Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite

The solubility of synthetic ZnS_(cr) was measured at 25–250 °C and P = 150 bars as a function of pH in aqueous sulfide solutions (~ 0.015–0.15 m of total reduced sulfur). The solubility determinations were performed using a Ti flow-through hydrothermal reactor. The solubility of ZnS_(cr) was found to increase slowly with temperature over the whole pH range from 2 to ~ 10. The values of the Zn–S–HS complex stability constant, β, were determined for Zn(HS)₂⁰_(aq), Zn(HS)₃^?, Zn(HS)₄^2?, and ZnS(HS)^?. Based on the experimental values the Ryzhenko–Bryzgalin electrostatic model parameters for these stability constants were calculated, and the ZnS_(cr) solubility and the speciation of Zn in sulfide-containing hydrothermal solutions were evaluated. The most pronounced solubility increase, about 3 log units at m(S_total) = 0.1 for the temperatures from 25 to 250 °C, was found in acidic solutions (pH ~ 3 to 4) in the Zn(HS)₂⁰_(aq) predominance field. In weakly alkaline solutions, where Zn(HS)₃^? and Zn(HS)₄^2? are the dominant Zn–S–HS complexes, the ZnS_(cr) solubility increases by 1 log unit at the same conditions. It was found that ZnS(HS)^? and especially Zn(HS)₄^2? become less important in high temperature solutions. At 25 °C and m(S_total) = 0.1, these species dominate Zn speciation at pH > 7. At 100 °C and m(S_total) = 0.1, the maximum fraction of Zn(HS)₄^2? is only 20% of the total Zn concentration (i.e. at pH_t ~ 7.5), whereas at 350 °C and 3 <pH_t <10, the fraction of Zn(HS)₄^2? and ZnS(HS)^? is less than 0.05% and 2.5% respectively, of the total Zn concentration and Zn(HS)₂⁰ and Zn(HS)₃^? predominate. The measured equilibrium formation constants were combined with the literature data on the stability of Zn–Cl complexes in order to evaluate the concentration and speciation of Zn in chloride solutions. It was found that at acidic pH, and in more saline fluids having total chloride > 0.05 m, Zn–Cl complexes are responsible for hydrothermal Zn transport with no significant contribution of Zn–S–HS complexes. The hydrosulfide/sulfide complexes will play a more important role in lower salinity (< 0.05 m chloride) hydrothermal solutions which are characteristic of many epithermal ore depositing environments. The value of Δ_fG° (β-ZnS_(cr)) = ? 198.6 ± 0.2 kJ/mol at 25 °C was determined via solubility measurements of natural low-iron Santander (Spain) sphalerite.     

Laboratory and field investigations of rockburst phenomena using concurrent geotomographic imaging and acoustic emission/microseismic techniques

The progress made on three phases of a research project, started in 1986 to investigate mining induced seismicity/rockburst phenomena using concurrent geotomographic imaging and microseismic monitoring techniques, is described. Phase I is the geotomographic software development and laboratory calibration trials. Phase II is the enhancement of traditional microseismic monitoring instrumentation with a waveform acquisition system, so that source mechanism studies can be carried out on mining induced seismic events. Phase III is the field trials of the hybrid technique which will be used to monitor changing rock mass physical properties, in response to mining. Preliminary results from all three phases are given, together with an outline of current and future research planned.Presented at the Fred Leighton Memorial Workshop on Mining Induced Seismicity, Montreal 1987.     

Underwater sounds near a fuel receiving facility in western Hong Kong: relevance to dolphins

