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61.
表面张力是固体表面重要的物理化学参数之一,其大小与温度和界面两相物质的性质有关。基于Young方程的推导,使用接触角测量法计算固体表面张力已被广泛应用于表面科学和工程领域。宝玉石材料大多具有光洁的表面,在接触角测量的准确性方面较其他表面不均一的固体材料具有明显的技术优势。本文运用现代仪器(FTA200动态接触角测量仪)测量了15个天然和合成宝玉石品种(钻石、合成碳硅石、合成立方氧化锆、碧玺、托帕石、翡翠、琥珀等),以及经覆膜和充填2种处理方法的宝玉石样品(镀膜钻石、覆膜托帕石、覆膜翡翠、覆膜琥珀、充填碧玺)的表面接触角,并运用公式计算其表面张力。测试数据表明,不同品种宝玉石的接触角数值存在差异,如钻石的接触角值为56.68°,其仿制品立方氧化锆的接触角值为37.79°;覆膜处理与未经覆膜处理的天然宝玉石的接触角数值差异明显,如琥珀的接触角值为92.49°,覆膜琥珀的接触角值为66.49°;充填处理宝玉石接触角的测试由于控制液滴的大小受条件限制操作难度较大,测试结果不能准确表达为裂隙中充填物的接触角数值,故充填处理的宝石不宜采用此方法进行区分。研究表明,对于部分宝玉石品种和覆膜处理宝玉石,其表面接触角及表面张力数值差异显著,可以作为宝玉石品种的辅助鉴定依据;尤其是运用接触角的差异对于宝玉石鉴定具有较好的判别性,能够对不同品种的天然宝玉石与表面覆膜的宝玉石样品进行有效区分。与常规宝石检测方法(如红外光谱、折射率测量方法)对比,接触角测量方法具有测量准确、操作简便,不破坏样品的特点,符合宝玉石无损鉴定的基本原则,且能够安全快速地测量高折射率宝石,可以解决宝玉石表面覆膜等与表面物性相关的检测疑难问题。 相似文献
62.
在基于性能抗震设计中,要求实现多级设防,目的是使结构抗震设计不仅要保护生命安全,同时也要控制因结构破坏而带来的经济损失,使结构在整个生命周期内费用达到最小。但由于结构抗震设计中存在着大量的不确定因素,使得实现每个性能水平都是不确定的,因此,每个性能水平的目标可靠度究竟取多高才能达到设计要求,是目前抗震设计的一个基本问题。针对这一问题,将地震作用、自重荷载、材料强度等看作随机变量,分析了结构造价与失效概率之间的近似关系,明确了不同性能水平失效概率之间的合理比例关系,采用"投资-效益"准则,且控制人员伤亡率小于社会可接受水平,来确定结构的目标性能水平。以两个钢筋混凝土框架结构为例,说明了该方法的应用。 相似文献
63.
64.
Rainfall characteristics are key factors influencing infiltration and runoff generation in catchment hydrology, particularly for arid and semiarid catchments. Although the effect of storm movement on rainfall-runoff processes has been evaluated and emphasized since the 1960s, the effect on the infiltration process has barely been considered. In this study, a physically based distributed hydrological model (InHM) was applied to a typical semi-arid catchment (Shejiagou, 4.26 km2) located in the Loess Plateau, China, to investigate the effect of storm movement on infiltration, runoff and soil erosion at the catchment scale. Simulations of 84 scenarios of storm movement were conducted, including storms moving across the catchment in both the upstream and downstream directions along the main channel, while in each direction considering four storm moving speeds, three rainfall depths and two storm ranges. The simulation results showed that, on both the hillslopes facing downstream (facing south) and in the main channel, the duration of the overland flow process under the upstream-moving storms was longer than that under the downstream-moving storms. Thus, the duration and volume of infiltration under upstream-moving storms were larger in these areas. For the Shejiagou catchment, as there are more hillslopes facing downstream, more infiltration occurred under the upstream-moving storms than the downstream-moving storms. Therefore, downstream-moving storms generated up to 69% larger total runoff and up to 351% more soil loss in the catchment than upstream-moving storms. The difference in infiltration between the storms moving upstream and downstream decreased as the storm moving speed increased. The relative difference in total runoff and sediment yield between the storms moving upstream and downstream decreased with increasing rainfall depth and storm speed. The results of this study revealed that the infiltration differences under moving storms largely influenced the total runoff and sediment yield at the catchment scale, which is of importance in runoff prediction and flood management. The infiltration differences may be a potential factor leading to different groundwater, vegetation cover and ecology conditions for the different sides of the hillslopes. 相似文献
65.
煤矿防治煤和瓦斯突出是一项极其复杂的系统工程,人们逐步探索煤与瓦斯突出规律,人工计算已不能适应大量数据处理与分析之需要,将计算机数据库及计算机绘图功能运用于防突工作中,能较好地处理防突数据,提高防突预测预报的针对性和准确性,使之更好地为矿井安全生产服务。 相似文献
66.
