Geochemistry of Late Mesozoic mafic dykes in western Fujian Province of China： Sr-Nd isotope and trace element constraints

The Bancun diabase dyke and the Bali hornblende gabbro dyke in western Fujian Province were emplaced in the Early and Late Cretaceous periods, respectively; the former is designated to calc-alkaline series and the latter to K-high-calc-alkaline rock series. Both the dykes are characterized by such geochemical characteristics as high Al and Na2O>K2O. As for the Bancun dyke, Al2O3=16.32%–17.54% and K2O/Na2O=0.65–0.77; as for the Bali dyke, Al2O3=16.89%–17.81% and K2O/Na2O=0.93–0.99. Both the Bancun and Bali mafic dykes are relatively enriched in LILE and LREE, but depleted in HSFE, displaying the geochemical characteristics of continental marginal arc, with high initial Sr isotopic ratios and low εNd (t) values. The (87Sr/86Sr)i ratios of the Bancun diabase dyke are within the range of 0.708556–0.70903 and their εNd (t) values vary between -6.8 and -6.3; those of the Bali hornblende dyke are within the range of 0.710726–0.710746 and their εNd (t) values are -4.7– -4.9, showing the characteristics of enriched mantle EM II. The isotope and trace element data showed that the mafic dykes have not experienced obvious crustal contamination, and metasomatism caused by subduction fluids is the main factor leading to LILE and LREE enrichments. The enriched mantle is the source region for the mafic dykes, and mixing of subduction fluid metasomatized enriched mantle and EM II-type mantle constituted the mantle source region of both the Bancun and Bali mafic dykes. Upwelling of the asthenosphere mantle provided sufficient heat energy for the generation of magmas. In accordance with the discrimination diagram of their tectonic settings as well as their trace element geochemical characteristics, it is considered that the dykes both at Bancun and Bali possess the characteristics of continental marginal arc, revealing the tectonic environment of formation of the mafic dykes, the continental dynamic background as an intraplate tensional belt in which the mafic dykes were emplaced. Meanwhile, it is also indicated that the tensional tectonic stress mechanism is responsible for the formation of the mafic dykes in western Fujian Province.     

天然矿物自然铝的研究进展

综述了国内外自然铝的发现与研究史;自然铝的物理性质和颗粒形态、元素组成及含量、晶体结构参数等特征;自然铝的成因模式。自然铝主要见于老的火山和热液矿石中,或现代和中-新生代的海底活动构造带（如转换断层、中央海隆以及弧后扩张中心）的海洋沉积物中,有地幔碳热还原、海底热液内生和陆地表生置换等3种成因模式。     

福建肖坂韧性剪切带型金矿特征及成因探讨

肖坂金矿处在闽中金矿化集中区内。矿床受元古界基性、酸性双峰式火山岩层位及韧性剪切带双重控制,属绿岩带中的韧性剪切带型金矿床。     

Cooling and exhumation of the oldest Sanqiliu uranium ore system in Motianling district,South China Block

The Sanqiliu uranium deposit belongs to a uranium ore system in Motianling district. It is the oldest uranium deposit in South China. Primary uranium mineralization occurred almost simultaneously with the emplacement of the host granites and subsequent dykes, and it has a relatively high grade of uranium (0.421%). We clarify the age of mineralization and investigate the cooling history through new pitchblende U–Pb and apatite fission‐track thermochronology. The pitchblende U–Pb results indicate that uranium mineralization occurred at ~801–759 Ma. Fractionation of uranium and lead at ~374–295 Ma is interpreted as remobilization and resetting of the original uranium. The Motianling area has apatite fission‐track ages of 57 to 18 Ma. By combining our results with previous work, we conclude that the deposit cooled slowly and was exposed at the surface during the Cenozoic. The timing and depth of exhumation helped to preserve and avoid erosion of the uranium deposit, and highlight the potential for regional uranium exploration.     

