Hydrogeological and Gasgeochemical Earthquake Precursors – A Review for Application

Even if earthquake precursory signals can be identified, how can they be useful? This paper investigates relationships among the attributes of 229 proposed earthquake related gasgeochemical and hydrogeological precursory signals, and applies these results to improve future earthquake prediction strategies. Sub-groups of these reported signals and relationships between sub-groups are established using parameters, including earthquake magnitude, signal duration, precursory time, and epicentral distance to the monitoring site (original studies are used wherever possible to improve data quality). A strong correlation (r=0.86) between signal duration and precursory time was identified. This suggests a relationship between the investigated precursory signals and tectonic processes related to the referenced earthquakes. Moreover, these signals are categorized into four groups, reflecting differences in monitoring station densities, measurement methods and physical processes related to signal occurrence: (a) radon exhalation from the earth’s crust, (b) exhalation of other gases (helium, argon and others), (c) temporal variation in water level or discharge of springs and (d) temporal variation in temperature and dissolved ions in the water of the monitoring sites. In addition, boundary functions are used to separate signal group subsets. Finally, it is shown how these boundary functions can be used in the context of an earthquake prediction strategy by identifying potential minimum magnitudes and maximum epicentral distances from the monitoring site.     

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

Microbarograph

The microbarograph of a new design has been offered, and the general principle of its operation is considered. The microbarograph is distinguished from well-known ones; it incorporates a compensatory spring eliminating a zero-point drift of the measuring spring, two additional springs that upgrade the angular displacement sensitivity of the microbarograph, and a control and calibration block that makes it possible to perform the remote calibration of the microbarograph and to control it.     

Adjustments by the Charwell River, New Zealand, to uplift and climatic changes

Major climatic changes and rapid local and regional tectonic movements were common in New Zealand during the late Quaternary and caused a diversity of adjustments in the drainage-basin and piedmont reaches of the Charwell River, which are separated by the Hope Fault. The onset of semi-arid, frigid climates during the latest Pleistocene probably greatly increased hillslope sediment yields in a periglacial environment, and the piedmont reach aggraded as much as 42 m on top of a broad strath. With the return of humid, mesic climates in the Holocene sediment yields decreased as dense forests again mantled the slopes, and the piedmont reach degraded as mush as 81 m. Dating of eleven cut-and-strath terraces by radiocarbon-calibrated weathering rind measurements on greyawake cobbles shows the degradation rates varied greatly during the last 14 ka (1 ka = 1000 yr). Initial degradation rates of < 4 m ka⁻¹ increased to 30 m ka ⁻¹ by 6 ka ago during a mid-Holocene climatic optimum. Since 4 ka ago degradation rates have been only 1.2 m ka⁻¹, comparable to uplift rates in the piedmont reach inferred from marine-terrace studies, and the river is again cutting a broad strath. Each broad strath represents equilibrium conditions attained by this powerful stream during interglacial times despite episodes of being overwhelmed by climatically induced sediment-yield increases during full-glacial climates and having to maintain a long-term degradation rate equal to the uplift rate.The 75–81 m of degradation since formation of the latest Pleistocene fill-terrace tread is the sum of the amount of late Pleistocene valley-floor aggradation and the amount of regional uplift that occurred between the estimated times of major strath formation at about 30 and 0 ka. The 39 m of tectonically induced degradation below the pre-aggradation strath is sufficiently large that post-30 ka uplift may have doubled Holocene degradation rates.Each of the eleven degradation terraces represents pauses of a few centuries in Holocene downcutting. Brief equilibrium conditions were attained by streambed armoring and concurrent growth of riparian plants; both processes progressively increased hydraulic roughness and the shear stresses needed to entrain streambed materials. Occasional floods, possibly from rare cyclones derived from tropical moisture sources, destroyed streambed armor and channel downcutting was renewed. Thus the formation of eleven equilibrium terraces can be accounted for without postulating additional tectonic perturbations or secular climatic changes.     

