamprophyre dykes have palaeomagnetic directions inconsistent with Tertiary age, and not inconsistent with their previously held Caledonian age. The remaining 409 dykes have palaeomagnetic directions that are consistent with a Lower Tertiary age. We present evidence suggesting that the Tertiary dykes might have been emplaced during a short time, over which the geomagnetic polarity occupied as few as three polarity intervals (NRN or RNR).
Certain 'intermediate' directions of magnetization have also been found, and are presented here.     

Effects of grazing by Daphnia on algal carotenoids: Implications for paleolimnology

Reverse-phase thin layer chromatography was used to quantify algal carotenoid degradation resulting from grazing by Daphnia magna in suspensions of lyophilized Oscillatoria utermöhlii, O. limnetica, Anabaena flos-aquae and Synechococcus sp. Three samples were removed every 24 h from 0 h to 144 h and the carotenoid, carbon and nitrogen content of the remaining algal-fecal mixture was determined. Grazing by Daphnia reduced carotenoid concentrations by 30%–80% after 144 h, with myxoxanthophyll being the most labile pigment in experiments with filamentous cyanophytes. However, as a group, the carotenoids were more resistant to the combined effects of grazing by Daphnia and bacterial action than were particulate algal carbon (78% to 82% lost by 144 h) or nitrogen (86%–90%) during the period in which easily digestible material remained. The maximal extent of carotenoid enrichment relative to particulate carbon ranged from 150% to 300% of initial pigment concentrations but declined with repeated coprophagy. On the basis of these results and published pigment budgets, we conclude both that fecal transportation of pigments may be an important determinant of carotenoid accumulation rates and that carotenoid stratigraphies should record predator-mediated changes in zooplankton community structure, especially in oligotrophic conditions.     

Saturn's electrostatic discharges: Could lightning be the cause?

It is proposed that Saturn's electrostatic discharges (SED) might be generated in the planet's equatorial atmosphere, perhaps as lightning from a storm system. The 10^h10^m periodicity of the signal envelope duplicates that of Saturn's equatorial jet. The rings shield the atmosphere from solar EUV photons, and thereby substantially reduce the local ionospheric cutoff frequency to allow low-frequency SED to leak out. Many of the unusual properties of SED could be explained in terms of changes in the storm system, the relative spacecraft position in the beaming pattern of the source, local refraction of the signal by the highly disturbed ionosphere, and the influence of the ring particles on the highest frequency component of SED. A comparison of SED with planetary lightning on other planets shows that the two are similar in general character and some time behavior; the power output of SED may be higher than most planetary lightnings but that is unclear because of uncertainties in the measurements and variations in the signal's spectrum. Our simple discussion suggests that lightning could be a viable source for SED and that exotic ring mechanisms are not necessarily required.