草桃背矿床白垩纪橄榄玄粗岩与铀成矿关系

赣南会昌断陷盆地沿石城-寻乌深断裂分布一条白垩纪橄榄玄粗岩系列的火山岩带。草桃背大型铀矿床内出露大富足岩体中-粗粒黑云母花岗岩及早白垩世晚期到晚白垩世早期橄榄玄粗岩系列火山岩。大富足花岗岩体岩石w(SiO₂)平均为74.67％,碱总量(w（K₂O+Na₂O）)平均为7.99％,w(K₂O)>w(Na₂O),w(CaO)平均为0.54％,w(Al₂O₃)>w(CaO+Na₂O+K₂O),属高钾钙碱性岩石系列。橄榄玄粗系列火山岩岩石w(SiO₂)为45.78 %~59.78 %,w(K₂O+Na₂O)平均为7.37%,K₂O/Na₂O平均为1.02,w(TiO₂)平均为0.86%, 全铁质量分数平均为7.09%,属偏碱性橄榄玄粗质火山岩类。草桃背铀矿床赋矿岩性为橄榄玄粗岩、碎裂花岗岩及隐爆角砾岩。赋存于碎裂花岗岩及隐爆角砾岩中铀矿石化学成分,与围岩花岗岩成分相似;赋存于橄榄玄粗岩中铀矿石,Fe₂O₃+Fe₂O、CaO、MgO不同程度地带出,w(SiO₂)明显增高,表明橄榄玄粗岩在成矿过程中,通过输出大量Fe、Mg、Ca等阳离子而促进铀离子从含矿溶液中沉淀。草桃背矿床的铀矿化与充填在草桃背火山口的橄榄玄粗岩关系密切,在时间上相近、在空间上相伴、在成生上相关,受橄榄玄粗岩岩浆系列热动力的影响,铀元素发生活化、转移或物质交换而成矿,成岩成矿时代属早白垩世晚期到晚白垩世早期。从草桃背铀矿床岩石学、地球化学及赋矿特征入手,总结了铀成矿是富铀矿的花岗岩基底、北东向构造及火山作用结合的产物,橄榄玄粗岩提供热源,并指出半岭、上寮、小富足等地段是寻找草桃背式铀矿床的极有利地区。     

大兴安岭东坡小奎勒河中基性侵入岩成因及地球动力学意义:锆石U-Pb年代学、元素和Hf同位素地球化学证据

大兴安岭地区以发育显生宙花岗岩和火山岩为特征,基性和中性侵入岩不是十分发育,仅在塔河、塔源、富西里、乌拉山、碧流台等地有所报道,且规模相对较小,它们在形成时代和成因上的差别为我们深入揭示大兴安岭地区壳幔过程提供了重要依据和线索。近期我们在大兴安岭东坡北部红花尔基地区开展了基础地质调查,在小奎勒河中游花岗杂岩体内部发现并确定了两处不规则中基性岩体,经系统的岩相学、年代学、元素和Hf同位素地球化学研究揭示：两处中基性岩体由细粒角闪辉长岩岩相和辉长闪长岩岩相构成; LA-ICP-MS单颗粒锆石U-Pb同位素定年结果显示,其成岩作用于310~293 Ma;岩石系列为准铝质、钾质-钠质、拉斑玄武质-钙碱性过渡岩系;初始岩浆为来自熔体-流体交代作用的富集地幔低程度（<5%）部分熔融作用,源区主要残留矿物相为辉石和石榴石、钙钛矿等;岩浆演化过程以结晶分离作用为主,伴随堆晶作用;形成于松嫩地块-兴安地块碰撞拼合晚期向初始大洋岛晚期大洋弧初始环境。     

