淮北煤田煤中汞的赋存状态

系统采集淮北煤田10、7、5、4和3煤层的29个煤样品, 采用逐级化学提取方法研究了煤中汞的赋存状态, 根据提取步骤和汞的特性, 将煤中的汞分为水溶态、离子交换态、有机态、碳酸盐结合态、硅酸盐结合态和硫化物结合态, 利用Flow Injection Mercury System(FIMS)分析了样品中总汞和不同形态中汞的含量.测试结果表明, 与华北石炭-二叠纪煤、中国煤以及美国煤含量相比较, 淮北煤田煤中汞的含量明显富集.逐级化学提取实验结果和煤中汞与硫、灰分的相关分析结果表明, 岩浆的侵入对煤中汞的赋存状态有较大的影响, 不受岩浆侵入影响的10、4和3煤层煤中的汞主要以有机态和硫化物结合态存在, 受岩浆侵入影响的5和7煤层中的汞主要以硅酸盐结合态存在.      

龙门山的石炭系

四川江油马角坝、北川沙窝子是龙门山上泥盆统、下石炭统区域性主要岩石地层单位的命名地,对这两地及前龙门山北段地区的调查发现:1)前人关于马角坝地区下石炭统的层序和马角坝组主要化石群的记载有与实际不符之处,当地实际缺失杜内期至维宪早、中期地层,总长沟群的时代应属晚维宪—谢尔普霍夫期,重新厘定马角坝组含义,新指定北川桂溪沙窝子的长滩子剖面为该组的参考剖面;2)在长滩子剖面长滩子组顶部Beichuano-phyllum与Cystophrentis珊瑚化石富集层之上、马角坝组Pseudouralinia富集层之下的大套厚层白云岩层组合的中上部层位,发现Cystophrentis等化石,基于这套厚层白云岩组合的岩性特征明显、顶底接触关系清楚、区域展布广泛,建议引用前人提出的黑岩窝组,同时对黑岩窝组的岩性、岩层组合与古生物组合特征、厚度和时代归属等作了补充和修正,根据其中所含生物群认为黑岩窝组时代为晚泥盆世法门晚期;3)通过与周边地区的地层对比,探讨了龙门山石炭纪的古地理格局及环境演变,认为除前龙门山中部的桂溪—沙窝子等狭窄地区因长期地处泥盆纪海水入侵通道,地势低洼,出现了残存式的杜内期沉积外,前龙门山南、北段广大地区杜内期至维宪早、中期已大部抬升露出水面,直到维宪晚期的全球性海侵,前龙门山遂再度没于水下,出现准平原化浅滩相沉积环境,并延续至石炭纪末。     

乌兰图嘎超大型锗矿床含锗煤的矿物学

内蒙古乌兰图嘎锗矿是我国近年来发现的产在煤层中的超大型锗矿床,锗金属储量达1600 t。以乌兰图嘎超大型锗矿床的含锗煤为研究对象,利用X射线衍射(XRD)、带能谱的扫描电镜(SEM-EDX)和电子探针(EPMA)详细研究了乌兰图嘎含锗煤及其同时代的红旗煤矿无矿煤的矿物学特征。分析结果表明,乌兰图嘎含锗煤中的主要矿物包括石英、蒙脱石;次要矿物包括长石、高岭石、伊利石;另含少量三水铝石、角闪石、叶蜡石、石膏、绿泥石、锐钛矿、黄铁矿、方解石、白云石和草酸钙石;微量的锆石、闪锌矿、白钨矿、重晶石、黄铜矿、卤化物、磷酸盐以及含Pb、Bi、Cr、As和Sb矿物。未发现含锗矿物。推测含锗煤中的锗可能主要呈有机结合,而Ba、Zn、Ti、W、Pb、Bi、Cr、Fe、As、Zr、Sb、Cu和REE可能主要与矿物相结合。此外,首次在乌兰图嘎含锗煤及红旗煤矿无矿煤中发现含银颗粒或自然银,推测胜利煤田的褐煤可能有相当规模的Ag矿化。     

芙蓉锡矿方解石稀土元素地球化学特征及其对成矿流体来源的指示

方解石是芙蓉锡矿田重要的脉石矿物。根据芙蓉矿田白蜡水矿区和狗头岭矿区不同产状(云英岩型、蚀变岩体型和构造蚀变带-矽卡岩型)矿石中方解石稀土元素地球化学特征研究表明:两矿区成矿期热液方解石具有两种稀土模式,LREE(轻稀土元素)富集型和相对平坦型。其中,蚀变岩体型方解石所具有的相对平坦型稀土模式代表了LREE带出后残余热液的稀土模式特征,而云英岩型和构造蚀变带—矽卡岩型方解石的LREE富集型稀土模式与骑田岭新鲜花岗岩类似,表明成矿过程中没有LREE明显带出的迹象,残余热液继承了岩浆期后热液的特征。成矿流体来源于骑田岭花岗岩岩浆期后热液。     