Western Hong Kong is home to two species of marine mammals: Indo-Pacific humpbacked dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides). Both are threatened in many parts of their range in southeast Asia [for example, International Biological Research Institute Reports 9 (1997), 41; Asian Marine Biology 14 (1997) 111]. In 1998, when the new Hong Kong International Airport opened in western Hong Kong, small tankers (about 100 m long, cargo capacity about 6300 metric tons) began delivering fuel to the Aviation Fuel Receiving Facility (AFRF) just off Sha Chau Island, north of the airport. Calibrated sound recordings were taken over a 4-day period from a quiet, anchored boat at distances 80-2000 m from aviation fuel delivery activities at the AFRF. From the recordings, 143 sections were selected for analysis. Narrowband spectral densities on the sound pressures were computed, and one-third octave band levels were derived for center frequencies from 10 to 16,000 Hz. Broadband levels, viz. 10-20,000 Hz. were also computed. The results showed that the Sha Chau area is normally noisy underwater, with the lowest broadband levels measured corresponding to those expected during a storm at sea (sea state 6). This background noise is believed to come largely from heavy vessel traffic in the Urmston Road to the north and east of Sha Chau and from vessels in the Pearl River Estuary to the West. The sound levels from the AFRF tankers are comparable to the levels measured from similar- and smaller-sized supply vessels supporting offshore oil exploration. The strongest sounds recorded were from a tanker leaving the AFRF at distance 100 m from the hydrophone, for which the one-third octave band level at 100 Hz was 141 dB re 1 microPa (spectrum level 127 dB re 1 microPa2/Hz) and the 10-20,000 Hz broadband level was 146 dB. At distances of 100 m or more and frequencies above 300 Hz, the one-third octave band levels were less than 130 dB (spectrum level 111 dB re 1 microPa2/Hz) and decreased with increasing frequency and distance. At distances greater than about 500 m, AFRF-associated sounds were negligible, masked by the generally high noise level of the area and attenuated by poor transmission in the very shallow water (<10 m). Because it is believed that humpbacked dolphins and finless porpoises are not very sensitive to sounds below 300 Hz, the Airport Authority Hong Kong (AA) stipulated that dedicated terminal vessels not radiate underwater sounds at spectrum levels greater than 110 dB re 1 microPa2/Hz at frequencies above 300 Hz and distances greater than 300 m. The spectrum levels at 300 Hz and higher frequencies of sounds from the tankers arriving, departing, or off-loading at AFRF were less than 110 dB re 1 microPa2/Hz even at distances of 200 m or less. The AA stipulation was met. However, it is presently unknown whether the generally strong noise levels of western Hong Kong inhibit acoustically based feeding and communication, or result in increased stress or permanent shifts in hearing thresholds.     

Transient soil response in a porous seabed with variable permeability

The soil permeability of many natural marine sediments decreases with depth because of consolidation under overburden pressure. This is accompanied by a decrease in porosity and void ratio that also affect the permeability. Conventional theories for wave-induced soil response have assumed a homogeneous porous seabed. This paper presents a new approach for the wave-induced response in a soil matrix, with variable permeability as a function of burial depth. The soil matrix considered is unsaturated and anisotropic, and is subject to a three-dimensional wave system. The pore pressure and effective stresses induced by such a system are obtained from a set of equations incorporating a variable permeability. Verification is available through reduction to the simple case of uniform permeability. The results indicate that the effect of variable soil permeability on pore pressure and vertical effective stress may be significant, especially in a gravelled seabed and for unsaturated sandy soils.     

Options to overcome the barriers to pricing European agricultural emissions

Although agriculture could contribute substantially to European emission reductions, its mitigation potential lies untapped and dormant. Market-based instruments could be pivotal in incentivizing cost-effective abatement. However, sector specificities in transaction costs, leakage risks and distributional impacts impede its implementation. The significance of such barriers critically hinges on the dimensions of policy design. This article synthesizes the work on emissions pricing in agriculture together with the literature on the design of market-based instruments. To structure the discussion, an options space is suggested to map policy options, focusing on three key dimensions of policy design. More specifically, it examines the role of policy coverage, instruments and transfers to farmers in overcoming the barriers. First, the results show that a significant proportion of agricultural emissions and mitigation potential could be covered by a policy targeting large farms and few emission sources, thereby reducing transaction costs. Second, whether an instrument is voluntary or mandatory influences distributional outcomes and leakage. Voluntary instruments can mitigate distributional concerns and leakage risks but can lead to subsidy lock-in and carbon price distortion. Third, the impact on transfers resulting from the interaction of the Common Agricultural Policy (CAP) with emissions pricing will play a key role in shaping political feasibility and has so far been underappreciated.

