Adsorption of aqueous Pb(II), Cu(II), Zn(II) ions by amorphous tin(VI) hydrogen phosphate: an excellent inorganic adsorbent

Amorphous tin(VI) hydrogen phosphate (ATHP) was synthesized using the liquid phase precipitation method and served as an adsorbent to remove Pb(II), Cu(II), and Zn(II) from aqueous solutions. The ATHP was characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption techniques. Adsorption properties were evaluated as a function of pH, reaction time, concentration of reactants, and salinity. Their equilibrium adsorption data were modeled using Freundlich, Langmuir, and Dubinin–Kaganer–Radushkevich isotherms, respectively. The results revealed that adsorption equilibrium reached within 180 min. ATHP indicated good adsorption even below the pH_ZPC, and best adsorption at pH 5 for Pb(II) and Cu(II) and at pH 5.5 for Zn(II) was observed. Equilibrium data fitted better to the Langmuir model for Pb(II) and Cu(II) and fitted better to the Freundlich model for Zn(II). The saturated adsorption capacities deduced from the Langmuir model were 2.425, 1.801, and 0.600 mmol/g for Cu(II), Pb(II), and Zn(II), respectively, indicating an adsorption affinity order of Cu > Pb > Zn. There is a negative correlation between the concentration of NaCl and adsorption capacity of ATHP, yet ATHP still exhibited excellent adsorption having an adsorption capacity of 19.35, 15.16, 6.425 mg/g when the concentration of NaCl was 0.6 mol/L. The free energy (E) was 12.33, 10.70, and 14.74 kJ/mol for Pb(II), Cu(II), and Zn(II), respectively. An adsorption mechanism based on ion exchange between heavy metal ions and H⁺ in the ATHP is proposed. Furthermore, the used ATHP was regenerated by HCl solution and the adsorbent was used repeatedly.     

Autonomic visiting in digital 3D scenes

Human-machine interactive visiting and fixed-route visiting are currently the main roaming modes in digital three-dimensional (3D) scenes. However, in general, when a person visits an attraction area, s/he does not follow a fixed path, but instead wander about according to his/her interests. Here, we propose a new roaming mode, called autonomic visiting. That is, in a digital 3D scene, a user selects several interest spots, then a route connecting these spots can be automatically determined and 3D scene can be seen along this route. This study presents a technical approach that enables the realization of autonomic visiting in 3D scenes. Firstly, Delaunay triangular meshes for the terrain in 3D scene are established. Secondly, a plane-growth algorithm and a line-connection algorithm are introduced to automatically mend the broken parts of these triangular meshes. Thirdly, the triangular meshes are then merged and differently weighted according to different layers. Finally, a progress-zone transmission algorithm is presented to optimal the shortest route, which is derived from A-Star (A*) algorithm. Digital 3D campus of Nanjing University, China, is taken as the experimental materials. The experimental results prove the effect of the proposed approach.     

Sand eddies induced by cyclic tilt of a retaining wall

The cyclic tilt of a retaining wall induces a peculiar motion in the backfill (sand), which exhibits closed trajectories (eddies). In this paper, the motion of the backfill has been optically traced and analyzed by means of particle image velocimetry, also known as digital image correlation. The results are of importance for cyclically loaded structures (e.g, piles for off-shore structures) and can also serve to test numerical simulations of large deformation.     

Simulating train moving loads in physical model testing of railway infrastructure and its numerical calibration

Ballastless high-speed railways have dynamic performances that are quite different from those of conventional ballasted railways. The essential dynamic characteristics of high-speed railways due to passing train wheels, such as the cyclic effect, moving effect, and speed effect, were put forward and discussed. A full-scale accelerated railway testing platform for ballastless high-speed railways was proposed in this study. The feasibility of the sequential loading method in simulating train moving loads, and the boundary effect of the proposed physical model of ballastless railways, was investigated using three-dimensional finite element models. A full-scale physical model, 5 m long, 15 m wide, and 6 m high, was then established according to practical engineering design methods. Using a sequential loading system composed of eight high-performance hydraulic actuators, loads of a moving train with highest speed of 360 km/h were simulated. Preliminary experimental results of vibration velocities were presented and compared with field measurements of the Wuguang high-speed railway in China. Results showed that the experimental results coincided with the field measurements, demonstrating that the full-scale accelerated railway testing platform can simulate the process of a moving train and realistically reproduce the dynamic behaviors of ballastless high-speed railways.