离子色谱法测定六价铬和三价铬

本文提出了用HPIC-AG4柱和用0.5mmol/L Na_2CO_3为淋洗剂(2.0ml/min),离子色谱法测定土壤中Cr(Ⅵ)。50μl进样体积时的检测限为0.1μg/ml Cr(Ⅵ),同时在0.01mol/L NaOH的介质中,H_2O_2将Cr~(3+)氧化成CrO_4~(2-),然后测定总Cr量,由此计算Cr~(3+)的含量。     

Relation between temperature changes of the mid-upper troposphere over Eurasian mid-high latitudes and solar irradiance in the twentieth century

The δ¹⁸O data obtained from an 18.7 m ice core drilled in Chongce Ice Cap at an elevation of 6,530 m a.s.l. in the West Kunlun Mountains on the northern Tibetan Plateau show a strong correlation with the summer temperature of the middle to upper troposphere over the mid-high latitudes of Eurasia. Based on this, the δ¹⁸O record can be used as a proxy of the June–September mean temperature of the mid-upper troposphere (MUT) from 1903 to 1992. The time span of the ice core record is much longer than the meteorological data available only after 1948. Using the empirical mode decomposition method (EMD), the δ¹⁸O record is decomposed into various frequency components and compared with the solar irradiance variations of the same period. The results show that (1) The June–September mean temperature of the MUT over Eurasian mid-high latitudes is completely decomposed into four IMF (intrinsic mode function) components and an increasing trend. (2) Solar irradiance is decomposed into the Schwabe cycle, the Hale cycle, the Gleissberg cycle, and an increasing trend. (3) The correlation coefficients between the June and September mean temperatures of the MUT over Eurasian mid-high latitudes and solar irradiance on the longer timescales (at least more than 11-year) show the significant correlations; their phase changes are basically identical in general, and (4) the 11-year Schwabe cycle exists in the June–September mean temperature of the MUT over Eurasian mid-high latitudes during most of the time from 1903 to 1992, and only in the two high-temperature phases (1929–1944 and from 1975 to the present) may global warming disturb this relation. A full understanding of this phenomenon would shed insight into the potential consequence of global warming on the MUT.     

A 16 ka climate record deduced from δ^13C and C/N ratio in Qinghai Lake sediments, northeastern Tibetan Plateau

1 INTRODUCTION δ13C in organic matters from lacustrine sedi- ments varies with several factors including aquatic plants, vegetation type in the catchment, atmos- pheric CO2 concentration, climate (temperature and precipitation), and properties of water, …     

The hydrothermal karstification and its effect on Ordovician carbonate reservoir in Tazhong uplift of Tarim Basin,Northwest China

With a detailed study on petrology, mineralogy and geochemistry of some important Ordovician carbonate well core samples in Tazhong uplift of Tarim Basin, the distinguishing symbols of hydrothermal karstification are first put forward as the phenomena of rock hot depigmentation, hot cataclasm and the appearance of typical hydrothermal minerals such as fluorite, barite, pyrite, quartz and sphalerite. The main homogenization temperatures of primary fluid inclusions in fluorite are from 260 to 310°C, indicating the temperature of hydrothermal fluid. The fluid affected the dissolved rocks and showed typical geochemistry features with low contents of Na and Mg, and high contents of Fe, Mn and Si. The ratio of ³He/⁴He is 0.02R _a, indicating the fluid from the typical continental crust. The hydrothermal fluid karstification pattern may be described as follows: the hot fluid is from the Permian magma, containing dissolving ingredients of CO₂ and H₂S, and shifts along fault, ruptures and unconformity, and dissolves the surrounding carbonates while it flows. The mechanism of hydrothermal karstification is that the mixture of two or more fluids, which have different ion intensity and pH values, becomes a new unsaturated fluid to carbonates. The hydrothermal karstification is an important process to form hypo-dissolved pinholes in Ordovician carbonates of Tazhong uplift of Tarim Basin, and the forming of hydrothermal minerals also has favorable influence on carbonate reservoirs.

