用于地质研究的质谱计

由于高精度质谱计的使用范围日益扩大及其可靠性的不断增长,使一些地质问题的研究方法有了新的重大发展。这些方法的重要性日益增加,目前已为质谱计的应用提供了主耍的场所。在地球化学中有三个经常碰到的问题,即放射性测定年龄、研究非放射成因的同位素丰度变异及分析微量元素,它们都需要相当专门性质的质谱技术。例如,在地质年代学研究中使用的仪器,要求在小质量范围内,重复测量结果的偏差不大于千分之几;而许多丰度变异的研究,要求偏差要在万分之一左右。本文从较为专门     

PROGRAM FOR PROCESSING OF HISTORICAL LABORATORY DATA BASED ON FUZZY SET THEORY AS A TOOL FOR DECISION SUPPORT

A computer program(FEA)is presented for processing historical laboratory data.It performs on a list ofsample entries stored in a laboratory information management system.Using an algorithm which is basedon fuzzy set theory,FEA classifies the entries into a limited number of clusters called sample types.Theclassification is fully user-defined.The program transforms the historical data into a representation whichis more suitable for studying the performance of the laboratory or which can be used as preparation for asimulation project.     

Contaminant concentrations in sport fish from San Francisco Bay, 1997

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.     

Effects of antifouling paint components (TBTO,copper and triazine) on the early development of embryos in cod (Gadus morhua L.)

To assess the risk of antifoulant use to the commercially important cod (Gadus morhua L.), fertilised cod eggs were exposed to triazine, copper and TBTO singly or combined in laboratory tests with running seawater. At the highest tested concentrations (11.5 microg Cu l(-1); 5 microg TBTO l(-1)) larval mortality was increased. The highest concentration of triazine (40 microg l(-1)) did not cause any significant mortality. Fertilised eggs that had been exposed to all the three chemicals singly for five days showed a higher buoyancy than the controls. No synergistic or antagonistic effects were indicated. Embryos/larvae exposed to 0.004-0.8 microg TBTO l(-1) did not show any changed respiration compared to the controls after hatching. It is concluded that existing known field concentrations of the three antifoulants are hardly expected to cause detectable effects on fish embryonic/larval development.     

Assessment of potential transport of pollutants into the Barents Sea via sea ice--an observational approach

The present estimates of ice drift in the Arctic include utilization of satellite imagery data (special sensor microwave/imager) and a reconstruction of air pressure for the period 1899-1998. A significant part of the sea ice in the Arctic Ocean has its origin in the Kara Sea and melts in the Greenland and the Barents Sea (BS). Consequently there may be a particular risk of pollutants in the Kara Sea entering the food webs of the Greenland and BS. The ice export from the Kara Sea between 1988 and 1994 was about 208,000 km2 (154 km3) per year. The import of ice into the BS was during the same period 161,000 km2 (183 km3) per year while the ice drift through the Fram Strait into the Greenland Sea was 583,000 km2 (1859 km3) per year. Ice which formed adjacent to the Ob and Yenisey rivers in early January, drifted into the BS within two years (with a probability of about 50%.