埃迪卡拉系微生物碳酸盐岩沉积特征及其地质意义:以川中磨溪8井区灯影组四段为例*

四川盆地高石梯—磨溪地区埃迪卡拉系灯影组广泛发育一套微生物碳酸盐岩。以磨溪8井区灯影组四段(灯四段)为例,通过精细解析高频向上变浅序列的岩石学特征,发现灯四段微生物云岩及序列建造具有如下特征: (1)向上变浅序列主要由凝块石云岩、叠层石云岩和(含微生物)泥晶云岩3类构成,伴以少量微生物粘结颗粒云岩;(2)完整的典型向上变浅序列自下而上由(含微生物)泥晶云岩(A段)、平直状叠层石云岩(B段)、小型丘状叠层石云岩(C段)、分散状凝块石云岩(D段)、格架状凝块石云岩(E段)、微生物粘结颗粒云岩(F段)等6个岩性单元构成,但大量的序列由A-C-E、A-C-D、B-D、B-C-D-E等不完整的岩性单元构成,且序列顶底皆以凝块石云岩/(含微生物)泥晶云岩、叠层石云岩/(含微生物)泥晶云岩等不平整的岩性突变面或暴露面区分;(3)埃迪卡拉系微生物碳酸盐岩发育于浪基面之上至平均海平面附近的相对高能区域,且凝块石云岩较叠层石云岩形成的环境能量高。该研究结果不仅揭示出较高能的浅水环境控制了规模性微生物岩分布这一规律,而且对区域储集层预测具有指导意义,同时也因建立了有别于现代微生物的环境分布模式而具有重要的沉积学意义。     

砾石长期覆盖对土壤呼吸的影响

砾石覆盖是西北黄土高原地区的传统保护性耕作技术,具有明显的蓄水、保墒、增温、压碱和保持地力作用。研究砾石覆盖农田系统中的土壤呼吸,有助于了解地面覆盖条件对CO₂通量的影响和土壤健康状况。利用LI6400土壤呼吸系统对甘肃皋兰长期砾石覆盖农田(12年)不同覆盖厚度下的土壤呼吸进行了原位监测,并对环境因子与土壤呼吸的日变化相关性进行了分析。结果表明:(1)土壤呼吸的日变化与温度的变化一致,呈单峰型,砾石覆盖后土壤呼吸峰值出现在16:00—17:00,明显滞后于裸地出现的峰值时间(14:00—15:00),且峰值随着覆盖厚度的增加而减小;(2)土壤表层(0~10 cm)温度与土壤呼吸呈极显著幂函数关系(P<0.01),砾石覆盖降低了土壤呼吸的温度敏感性指数(Q₁₀),覆盖后两次监测中Q₁₀为1.78~2.87(2017年)和1.70~1.96(2018年);(3)砾石覆盖后提高了夜间土壤呼吸,导致土壤呼吸的日累积碳排放量显著提高,随着覆盖厚度的增加而降低,覆盖处理中厚度为11 cm最小的碳排放量两次测量分别为2.00 g·m^-2和0.90 g·m^-2,比裸地分别增加了15%和18%;(4)土壤特征因子中,土壤水分、pH与土壤呼吸累积碳排放量呈正相关,有机质、碱解氮、速效磷、电导率与土壤呼吸累积碳排放量呈负相关。     

强流脉冲电子束作用下金属纯Cu的微观结构状态——空位簇缺陷及表面微孔结构

利用强流脉冲(HCPEB)电子束技术对多晶纯Cu进行了辐照处理,并利用透射电镜对HCPEB诱发的空位簇缺陷进行了表征.实验结果表明,HCPEP辐照金属可在纯Cu表层诱发大量的过饱和空位,并形成四方形空位胞及空位型位错圈和堆垛层错四面体(SFT),HCPEB瞬间的加热和冷却诱发的幅值极大的应力和极高的应变导致的整个原子平面的位移是空位簇缺陷形成的主要原因.此外,扫描电镜分析表明HCPEB辐照可以在纯Cu表面形成高密度、弥散分布和尺寸细小的微孔.过饱和空位或空位团簇沿晶体缺陷向表面扩散、凝聚是表面微孔形成的根