     

GIS工作流系统的长事务处理研究

分析了Sagas事务模型及空间数据版本树技术,设计了一种灵活的长事务补偿控制方案,为集成GIS,MIS及OA的工作流系统提供了有力的事务处理技术支持。     

Dynamic Response and Mechanical Behaviours of Geogrid for High Earth-rockfill Dams

Geotechnical and Geological Engineering - Due to the complexity of the interaction between the geogrid and the soil interface in high earth-rock dams, the method of replacing the grid with steel...     

江西气候生态产品价值实现的探索与思考

江西省气象部门针对气候生态产品价值实现开展了许多探索,积累了一系列的先进经验。文中从江西气候生态产品价值实现途径、效益、政策等方面进行思考和分析,认为政策先行营造制度环境、创建品牌实现气候价值、试点示范稳步实践创新和搭建平台培育价值理念等手段为挖掘气候好资源做好“两山”转化工作提供了有力支撑。针对发现的问题,提出了建议：理念创新,将气候资源价值转化固化于制;机制创新,用制度保护气候资源价值实现;载体创新,创品牌实现气候生态产品价值。     

内蒙古地区场地响应区域特征分析

本文以内蒙古地区台站分布、地质构造和地震活动性为基础,将内蒙古的大部地区划分为三个研究区域分别进行了场地响应研究。对近几年积累的大量ML≥3.0级以上地震,共计39个台站记录到的124次地震事件的785条波形,根据S波的观测振幅谱,采用遗传算法分别反演了三个区域的介质非弹性衰减系数和台站场地响应,并对其进行了讨论。本文得到的介质衰减模型和台站场地响应,将对台网测定ML震级需要考虑的量规函数、台站校正值等提供重要参考。研究结果表明:除个别台站存在场地放大或缩小的响应外,绝大多数台站的场地响应表现出一定的区域性特征;西部区域(除极个别台站外)对高频存在明显衰减;中东部区域对整个频段的反映都比较稳定;东部区域对整个频段存在明显放大,这与该区域覆盖层厚度大相吻合。     

邻近算法在微地震震源位置和一维速度模型同时反演中的应用

微地震事件的空间分布可以用来监测水力压裂过程中裂缝的发育情况.因此,震源定位是微震监测中重要的环节.震源定位依赖准确的速度模型,而震源位置和速度模型的耦合易导致线性迭代的同时反演方法陷入局部极小值.邻近算法作为一种非线性全局优化算法,能够最大程度地避免陷入局部最优解.本文将邻近算法应用于单井监测的微震定位和一维速度模型...     

应用实时定量PCR技术检测秦皇岛近岸海域褐潮原因种——抑食金球藻(Aureococcus anophagefferens)

Aureococcus anophagefferens, a small pelagophyte algae, has caused brown tide blooms in coastal waters of Qinhuangdao in recent years, presenting significant negative impacts on the shellfish mariculture industry. Under standard light microscopy, it is visually indistinguishable from other small algae in field samples due to its extremely small size. In this study, quantitative polymerase chain reaction(q PCR) based on 18 S r DNA sequences was developed and used to detect and enumerate A. anophagefferens. A linear regression(R2 = 0.91) was generated based on cycle thresholds value(Ct) versus known concentrations of A. anophagefferens. Twenty-two field samples collected in coastal waters of Qinhuangdao were subjected to DNA extraction and then analyzed using q PCR. Results showed that A. anophagefferens had a wide distribution in coastal waters along Qinhuangdao. Elevated A. anophagefferens abundance, category 3 brown tide blooms(200 000 cells/m L) occurred at Dongshan Beach and Tiger-stone Beach in August in 2013. In shellfish mariculture areas along coastal waters of Qinhuangdao, 4 stations had category 3 blooms, and 6 stations had category 2 blooms(35 000–200 000 cells/m L) in August and all stations had category 1 blooms(0 to ≤35 000 cells/m L) in October. Quantitative PCR allows for detection of A. anophagefferens cells at low levels in filed samples, which is essential to effective management and prediction of brown tide blooms.