Metallic ore mining causes heavy metal pollution worldwide. However, the fate of heavy metals in agrosystems with long-term contamination has been poorly studied. Dongchuan District (Yunnan, southwest China), located at the middle reaches of the Xiaojiang River, is a well-known 2000-year-old copper mining site. In this work, a survey on soil heavy metal contents was conducted using a handheld X-ray fluorescence instrument to understand the general contamination of heavy metals in the Xiaojiang River Basin. Furthermore, river water, soil, and rice samples at six sites along the fluvial/alluvial fans of the river were collected and analyzed to implement an environmental assessment and an evaluation of irrigated agrosystem. V, Zn, and Cu soil levels (1724, 1047, and 696 mg·kg−1, respectively) far exceeded background levels. The geo-accumulation indexes (Igeo) showed that cultivated soils near the mining sites were polluted by Cd and Cu, followed by Zn, V, Pb, Cr, Ni, and U. The pollution index (Pi) indicated that rice in the area was heavily polluted with Pb, Cr, Cd, Ni, Zn, and Cu. The difference in orders of metal concentrations between the soil and rice heavy metal contamination was related to the proportion of bioavailable heavy metals in the soil. The crop consumption risk assessment showed that the hazard quotient exceeded the safe threshold, indicating a potential carcinogenic risk to consumers. The Nemerow integrated pollution index and health index indicated that the middle of the river (near the mining area) was the heaviest polluted site.
Based on the data observed at two sites (site H1, 4,473 m a.s.l., and site H2, 4,696 m a.s.l.) on Qiyi Glacier in Qilian Mountains, China, by automatic weather station and spectral pyranometer during the period of June 9 through September 27, 2006, we investigated the temporal and spatial variations in surface albedo and spectral reflectance on the glacier. At site H1, the daily mean surface albedos fluctuated between 0.233 and 0.866, which were significantly affected by the air temperature on the glacier. It was found that the albedos clearly showed a diurnal cycle with the lowest value at noon at the two observation sites over the study period, and the difference of albedos between the upper site H2 and the lower site H1 also showed diurnal cycle but with the highest value at noon. The reflectance on the glacier was higher in the ultraviolet (0.28-0.4 μm) and visible (0.4-0.76 μm) wavelengths, lower in the near infrared wavelength (0.76-3 μm), which is quite contrary to the spectral reflectance on other ground surfaces. At the two observation sites, the spectral reflectance declined in all wavelengths with the ablation of snow generally. However, it declined drastically in ultraviolet (0.28-0.4 μm) and 0.6-0.7 μm wavelength, and declined less in 0.4-0.5 μm wavelength. On fresh snow surface, the spectral reflectance had the high values of 0.983 and 0.815 in the ultraviolet and visible (0.4-0.76 μm) wavelengths, respectively; but it had a relatively lower value of 0.671 in near infrared (0.76-3 μm) wavelengths. However, on dirty and melting ice surfaces, the reflectance had the very low values of 0.305 and 0.256 in the ultraviolet and visible wavelengths, with the lowest value of 0.082 in near infrared wavelengths. The spectral reflectance also showed a diurnal cycle like that of albedo. The diurnal variations of spectral reflectance on snow surface in ultraviolet and visible wavelength changed to a greater degree than that on ice surface. The diurnal variation curves were asymmetrical before and after t 相似文献