微束分析技术在研究伴生金元素赋存状态中的应用

运用微束分析技术扫描电子显微镜(SEM)及其配套的背散射电子像功能,特征X射线线扫描、面扫描功能,能谱仪(EDAX)鉴定功能,观察里伍铜矿矿石中纳米级至微米级的伴生金(超微细金)矿物,获取其形貌照片、能谱图和定性定量分析结果,得到了清晰的金元素及与其共生的元素线、面分布图像,查明了里伍铜矿中的金元素是以类质同象的形式分布于含银的铋矿物和金银矿中,含银的铋矿物和金银矿分布在黄铜矿与磁黄铁矿的裂隙中及含锰的铁闪锌矿中,排除了基体成分的干扰,载金矿物颗粒至少大于20 nm。该方法操作简便,过程简单,分析结果直观、可靠,提高了研究伴生金元素赋存状态的效率。测试的样品为里伍铜矿热液型矿石,经分析形成于燕山中晚期(104～142.2 Ma),为局部构造运动和岩浆期后热液使成矿元素再富集成矿的地质产物,晚于主成矿期——燕山中期。里伍铜矿中Ag和Au的质量比值为1.38～4.59,推测伴生金的成矿温度应小于或等于227℃。里伍铜矿在成矿过程中至少经历了早期的中高温热液阶段和晚期的中低温热液阶段,早期大量硫化物的析出和晚期中低温绿泥石、绢云母矿物的大量出现也证实了这一过程的存在。     

Estimation of the evacuation clearance time based on dam-break simulation of the Huaxi dam in Southwestern China

It is necessary for China to establish a feasible method to verify whether an emergency evacuation plan (EEP) provides timely evacuation under the threat of flooding as a result of dam failure. Based on simulating the inundation area resulting from failure of the Huaxi Dam, this paper puts forward a quantitative approach to assess the effectiveness of an EEP by estimating the evacuation clearance times. Differences between urban and rural areas are considered, and two transportation modes are selected. Total evacuation clearance times in rural and urban areas are 135 and 80?min, respectively. Results show that total evacuation clearance times are longer than the time it takes for the flood wave to reach some communities in the area. The paper also makes some suggestions on how to decrease the total clearance time and thus enhance the effectiveness of the EEP for the Huaxi Dam.     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

海南岛中三叠世正长岩—花岗岩套的地质地球化学特征与构造意义

海南岛中三叠世正长岩-花岗岩套分布于陵水-龙滚深断裂两侧及白沙深断裂南东侧.出露总面积516km2.由石英二长岩、石英正长岩及正长花岗岩组成.该岩套SiO2含量变化大,为58.40%-76.14%,富碱富钾,Na2O+K2O为7.10%-11.49%,K2O含量为3.78%-7.91%,属钾玄质碱性系列;A/CNK为0...     

CSAMT全区视电阻率电场正演迭代拟合近场校正方法

利用水平电偶源激发的电磁场,提出了正演迭代拟合电场强度的CSAMT近场校正方法。实验应用表明,在远区该方法的结果等于卡尼亚电阻率,在近区和过渡区则明显改善了卡尼亚电阻率的非波区场畸变。使用该方法能扩大CSAMT的勘探深度,扩展应用领域,更形象地反映地下介质的垂向电性的变化。     

Geological characteristics of the Sizhuang gold deposit in the region of Jiaodong, Shandong Province——A study on tectono-geochemical ore prospecting of ore deposits

