Geomorphological and sedimentological comparison of fluvial terraces and karst caves in Zhangjiajie,northwest Hunan,China: an archive of sandstone landform development

The Zhangjiajie Sandstone Peak Forest Geopark (Zhangjiajie World Geopark) of northwest Hunan, China hosts a well-preserved sequence of fluvial terraces and karst caves. In this contribution, a comparative study of fluvial terraces with karst caves along the middle-lower Suoxi River in Zhangjiajie World Geopark is presented to improve the understanding of the development of striking sandstone landscape in the upper Suoxi River. By integrating geomorphological, sedimentological, and geochronological techniques, the possible correlation between fluvial terraces and karst caves, as well as their climatic and tectonic implications is investigated. The available electron spin resonance and thermo-luminescence numerical ages coupled with morphostratigraphic analysis indicate that aggradation of fluvial terrace levels occurred at ca. 347 ± 34 ka (T₄), 104.45 ± 8.88 to 117.62 ± 9.99 ka (T₃), 60.95 ± 5.18 ka (T₂), and Holocene (T₁), followed by the stream incision. Fluvial terrace levels (T₄ to T₁) correlate morphologically with the karst cave levels (L₁ to L₄), yet the proposed chronology for the fluvial terrace levels is a bit later than the chronological data obtained from karst caves. In northwest Hunan, where a unique sandstone peak forest landscape was extensively developed, the fluvial terrace sequences as well as the cave systems are the important archives for studying the evolution of the sandstone landscape. The beginning of the sandstone landscape development must be earlier than the aggradation of the fluvial terrace T₄, allowing this unique landscape to occur in the Middle Pleistocene.     

大型地下洞室对穿预应力锚索失效形式与耦合模型

以锦屏二级水电站地下厂房与主变室之间中隔墙的多根对穿预应力锚索失效实例为背景,首先总结对穿预应力锚索失效的多种现场表现形式,采用现场取证和室内试验再现的方式论证锚索钢绞线断裂的拉破坏模式。将对穿锚索视为弹脆性体,被锚固围岩视为黏弹性体,提出描述对穿预应力锚索与被锚固围岩之间相互作用关系的锚索-围岩耦合元件模型,并据此分别阐明在洞室开挖卸荷阶段和围岩时效变形阶段中预应力锚索的力学响应机制和荷载变化规律。最后,在现场调研、室内试验和机制分析基础上,综合分析导致锦屏二级水电站地下厂房与主变室之间对穿锚索失效的主要原因,并探讨对穿预应力锚索与被锚固围岩之间对立统一的矛盾关系以及大型洞室群预应力锚索支护时机问题。     

Bioadsorption by sugarcane bagasse for the reduction in oil and grease content in aqueous effluent

Several techniques have been used to reduce the oil and grease content in aqueous streams; one excellent is bioadsorption. With a view to provide a sustainable method for the treatment of oily effluents, the aim of this study was to evaluate sugarcane bagasse as bioadsorbent to reduce the oil and grease content of aqueous effluents. Analysis of the material was performed, and the adsorption experiments were in a batch system, using a synthetic effluent. The results showed that the kinetic equilibrium occurred in 0.08 h of contact. The study of influence of pH of the aqueous phase and the temperature showed that the adsorption capacity was proportional to the pH value, but inversely proportional to the temperature. The adsorption isotherm was obtained at a temperature of 298.15 K using the Langmuir and Langmuir–Freundlich models, and the maximum adsorption capacity obtained was 6.65 kg of hydrocarbon per kg of bioadsorbent. It was verified that sugarcane bagasse represents an excellent material for application in the treatment of oily aqueous effluents, since it is associated with low cost and a high adsorption capacity. The variation in the adsorption capacity observed as a function of pH of the aqueous phase was not found to be significant. This is an important characteristic of the material in terms of its industrial application, verifying the possibility for its implementation in any treatment process, demonstrating the great potential of sugarcane bagasse for use as a sustainable alternative in the reduction in oil and grease in aqueous effluents.     

Impacts of climate change and human activities on the aboveground production in alpine grasslands: a case study of the source region of the Yellow River,China

Changes in aboveground net primary productivity (ANPP) in alpine grasslands are the consequence of climate change and human activities, but it is difficult to disentangle their relative contributions. Based on monthly remote-sensed vegetation index and meteorological data during the period 1982–2010, we analysed the long-term variation of annual ANPP in the source region of the Yellow River and quantified the effects of climate and human activities including grazing on ANPP variability, using the Carnegie–Ames–Stanford Approach (CASA) model and the ANPP-based residual trend analysis method. Our results suggested that ANPP increased in 80% of alpine grasslands. Areas with negative changes in ANPP were found mainly in the eastern portion of the region, accounting for 0.3% of alpine grasslands. ANPP was positively correlated with the monthly mean temperature from June to September and the sunshine duration in September at a regional scale. Moreover, ANPP was negatively correlated with the total livestock numbers. Using the residual trend analysis method, we demonstrated that climate and human activities accounted for 76.6 and 23.4%, respectively, of the variability in ANPP for the entire study region in 1982–2010. We concluded that climate change alleviated climatic constraints, in particular temperature limitations and sunshine duration, resulting in a significant increase in ANPP. Overgrazing was supposed to be the primary driver for grassland degradation in the eastern region. Our study has implications for grassland management and its sustainability to minimize the risk of grassland degradation and desertification processes in geo-ecologically and socially important regions such as the study region in China.     

Wind-Driven Dissolved Organic Matter Dynamics in a Chesapeake Bay Tidal Marsh-Estuary System

Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River.