POLICY RELEVANCE

Following the 2015 Paris Agreement, European climate policy is at a crossroads. Achieving cost-effectively the 2030 and 2050 European targets requires all sectors to reduce their emissions. Yet, the cornerstone of European climate policy, the European Union Emissions Trading System (EU ETS), covers only about half of European emissions. Major sectors have been so far largely exempted from carbon pricing, in particular transport and agriculture. While transport has been increasingly under the spotlight as a possible candidate for an EU ETS sectoral expansion, policy discussions on pricing agricultural emissions have been virtually absent. This article attempts to fill this gap by investigating options for market-based instruments to reduce agricultural emissions while taking barriers to implementation into account.     

Palynology suggests hydrocarbon mobilization in Ordovician of Kasba Tadla Basin,Morocco

Palynological analysis of twelve wells shows that the metamorphic gradient of the pre-Mesozoic in the Kasba Tadla Basin of Morocco increases rapidly northwest-, southeast-, and eastward, from the center of the Basin. In the center, the Ordovician may still be releasing mobile hydrocarbons.

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Zusammenfassung Eine palynologische Untersuchung von zwölf Bohrungen zeigt, daß der thermale Gradient sich im Premesozoikum des Kasba-Tadla-Beckens in Marokko vom Zentrum des Beckens aus nach Nordwesten, Südosten und Osten schnell vergrößert. Es ist sehr wohl möglich, daß das Ordovizium des Beckenzentrums noch flüssige und gasförmige Kohlenwasserstoffverbindungen abgibt.

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Résumé L'analyse palynologique de 12 sondages montre que le gradient métamorphique du pré-Mésozoïque dans le Basin du Kasba Tadla, au Maroc, augmente à partir du centre du Bassin vers le nordouest, le sudest et vers l'est. Il est possible que l'Ordovicien de la partie centrale du Bassin produise encore des hydrocarbures liquides et gaseux.

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12 , Kasba Tadla -, - . , .

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The authors gratefully acknowledge support of this project through Grant GF-32510-X from the National Science Foundation, Washington, D.C., U.S.A.     

Two acoustic surveys of pelagic fish in Hawke Bay,New Zealand, 1980

The design and execution of two acoustic surveys of Hawke Bay in February and September/October 1980 are described. Though the resulting acoustic data were, for technical reasons, of limited value, they illustrate the information which may be drawn from acoustic surveys. Fish distributions may be rapidly mapped, not only by area, but throughout most of the water column and over time. Qualitative observations on fish distribution may be quantified. The estimation of variance in acoustic surveys is discussed in detail with particular emphasis on the problems of systematic surveys. The role of replicate observations is stressed. Coefficients of variation for relative fish density estimates from the two surveys probably lie between 5 and 30%.     

A shipborne magnetic survey in Hudson Bay

A marine magnetic total-field survey of Hudson Bay was conducted from 1975 to 1978. Approximately 62 000 line-km of data, or 35 000 five-minute averages, were acquired. The data were corrected for secular variation by means of a polynomial in latitude, longitude, and time, first fitted to annual mean differences from nine observatories and then integrated over time. The data were corrected for diurnal and transient variations by means of a linear interpolation, over geomagnetic latitude, of running hourly mean values from two neighbouring magnetic stations (numbering seven in all). Crossover differences are analysed in terms of a mixture of normal distributions resulting from the intermittent transient variations, and indicate the effectiveness of the corrections. The variance of the data is reduced, as a result of the corrections, by 87% during quiet periods and by 53% during disturbed periods, the weighted variance being reduced by 66%. Navigational accuracy is estimated, from a novel method utilizing crossover differences and field gradients, to be approximately 300 m. Anomalies are presented in profile form, and discussed briefly.Contribution from the Earth Physics Branch No. 973.     

Gravity results from the continental margin of south-western Africa

Gravity, magnetic and bathymetric data were collected over the continental margin of south-western Africa by H.M.S. Hecla in 1966. A study of the gravity measurements shows that the positive free-air anomalies of the continental edge effect are unusually large, and in excess of those calculated for an isostatic model of the Earth's crust. Taking into account the available seismic and magnetic evidence, a two-dimensional crustal model has been designed incorporating a body of relatively high density in the upper crust to account for the unusually large values.