Tectono-geochemical samples were systematically collected from 5 drillcores along the No. 304 explora-tion line and at the -310 m level under the pit in the mining area, totalling 705 samples from the metamorphic rocks, granites, altered rocks and orebodies, and were determined for their contents of 20 kinds of elements including Au, Ag, As, Sb, Hg, Cu,,Pb, Zn, Sn, Bi, Mo, Co, Ni, Mn, Cr, V, Ti, Ba, Rb, Sr, etc. By using the Surfer software the geochemical exploration line profile maps for the 20 kinds of elements and the curves for the element geochemical contents of individual ore vein groups were established. In conbination with the geochemical map analytical method and Gregorian’s zoning index calculation method, the vertical, longitudinal and lateral zonation sequences of the elements were ascertained and the geochemical three-dimentional zonation model of the primary halos was estab-lished on the basis of the analysis of metallogenic structures and alteration zonation. Coupled with the results of analysis of the geology and geochemistry data, it may be concluded that the process of alteration of granites in the mining area is also accompanied with the process of gold enrichment and mineralization. With the intensification of alteration of granites from granite →potash feldspathization granite →sericite-quartz alteration granite, seric-ite-quartz rocks →beresitized granite, pyrite sericite-quartz rock, silicified granite →gold ore, the contents of thio-phile ore-forming elements such as Au, Ag, As, Cu, Bi, Mo, Pb, Sb, Hg, and Sn tended to increase. Factor analysis of trace elements indicated: factor F2 (Au, Ag, Cu, Sn, As) represents the element association brought in at the main stage of hydrothermal metallogenesis; factor F4 (Bi, Sb) and factor F5 (Pb, Zn) represent the ore-forming element association supperposed during the late stage of Au-bearing sulfides. By using the Gregorian’s zoning index and map analysis method we have ascertained the primary halo axial zonation sequence (form frontal halo →tail halo): Pb, Zn, Mn, Ba, Sr, Rb, As, Sb, Ag, Cu, Sn, Mo, Au, Bi, Hg, Ti, Cr, V, Ni, and Co. The geochemical anomalies in the mining area display a tendency of lateral plunging to WS, which is consistent with the lateral plunging of orebodies and mineralization alteration zone. Comprehensive analysis of the results of investigations on ore-controlling structures, mineralization-alteration zonation and geochemical zonation of the primary halos indicates that the gold orebodies in this area are still of greater extension.     

祁连山夏季地形云综合探测试验

2006年和2007年夏季在祁连山冷龙岭西段开展了地形云云量、云状、大气水汽、风场、雨滴谱和雨强等的综合探测试验,以分析祁连山地形云的特征。结果表明：①祁连山区夏季云量丰富,平均云量在6成以上。西南气流天气背景下总云量多达8成;②祁连山夏季无降水日大气水汽非常少,700 hPa以上层大气相对湿度大多在20%以下;③西南气流背景下祁连山南北侧山谷风的共同作用,气流昼间向山顶辐合,夜间向山谷辐散,当水汽条件充足时,极易抬升形成可以产生降水的地形云;④祁连山降水主要由小于1 mm的雨滴组成。     

河南省城镇化空间差异研究

分别以地市和县(市)为单元,对河南省的城镇化空间差异进行了研究,发现中原城市群地区、三门峡以及豫北的安阳、鹤壁城镇化发展水平较高,而濮阳、南阳和黄海地区的城镇化发展水平较低。另外,从县域单元看,区域内部差异也较为明显:如中原城市群内部又可以从高到低分为三个圈层;一些重工业城市或资源型城市地区城镇化发展水平较高,而一些平原地区的传统农业区县(市)城镇化发展水平较低。基于此,提出了大力发展城市经济、增强城镇化的产业基础,实施重点突破、兼顾均衡发展,实施差异化发展、分区推进的城镇化发展策略。     

热球菌HJ21高温α-淀粉酶基因克隆、表达及性质研究

通过简并引物扩增热球菌(Thermococcus siculi)HJ21高温α-淀粉酶保守区域之间的序列,再利用Site-finding技术获得两端未知序列.构建了在N端添加了His6标签的表达载体pEt-28a-His6-THJA后转化E.coli,在IPTG诱导下表达.进一步纯化后SDS-PAGE电泳检测达到电泳纯...     

采煤塌陷区土地质量评价指标体系探讨——以徐州矿区为例

简要回顾采煤塌陷区土地质量研究状况,根据科学性、代表性、可行性、敏感性的原则,以徐州市采煤塌陷区为研究对象,运用PSR概念模型,尝试给出针对具体采煤塌陷区的土地质量评价指标体系。体系共分为3层23个指标,较全面的涵盖了社会经济、物理化学、政策法规等不同范畴。