Geochemical Characteristics and Genesis of Late Cretaceous to Paleogene Basalts in the Tuyon Basin, South Tianshan Mountains

1. Introduction The Tianshan Mountains is a typical intercontinental orogenic belt in the world. From late Carboniferous to Permian, the old Tianshan formed during the tectonic amalgamation of the Tarim block, Tianshan block and Siberia craton (Carroll et al, 1990). Mid-Cenozoic basalts are widely distributed in both the Tuyon basin of southwest Tianshan and its western part of Tianshan in Jierjisi in late Cretaceous-Paleogene period, which indicates the activation of the old Tianshan.…     

扬子陆块区东南缘碳硅泥岩型铀矿床与断陷红盆控矿机制

扬子陆块区东南缘是碳硅泥岩型铀矿床的重要矿集区,其中沉积一外生改造型和沉积一热液叠加改造型铀矿床均分布在断陷红盆边缘或附近。通过红盆与碳硅泥岩型铀矿床分布规律的研究,提出了碳硅泥岩型铀矿床与红盆边缘断裂的沟通效应和控矿机制,旨在强调红盆在找矿实践中的权重。     

Intensification of the East Asian Monsoon in Southern China at about 300–400 kaBP Inferred from Eolian Deposits in the Middle-lower Reaches of the Yangtze River

In the East Asian monsoon region,eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China.Typical eolian deposits in this region include upper Xiashu Loess(XL) and underlying Vermiculated Red Soil(VRS) layers.In this paper,chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang(JJ) city in northern Jiangxi province.A magnetostratigraphic study,combined with optically stimulated luminescence(OSL) dating,is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene,and that the boundary age between the XL and VRS layers is about 300-400 kaBP.In grain-size records of the JJ section,the median grain-size and content of the 30 μm size fraction increase sharply after 300-400 kaBP,representing an East Asian winter monsoon intensification event.Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP:there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP,implying an increase in precipitation caused by intensification of the East Asian summer monsoon.Global ice volume and uplift of the Tibet Plateau(TP) are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale.The deep-sea δ~(18)O record,which reflects variations in global ice volume,shows no obvious change after 300-400 kaBP.Moreover,the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse;the global ice volume increase(decrease) implies a strengthened(weakened) winter monsoon and weakened(strengthened) summer monsoon.We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene.This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau(CLP) and from the desert-loess transitional belt.However,it is not recorded in the loess-paleosol sequences from the central part of the CLP,thereby indicating differing climate responses to TP uplift in different regions,which requires further study.     

西藏得几蛇绿岩体中玻安岩的地球化学特征及其地质意义

西藏日喀则蛇绿岩是我国发育最好的蛇绿岩之一，目前有关日喀则蛇绿岩形成的构造背景存在多种不同的认识。作者在研究得几蛇绿岩剖面时发现存在玻安岩，从而为日喀则蛇绿岩具有弧前背景提供了直接证据。得几蛇绿岩中玻安岩类样品具有高硅、高镁、低铁的特征，岩石中Zr、Yb和Y的含量也较低，具有明显的玻安岩特征。根据这些岩石的地球化学性质，认为岩石是由早期经历过较高程度的部分熔融的残余在含水条件下再发生部分熔融形成的。得几蛇绿杂岩体部分形成于弧前环境。     

陕西金矿床类型及其找矿方向

通过对陕西金矿资源的分析、总结,将陕西金矿成因类型划分为7类14亚类;与金矿有关的成矿系列划分为3个矿床成矿系列组合,7个成矿系列类型,10个成矿系列和4个亚系列;金矿床空间分布严格受隐伏基底和出露基底,隐伏岩体、重磁吻合构造,构造和成矿时代的控制;与金成矿有关的Ⅲ级成矿区(带)有4条,有关的Ⅳ级成矿区(带)有10条,有关的Ⅴ级主要金成矿区(带)有16条;提出了金矿新的找矿方向,为今后本区金矿地质找矿的新突破提供信息.     

基于变动范围法(RVA)的信江水文改变及生态流量研究

选择信江下游梅港站1950~2010年日径流量,根据流域大型水库界牌枢纽运行时间将梅港站径流序列分为建库前(1953~2001)和建库后(2002~2010)两个时段。采用变动范围法(Range of Variability Approach,简称:RVA)分析水库运行对下游梅港站流域生态水文指标改变度,并分析了信江下游生态流量。研究表明:33个水文指标有22个发生中高度改变,11个指标发生低度改变,其水文综合改变度为0.51,属于中度改变;梅港站生态流量值均在RVA阈值内,基本能够保持河流稳定流量,但2月、7~9月及12月河道生态流量大于RVA下限。可适量增大水库下泄水量,降低对下游河段生态系统的威胁。