Modeling the biodegradation of multicomponent organic matter in an aquatic environment: 2. Analysis of the structural organization of lignin

A model is developed to describe the degradation kinetics of an organic substance with chaotic structure of macromolecules. The model is based on the results of analysis of lignin structure and its degradation mechanisms described in previous papers of this series. Model postulates are formulated and their chemical substantiation is given. Degradation regimes corresponding to different molecular size distributions are studied. The decrease in organic carbon concentration at the asymptotic stage of the process is shown to obey the power law. Theoretical results were checked against some empirical data taken from the literature.     

Probabilistic stability assessment of slopes using high dimensional model representation

This paper presents a new computational tool for probabilistic stability assessment of earth slopes/embankments. The method involves high dimensional model representation (HDMR) that facilitates lower dimensional approximation of the original limit state, response surface generation of HDMR component functions, and Monte Carlo simulation. HDMR is a general set of quantitative model assessment and analysis tools for capturing the high-dimensional relationships between sets of input and output model variables. It is a very efficient formulation of the system response, if higher-order variable correlations are weak, allowing the physical model to be captured by the first few lower-order terms. Once the approximate form of the original limit state is defined, the failure probability can be obtained by statistical simulation. Results of four numerical examples indicate that the proposed method provides accurate and computationally efficient estimates of the failure probability of earth slopes/embankments.     

Implications of the colour distribution in the galaxy M82

Photographic measurements of the colour distribution in the irregular galaxy M82 are presented and interpreted in terms of a model of that galaxy. Two alternative models are discussed. In the first the galaxy consists of a disc of highly reddened OB-stars, whose scattered light is also seen in the halo, and a bulge of less reddened A—F stars. The direction of the inclination of the system, as inferred from this model, is opposite to that of LYNDS and SANDAGE (1963). The alternative inclination (second model) may possibly be preserved if one assumes a central dust ellipsoid reemitting scattered light from a central source of OB stars. If the velocities of the line emitting material refer to scattering particles, an inward motion of them is more probable than an outward one, irrespectively of the model, and the (dust) halo of the galaxy is probably contracting.     

Minimum on the light curve of the classical symbiotic star AS 338 in 1999

We present our UBVRI photometry and spectroscopy of AS 338 performed in 1999–2000. Another eclipse of the hot component in this symbiotic binary system, the deepest one ever observed, occurred in September 1999. The U brightness declined by ～2^m, the Hβflux decreased by a factor of ～2.3, and the [O III]γ5007 flux did not change. The hot component is eclipsed at orbital phases ?≈0.045–0.057. The U-B color index begins to appreciably fluctuate during an eclipse of the hot component and its circumstellar envelope. About 100 days after a strong outburst of 1995, the mean UBV brightness of AS 338 declined linearly in the ensuing five years at the same rate in all bands (ΔU/Δt≈10^?3 mag/day). The brightness of the outer, uneclipsed parts of the circumstellar envelope also decreased, which is attributable to a reduction in the luminosity of the hot component against the rise in its temperature. The appearance of He II lines has not yet been recorded, though the optical brightness of AS 338 has already dropped by ～2^m after the outburst.     

Melting of corundum using conventional and two-phase molecular dynamic simulation method

The melting curve of corundum is calculated by using two approaches: the first one is conventional and the second one is two-phase molecular dynamics method both utilizing the same pairwise interatomic potential developed earlier on. The melting curve obtained by the two-phase simulation method is in agreement with the existing experimental data up to 25 GPa. A comparison of melting curves obtained by a two-phase simulation method and a conventional molecular dynamic method in NPT ensemble demonstrates a substantial overestimation of melting temperatures when applying conventional molecular dynamic technique. The inaccuracy of the conventional method increases with increasing pressure and, in the case of corundum, changes from about 300 K at 1 bar to about 1000 K at 1 Mbar. Received: 25 November 1996 / Revised, accepted: 11 March 1997     

Principal Components Analysis of Rainfall and Associated Synoptic Models of the Southwest Monsoon over India

Summary  The summer monsoon circulation shows various spatial and temporal oscillations and often a combination of systems produces an integrated effect. In this study phases of the southwest (SW) monsoon have been identified in an objective manner with the help of T-mode principal component analysis (PCA) of weekly rainfall anomalies. Mean composite charts have been prepared utilising all available upper air data (1977–1986) for each category of the SW monsoon epochs identified by the PCA. These sets of charts have been constructed for both the strong and weak phases associated with the first four significant principal components (PCs). A well defined east-west oriented trough system, extending from about 28° N Latitude/65° E Longitude to 20° N Latitude/90° E Longitude, in the lower levels, has been the main feature associated with the strong phase of the monsoon corresponding to PC I. The trough in the lower levels is more marked in the eastern half compared to the western half in both the sets of charts associated with strong phases of the monsoon related to the PC II and PC III. With PC II, the position of the troughs in the lower levels is further north of its location in PC III. The east-west trough system associated with the strong phase of PC IV has a large southward tilt with height. The charts corresponding to the weak phases of these PCs have synoptic features, such as the position of the trough close to the foothills of the Himalayas, and the shifting of middle and upper tropospheric anticyclones to the south. The study suggests an objective method of interpretation of principal components by utilising synoptic data. In addition, synoptic models and data sets corresponding to different phases of the monsoon can also be prepared in an objective manner by such PCA. Received July 18, 1997 Revised April 30, 1999     

Influence of food web structure on the biochemical composition of seston,zooplankton and recently deposited sediment in experimental freshwater mesocosms

The effects of food web structure on the quantity and biochemical composition of seston, zooplankton and recently deposited sediment in experimental freshwater mesocosms were examined. Food web structure was manipulated by addition of zooplanktivorous fish. Biochemical characterisations were carried out using lipid biomarkers (sterols, fatty acids, chlorophyll-derived compounds and long-chain alkanediols). Fish addition decreased zooplankton biomass and increased seston biomass and deposited sediment through a trophic cascade. Fish presence strongly influenced the biochemical characteristics of seston and sediment. In contrast, food web structure had a minor impact on the lipid biomarker composition of zooplankton. Although the relative abundance of sterols in the different compartments did not differ strongly between treatments, sterol profiles in seston and sediment depended on food web structure. The predominance of Δ⁷-sterols in seston and sediment in the fish treatment indicated a major contribution of Chlorophyceae. In contrast, the distribution of sterols in seston and sediment in the fishless treatment, dominated by cholesterol, indicated a major zooplanktonic input. The distribution of fatty acids and the relative abundance of chlorophyll-derived compounds and long-chain alkanediols agreed with the predominant contribution of phytoplankton or zooplankton to seston and sediment in the two treatments. The relative abundance of bacterial biomarkers suggested that the contribution of bacteria was rather low. The high relative abundance of polyunsaturated fatty acids (PUFAs) and the absence of stanols in sediments suggested low microbial reworking of organic matter in the recently accumulated sediments. The trophic cascade, generated by the addition of fish, increased the relative abundance of PUFAs in deposited organic matter, thus enhancing sediment quality and potential degradability.