广西来宾蓬莱滩剖面G-L界线草莓状黄铁微晶粒径特征及其氧化还原意义

在瓜德鲁普统末期发生了一次大规模生物灭绝事件,多类生物均遭受重创。关于此次生物灭绝事件成因,有学者认为海洋缺氧是主要的直接原因之一,但瓜德鲁普统-乐平统（G-L）过渡时期海洋的氧化还原条件的研究开展得较少,缺少直接证据证明海洋缺氧和瓜德鲁普统末期生物灭绝的关系。草莓状黄铁矿粒径是指示沉积水体氧化还原条件的少数可靠的指标之一。由于微晶粒径大小与草莓状黄铁矿粒径大小密切相关,草莓微晶粒径大小同样也可以作为沉积水体的氧化还原指标。本文通过研究蓬莱滩剖面卡匹敦阶茅口组和吴家坪阶合山组下部草莓状黄铁矿微晶粒径特征,从而分析沉积环境的氧化还原状态。研究结果表明蓬莱滩剖面茅口组和合山组微晶粒径多数分布在0.4～1.2 μm之间,大部分样品微晶粒径分布相对较窄,部分样品分布较宽。茅口组-合山组界线处间歇性出现微晶粒径很小且分布范围窄的样品,其平均微晶粒径一般小于0.7 μm,最大值一般不超过1.2 μm,很可能指示硫化-缺氧的环境。茅口组和合山组大部分样品平均微晶粒径分布在0.7～1.0 μm之间,最大值一般不超过3.3 μm,很可能指示的是氧化-贫氧环境。蓬莱滩剖面硫化至缺氧环境对应着瓜德鲁普末期生物灭绝事件层位,说明这两者很可能存在因果关系。海洋的硫化缺氧很可能是瓜德鲁普末期生物灭绝的主要原因之一。     

Response to the comment by Z.F. Zhao and T.S. Gao (2007) on “Paleozoic ages and excess Ar in garnets from the Bixiling eclogite in dabieshan, China: New insights from Ar/Ar dating by stepwise crushing”

In our paper we supposed that the Paleozoic ages of the Bixiling eclogitic garnets by ⁴⁰Ar/³⁹Ar crushing in vacuo were related to the UHP metamorphism. Zhao and Gao [Zhao Z.-F. and Gao T.-S. (2007) Comment on “Paleozoic ages and excess ⁴⁰Ar in garnets from the Bixiling eclogite in Dabieshan, China:Newinsights from ⁴⁰Ar/³⁹Ar dating by stepwise crushing” by Qiu and Wijbrans (2006). Geochim. Cosmochim. Acta71(24), 6046-6050] dispute our conclusions and re-interpret them as “the age of garnet growth by low-T/HP blueschist/eclogite-facies metamorphism of the UHP eclogite precursor during arc-continent collision in the early Paleozoic” without presenting any new petrological evidence. Based on our present understanding of ⁴⁰Ar/³⁹Ar crushing technique and petrological observations, we do not agree with their re-interpretation and still prefer our original interpretation.     

利用地质成果优化3010皮带上山设计

3010皮带上 山 建成 后将 担 负着 范各 庄 矿三 水平 、四 水平 的 煤炭 运输 任 务,服务 年 限要 求 至 少 30a。 此 皮 带上山 位于 岩 溶陷 落柱 较 发育 的井 口 区域 ,范 各庄 矿 发现 的 12个 陷落 柱 全部 位于 此 区域 。由 于 陷落 柱直 接 导通 下部 奥 灰水 ,一 旦揭 露 将有 淹没 整 个矿 井的 危 险。为 保 证矿 井安 全 ,在 工程 施工 前 ,利用 地 质手 段对 设 计区 域进 行 了探 查,发现皮 带上 山 的中 上部 发 育有 岩溶 陷 落柱 ,两 次对 设 计进 行了 修 改,为 施 工提 供了 安 全保 障。     

东昆仑地区驼路沟钴(金)矿床硅质钠长岩锆石U-Pb定年及Hf同位素特征研究

东昆仑驼路沟钴(金)矿床是青海省发现的首个独立大型喷流沉积型矿床,说明容矿围岩为一套海相火山-沉积岩系。本文在野外调查的基础上,对该矿区短沟矿段YM1坑口的硅质钠长岩进行岩石学、LA-ICP-MS锆石UPb年代学及Hf同位素分析。结果表明,区内钠长岩的形成年龄为(457.3±4.6)Ma,佐证了该矿区喷流作用成岩与成矿的同时性;另外获得9.20~1.10 Ga和2.40~2.50 Ga的2个年龄集中区,说明了研究区基底演化和源区物质的复杂性。Hf同位素显示为两个集中区,其中年龄峰值422~459 Ma的锆石获得εHf(t)值为-0.61~12.72,表明锆石母岩主要为新生的地壳物质,指示硅质钠长岩的形成与海底火山喷发作用密切相关;另外0.85~1.10 Ga的锆石εHf(t)值为-15.09~-0.07,其锆石母岩中主要为再造的古老地壳,表明该区基底源区物质的复杂性。通过区域对比分析,认为驼路沟矿区含矿火山-沉积岩系形成时代与钠长岩年龄、成矿年龄非常接近,喷流沉积时代应为晚奥陶世。     

