滇西点苍山—哀牢山变质岩系锆石SHRIMP定年及其地质意义

滇西点苍山和哀牢山主体分别由下元古界苍山群和哀牢山群深变质岩系组成,被认为是前寒武纪结晶基底。选取点苍山的花岗闪长质糜棱岩(DCS-1)和哀牢山元江段黑云母花岗闪长质片麻岩(SM07-1)之中的锆石进行U-Pb SHRIMP定年。样品DCS-1和SM07-1测年结果分别为233±2.6Ma和239.8±2.8Ma。结合前人对滇西地区花岗质岩类所做的研究,揭示滇西地区在三叠纪经历一期在空间上广泛分布的岩浆事件,点苍山花岗质糜棱岩和哀牢山花岗质片麻岩的原岩为三叠纪侵位的花岗岩,其构造环境属于大陆裂谷,反映了滇西地区在三叠纪地壳物质的重新调整,而该变质岩系不是前寒武纪的结晶基底,其变质作用与山体出露地表过程和新生代构造作用有关。     

AN ANALYTICAL METHOD OF ULTRA-TRACE TELLURIUM FOR SAMPLES OF SEA-AND ENVIRONMENTAL-WATER

Tellurium is known to be a poisonous element to human health. In recent years,determination of trace tellurium has been attached great attention in connection with thewide application of its compounds and/or with environmental pollution. Literature citedreported the determination of ppb level tellurium in waste water and artificial watersamples by atomic-absorption spectrophotometry. As the tellurium content in naturalwater is extremely low, there is not yet any sensitive analytical method for determination ofits background value in various natural water. In chemical oceanography, data abouttellurium content in seawater are rather scarce. This paper will summarize and evaluate a series of our investigations on the analytical     

乐亭发生特大渔业污染案渔民获赔1300多万元

2002年4月12日,天津海事法院对河北省乐亭特大渔业污染案做出一审判决,责令被告迁安第一造纸厂等9家单位连带赔偿原告乐亭18户渔民经济损失总计人民币1 365.97万元,立即停止侵害,不得再排放污水入海,消除继续污染原告养殖区域的危险。 接到判决书,原告对笔者表示说,他们“对     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

要十分重视另一类型地质灾害的防治

文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。     

中国大陆及邻近海域的Rayleigh波群速度分布

利用Rayleigh波群速度资料反演得到中国大陆及其临近海域的(70°E-145°E,10°N-55°N)15-120s周期的群速度分布图像. 塔里木盆地在15s处清楚地显示为低速,在16-33s左右没有显示,但在36-5s显示为高速,说明塔里木盆地有较深的根. 青藏高原块体是44s至120s图像中最为突出的低速块体,南面与印度板块的分界线以及与北面的塔里木盆地、柴达木盆地的分界清晰,其块体中西部的速度低于东部. 泰国清迈附近存在一尺度为1000km左右的低速带,可能是青藏高原块体的物质向东南方向迁移造成上地幔物质上涌的结果. 南北地震带表现为强烈的速度梯度带,西面为低速,东面为高速. 中国南海的中央、日本海中央、菲律宾海表现为海洋性地壳. 菲律宾海的图像与地形及地震带完全吻合. 环绕菲律宾海及日本海存在400km左右宽的低速带,可能是岩浆活动带.     

土体冻结过程中的盐分场研究

As to salty soil, salt migrates with water in freezing soils, assembles and crystallizes continuously. Consequently the swelling of the soil volume leads to the phenomenon of salt heaving. It has a practical significance for solving salt-heaving and frost-heaving damage in engineering to deepen the understanding of salt heaving mechanism. In this paper a general overview about new research results at this aspect was presented. And then the study of salt migration and salt heaving mechanism and present salt heaving models were summarized. For further researching the field of salt transfer it is urgent to continually strengthen the salt migration and the numerical simulation study of salt heaving mechanism to expect perfecting the general evaluation of salt heaving prediction models so as to have a better service for engineering.     

川东南龙王庙组埋藏及混合水白云岩化作用

通过野外调查和地球化学分析,认为四川盆地东南部土河场和南山坪剖面龙王庙组的白云岩不同于区内其他的白云岩。川东南地区龙王庙组白云岩多为回流渗透成因,土河场白云岩则为埋藏白云岩,而南山坪白云岩则为混合水成因。土河场白云岩分布在龙王庙组的下部,不具备形成回流渗透白云岩的地质条件,包体测温显示土河场白云岩的形成温度较高,均在105 ℃以上,其Mn元素和Fe元素含量较高,平均值分别为792.5×10-6和3 428.8×10-6,且具有很好的相关性,δ18O平均为-8.18‰,明显低于研究区其他剖面的白云岩,这些特征均反映了土河场剖面白云岩形成于埋藏环境的特征。南山坪剖面主体处于斜坡相中,也不具备形成回流渗透白云岩的地质条件。南山坪白云岩具有明显的低Na元素的特征,δ18O也明显偏负,显示其形成于温度相对较低的低盐度流体环境中,此外,南山坪白云岩具有明显的U元素富集的特征,指示南山坪白云岩形成与大气淡水有关,为混合水成因的白云岩。这两类白云岩具有相对较好的物性条件,对川东南地区储层发育具有重要意义。     

以PAC为原料合成锂吸附剂的工艺研究

研究了聚合氯化铝（PAC）为原料合成锂吸附剂的基本工艺路线,并探究了加料方式、反应物配比、反应温度、反应时间和加料速度等对所合成吸附剂吸附量的影响,研究结果表明配比是影响吸附剂吸附量的最主要因素,得到了最佳合成条件,在此条件下所合成吸附剂对锂离子的吸附容量为6.1mg/g。推断吸附剂的主要成分为晶态或非晶态的LiCl·2Al(OH)3·nH2O,同时含有Al(OH)3、(CaO)3Al2O3·6H2O及 LiCl·H2O等成分。从吸附结果来看,结晶度较差的片状LiCl·2Al(OH)3·nH2O和非晶态的Al(OH)3为主成分的吸附剂吸附性能最好。     

基于ARM的温度采集与以太网传输系统的设计

基于ARM的温度采集与以太网传输系统重点是实现稳定地采集实时温度、批量传送采集结果。系统采用基于ARM内核LPC2214对温度传感器LM235输出的模拟信号进行采集;用DM9000控制以太网传输采集结果。基于DM9000的以太网传输具有较高的可靠性,适合批量数据传输,并且可实现较远距离通信。此外,为方便调试和扩展,设计串口通信模块和JTAG仿真调试接口模块。最终,实现对温度的实时采集与传输。