Evaluation of daily precipitation in China from ECMWF and NCEP reanalyses

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Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Particle size distribution and dissolution properties of metals in cyclone fly ash

The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution.     

Zur Sedimentologie eines arktischen Deltas (Colville Delta,Nordalaska)

Zusammenfassung Im August 1971 wurden vom Verfasser Feldarbeiten zur Sedimentologie des Colville Deltas, Alaska, durchgeführt. Aus subaquatischen Typlokalitäten wurden Probenkerne gezogen und auf Strukturen, Korngrößen und Mineralogie hin untersucht. Neben konventionellen Labormethoden kamen moderne elektronische Verfahren zum Einsatz (Röntgenradiographie, Röntgendiffraktometrie, Elektronenmikroskopie). Die Arbeiten sind Teil eines Programmes, dessen Gesamtleitung Prof. Dr. H. J. Walker, Baton Rouge, USA, hatte und das unterstützt wurde von: Arctic Program and Geography Programs, Office of Naval Research.

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In August 1971, sedimentological field work was carried out by the author in the Colville River delta, Alaska. Short cores were taken from several deltaic environments and analyzed for structure and composition. Laboratory analysis included both conventional laboratory methods and modern electronic techniques (radiography, X-ray diffractometry, electron microscopy). The research reported is part of a program headed by Prof. Dr. H. J. Walker, Baton Rouge, USA, and was supported by the Arctic Program and Geography Programs, Office of Naval Research.

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Résumé En auguste 1971 l'auteur a étudié sur le terrain la sédimentologie du delta de Colville (Alaska). On a prélevé des échantillons dans des profiles de divers environnements typiques; on en a examiné les structures et la composition par les méthodes traditionelles et électroniques (rayons X, radiographie et diffractométrie, microscope électronique). Ces investigations font partie d'un programme sous la direction du Prof. Dr. H. J. Walker, Baton Rouge, USA, subventionné par »Arctic Program and Geography Programs, Office of Naval Research«.

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1971 . , . , . , - , . , . . H. J. Walker, Baton Rouge, USA Arctic Program, and Geography Programs, Office of Naval Research.

     

ON LOPINITE,A NEW TYPE OF COAL IN CHINA

To the east of Nanchang,the capital of Kiangsi Province,there cropsout a continuous belt of Permian coal series~1 trending approximately in thedirection from N.E.to S.W.Broadly speaking,this coal belt forms a synclinal     

Projection of Future Precipitation Extremes Change (2001-2050) in the Yangtze River Basin

 Daily maximum rainfall (R1D) was higher in the Jialing River basin, the Taihu Lake area and the mid-lower main stream section of the Yangtze River basin in the 1990s, and there was a good relationship between ECHAM5/MPI-OM model simulation and the observed data about extreme precipitation (R1D). Under the IPCC SRES A2, A1B, and B1 scenarios, R1Ds are all projected to be in increasing trends in the upper Yangtze River basin during 2001-2050, and R1D shows a more significant increasing tendency under the A2 scenario when compared with the A1B scenario before 2020. With respect to the middle and lower Yangtze River basin, an increasing tendency is projected before 2025, and since then the increasing tendency will become insignificant. There might be more floods to the south of the Yangtze River and more droughts to the north in the next decades.     

A note on the performance of the multiply-upstream semi-Lagrangian advection schemes for one-dimensional nonlinear momentum conservation equation

Summary Two-time-level multiply-upstream semi-Lagrangian schemes were examined in the case of the self-advecting, one-dimensional nonlinear momentum conservation equation. The shock formation process was analyzed. It is pointed out that the shocks cannot be created in the truncated systems satisfying the Pudykiewicz, Benoit and Staniforth criterion.The numerical integrations were restricted to 12 h. It was shown that, at least in the sub-CFL range, increased complexity of the scheme can compensate reduced horizontal resolution. A considerable sensitivity of the schemes with respect to the time step was detected. In the super-CFL mode, several windows on various time scales were found within which the Pudykiewicz, Benoit and Staniforth criterion was satisfied. The time step of 1.44 times the maximum time step allowed by the CFL criterion was used in the semi-Lagrangian runs.The super-CFL, semi-Lagrangian solutions were diverging progressively from the sub-CFL ones as the forecasts advanced. This was also reflected in the energy spectra.Unacceptably large energy losses were encountered in the super-CFL, semi-Lagrangian runs. Most of these losses could be explained by the reduced mean wind speed, i.e., the amplitude of the zero wavenumber wave. At the same time, the energy content in the shorter waves increased. In a more complex model, such a situation would resemble a loss of zonal, and an increase of transient eddy kinetic energy.A trajectory error measure was defined as the maximum absolute value of the distance between the actual arriving point of the particle originating at the estimated departure point, and the grid point assumed to be the arrival point in the semi-Lagrangian procedure. In contrast to the sub-CFL regime, this measure could reach a considerable fraction of the grid distance in the computations with the super-CFL time steps.In the physical system considered, the trajectories are determined only by the velocities at the departure points. With the semi-Lagrangian schemes the distances traveled by the particles are estimated on the basis of the velocities at the points downstream with respect to the departure points. Thus, unless the solution is smooth (in space and time) on the scales of the extrapolation distances/times, the upstream extrapolation does not promise the convergence of the solution.With 16 Figures