Morphotectonic evaluation of the Delhi region in northern India,and its significance in environmental management

This paper deals with the morphotectonic evaluation of the Delhi region in northern India to understand its impact on land use and urban development. To accommodate heavy urbanization and population rise (being the capital of India), the area has undergone tremendous environmental degradation resulting from a mismatch between adopted land use and morphotectonic considerations. The geomorphic and drainage signatures of the region have evolved out of interaction of varied geological parameters including neotectonic activities. We have evaluated the changes in the drainage pattern of the Yamuna River in the Delhi region to underline its significance in geomorphic evolution and subsequent land use and/or land suitability. The Yamuna River has shown variations both in channel position and geometry over the last two centuries. The observed migration pattern of the river (shifting of confluences, position and disposition of palaeochannels, etc.,) cannot be attributed to normal river phenomenon and appears to have been effected by neotectonic changes. In addition, some case studies are discussed to underline the significance of geomorphic factors in urban development.     

Structure and crystal chemistry of a dense polymorph of tricalcium phosphate Ca3 (PO4)2: A host to accommodate large lithophile elements in the earth's mantle

A phase of Ca₃ (PO₄)₂, synthesized at 12GPa and 2300° C, is structurally analyzed by the single crystal X-ray diffraction method. This Ca₃(PO₄)₂ is found to be a dense polymorph of tricalcium phosphate isostructural with Ba₃ (PO₄)₂ and named γ-Ca₃ (PO₄)₂. In the structure of Ca₃ (PO₄)₂, a phosphorus atom is tetrahedrally coordinated by oxygen atoms and calcium atoms occupy two types of large metal sites. The Ca(1) site has twelve oxygen neighbours with the mean bond length of 2.739 Å while the other Ca(2) site is coordinated by ten oxygen atoms with the mean Ca-O distance of 2.588Å. The structure is characterized by the translationally interconnected polyhedral sequence PO₄-Ca(2)O₁₀-Ca (1)O₁₂-Ca (2)O₁₀-PO₄ in the direction of the c axis. This dense phase of Ca₃(PO₄)₂ with two large metal sites may be an important host for very large lithophile elements in the deep upper mantle of the earth.     

Mineralogy and chemistry of bentonite (?) deposits at Minjingu, Lake Manyara, North Tanzania

Olive green clays likely to be bentonitic in composition have been mineralogically and chemically studied. They occur in association with other lacustrine sediments at Lake Manyara. Radiocarbon dates from four diatom horizons indicate ages ranging from 12 Ka to 135 Ka suggesting a Mid-Holocene age. Middle Pleistocene age have been assigned to the ridged oncolites of Lake Manyara. The olive green coloured clays in the Manyara basin are known to occur in association with other lake beds including phosphorite deposits, stromatolites, bioturbated silty clays, partly silicified marls, conglomerates and olive green coloured opal beds. The results presented herein are from the olive green coloured clays. The olive green clays (bentonite?) are a result of devitrification or alteration of volcanic ashes and/or pyroclasts. The green clays occur in different forms as they are separated from each other by other lacustrine sediments. The alteration might have taken place in slightly different environments in terms of salinity and alkalinity. One of the top layer is friable and shows conchoidal fractures when dry. The other beds below in the lacustrine sequence are cemented with calcite and some dolomite as well as zeolites. The lowermost layer in the sequence is friable and shows cracks filled with coarse crystalline calcite. Mineralogically the bentonite is composed of the clay minerals illite, illite-smectite mixed layer clays, and chlorite. Other authigenic minerals include various zeolites (analcime, clinoptilolite, erionite and some traces of mordenite), opal, and fluorapatite. The clays have magnesium contents varying from 3.01% to 7.43%. The calcium contents vary widely due to presence or absence of one of the two minerals calcite or apatite. Trace elements like Ba, Ce, Sr, Zr are equally attributed to the presence of calcite and apatite. The formation of the illite-smectite mixed layer clays in an alternating manner with other lake sediments depicts different episodes of volcanic eruptions in the area. The mineralogical composition of smectites, zeolites, and opal in the green clays suggests a deposition of pyroclasts and volcanic ashes in a closed lake system with fluctuating levels. Due to evaporation alkalinity and salinity levels were fluctuating. The clays might have been bentonite which have undergone illitisation, a phenomena noted in other neighbouring rift basins.