Hui Jiang Mads F. Knudsen Marit‐Solveig Seidenkrantz Meixun Zhao Longbin Sha Lihua Ran 《Boreas: An International Journal of Quaternary Research》2014,43(1):208-219
We present a new reconstruction of summer sea‐surface salinity (SSS) over the past 15 000 years based on a diatom record from piston core 17940, located on the northern slope of the South China Sea (SCS). The reconstructed diatom‐based summer SSS values for the modern period are in accord with instrumental observations of summer SSS in the area. Here, the modern summer SSS is primarily controlled by river runoff, in particular from the Pearl River. The reconstruction presented in this study shows that the summer SSS varied between 33.3 and 34.2 psu over the past 15 000 years. The long‐term summer SSS trend closely followed the trend of the orbitally controlled solar insolation at 20°N, suggesting that orbital forcing was the dominant driver of changes in summer SSS in this area. Comparisons to speleothem δ18O data and studies of surface hydrography in the region suggest that changes in solar insolation affected the summer SSS through changes in the East Asian Monsoon and sea‐level changes associated with the last deglaciation. Univariate spectral analyses indicate that centennial‐scale oscillatory variations in summer SSS were superimposed on the long‐term trend. During the deglacial period (c. 12 000–9000 cal. a BP), the dominant periodicity was centred around 230–250 years, whereas a ~350‐year oscillation dominated in the period 2200–4500 cal. a BP. The balance of evidence suggests that these centennial‐scale changes in summer SSS may have been driven by solar‐induced changes in the East Asian Monsoon, but further evidence is needed to firmly establish this relationship. 相似文献
67.
藻类作为水体中的初级生产力,通过生物积累、生物矿化等生理功能与环境中的重金属相互作用、对重金属地球生 物化学循环起到关键作用。为了探讨藻类生物矿化去除水体中重金属的现象,文中研究了淡水微藻FZUL-321对Pb2+的去除 及矿化。结果表明:微藻FZUL-321对Pb2+有较强的去除能力,且是一个快速去除的过程。随着Pb2+浓度增大,该微藻对Pb2+ 的去除效果也增大。在弱酸性条件下(pH5.0),其去除Pb2+的效果较好。如在Pb2+初始浓度为100mg/L,pH5.0,去除时间 为40min,此时Pb2+的去除量为423.2×10-3干重。原子力显微镜(AFM)对细胞表面的形貌进行观察,发现微藻FZUL-321与 Pb2+作用后,细胞形貌和尺寸变化较大,如细胞褶皱并塌陷,细胞表面变得粗糙等。傅里叶红外光谱(FT-IR)结果表明藻 细胞表面的羧基、氨基和磷酸基团等官能团参与前期Pb2+的吸附沉淀。最终,通过一系列生化作用,微藻FZUL-321将离子 态的Pb2+矿化,X射线衍射(XRD)分析显示,矿化产物为Pb5(PO4)3OH。 相似文献
68.
Amy L Wolfe Ran Liu Brian W Stewart Rosemary C Capo David A Dzombak 《Geochemical transactions》2007,8(1):9
Background
Standardized sample preparation techniques allow comparison of pyrite dissolution experiments under diverse conditions. Our objective was to assess dry and wet sieving preparation methodologies, and to develop a reproducible technique that yields uniformly size-distributed material within a limited size range of interest. 相似文献69.
Arching effect and displacement on theoretical estimation for lateral force acting on retaining wall
Jiang Junfeng Zhao Qihua Zhu Shuairun Peng Sheqin Wu Yonghong 《Natural Hazards》2021,108(3):2991-3019
Natural Hazards - A new approach is proposed to evaluate the non-limit active earth pressure in c–φ soil based on the horizontal slices method and limit equilibrium method, which takes... 相似文献
70.
西准噶尔谢米斯台山西缘火山岩岩石地球化学特征及其地质意义 总被引:3,自引:0,他引:3
为探讨西准噶尔谢米斯台山西缘新发现的中志留世火山岩的岩石属性和地质特征,对其进行岩石地球化学研究。分析结果显示,岩石以富Si、Sr、Ba为特征且具有较高的Mg#(55~75)、Sr/Y(28~59)和Ba/La(17.52~49.88)值,K/Na值0.33~0.66,大离子亲石元素(LILE)相对富集,高场强元素(HFSE)相对亏损,其中Nb、Ta、Ti强烈亏损,具有轻微的负铕异常(δEu=0.84~0.99)。上述特征显示其类似日本中新世Setouchi火山岩带中的赞岐岩。结合其他研究,推测该火山岩可能为受俯冲板片熔体交代的地幔源区部分熔融的产物,它与区内相近时期埃达克岩等的共生组合意味着西准北部在中志留世—早泥盆世曾受到热的洋壳俯冲机制的影响,为进一步认识博什库尔-成吉斯岩浆弧的性质及构造演化提供了新的证据。 相似文献