陆丰南地区断拗转换界面厘定及其地质意义

珠江口盆地经历裂陷阶段向拗陷阶段的转变，同期沉积地层记录了该构造变革和沉积演化过程，为厘定断拗转换界面提供了可能。基于地震反射、沉积旋回特征，识别出陆丰南地区恩平组内部存在全区可追踪对比的构造沉积转换面——T72界面，也是区分上下恩平组界面。对陆丰13洼洼间隆钻井LFA开展上下恩平组碎屑锆石U- Pb 定年、重矿物组分、元素分析，提出恩平组T72界面上下地层物源体系发生转变。结合区域沉积充填特征，表明陆丰南地区T72界面为断- 拗转换界面。具体表现为：下恩平组沉积期湖盆继承文昌期裂陷盆地特征，湖盆水体较深，物源主要为盆地内部的中生代基底凸起，沉积层序明显受盆内低凸起控制，在盆内低凸起四周发育一系列近源的辫状河三角洲，井区主要接受来自惠陆低凸起物源;上恩平组沉积期间，湖盆进入断拗过渡期，湖盆扩大、水体变浅，盆内低凸起四周的断裂活动减弱，沉积层序逐渐向盆内低凸起超覆，盆外太古宙—古生代物源组分供给不断加强，近源的三角洲砂体逐渐向远源的浅水三角洲砂体转化，同时发育宽广的滨浅湖环境，原供给物源的惠陆低凸起为水体淹没，井区接受了北部隆起外的物源。     

Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.     

四川盆地广安地区中二叠统栖霞组岩石特征与沉积环境

四川盆地中二叠统栖霞组勘探发现系列油气,资源潜力巨大。但广安地区中二叠统栖霞组的岩石学特征及沉积环境研究薄弱。在野外地质调查的基础上,结合室内岩石学、岩相学等综合分析,对广安地区栖霞组碳酸盐岩岩石特征、沉积相类型及其古地理展布特征进行了系统研究。结果表明：广安地区栖霞组主要发育亮晶颗粒灰岩、亮晶生物碎屑灰岩、微晶生物碎屑灰岩、微晶颗粒灰岩、生物碎屑微晶灰岩、含生物碎屑微晶灰岩和泥晶灰岩7种岩石类型;碳酸盐岩颗粒主要以生物碎屑为主,部分层位发育球粒;古生物化石以三叶虫、腕足和有孔虫为主,同时可见棘皮类和藻类;栖霞组沉积期主要为碳酸盐岩台地沉积环境,其中栖霞组晚期（栖二段）台缘滩和台内滩较为发育,为该区油气成藏提供了有利条件。     

皖浙赣断裂带的界定及其基本特征

以往文献中及众多研究者所指的“皖浙赣断裂带”实际上包括了不同时代形成的、方向有变化的多组规模巨大的区域性断裂带;最早的断裂带形成于新元古代,最晚的形成于晚中生代。在地壳演化过程中,随着构造应力场的变化,不同时代的断裂带方向变化较大,新元古代晋宁期为北东向,早古生代加里东期为近东西向—北东东向,晚中生代为北北东向;每一期断裂带都有它们自己的大地构造背景和指示意义。文中认为,不同阶段形成的断裂带不能混为一谈。新元古代晋宁期的北东向断裂带南段基本上以赣东北蛇绿混杂岩带为代表,向北东延至皖南伏川断裂带,具有板块(或地体)边界断裂的性质;加里东期以近东西向祁门—歙县断裂带为代表,其西段被后期牵引成北东向,造成两侧的变质基底特征明显不同;二者均不属于皖浙赣断裂带的组成部分。而通常意义上所指的具有区域控岩控矿作用的皖浙赣断裂带,是晚中生代北北东向的赣东北—五城—歙县—绩溪—宁国断裂带,控制了侏罗—白垩纪红色盆地及燕山期岩浆岩的形成和分布,是一条具有控矿作用的重要的构造岩浆岩带。