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991.
Janette Tourney Bryne T. Ngwenya J.W. Fred Mosselmans Laurence Tetley Gregory L. Cowie 《Chemical Geology》2008,247(1-2):1-15
This study investigated proton adsorption to an extracellular polymeric substance (EPS) producing bacterial strain, Bacillus licheniformis S-86, in order to characterise and quantify the contribution made by EPS to cell surface reactivity. Potentiometric titrations were conducted using both untreated cells and cells from which the EPS layer had been extracted. Surface-complexation modelling indicated the presence of four different functional groups in both untreated and EPS-free cells. These sites are assigned to phosphodiester, (pKa 3.3–3.4), carboxylic (pKa 5.3–5.4), phosphoryl/ (pKa 7.4–7.5) and hydroxyl/amine (pKa 9.9–10.1) type groups. The pKa values for the four groups were very similar for untreated and EPS-free cells, indicating no qualitative difference in composition, but site concentrations in the untreated cells were statistically found to be significantly higher than those in the EPS-free cells for the pKa 3.3–3.4 and pKa 9.9–10.1 sites. Infrared analysis provided supporting evidence that site 2 is carboxylic in nature but did not reveal any difference in IR absorption between the native and EPS-free cells. Dissolved organic carbon (DOC) analysis conducted during this study indicated that DOC release by cells is significant, and that the EPS layer is the major contributor. 相似文献
992.
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment. 相似文献
993.
Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The 176Hf/177Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic 176Hf/177Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system. 相似文献
994.
Paul R. Craddock Olivier J. Rouxel Lary A. Ball Wolfgang Bach 《Chemical Geology》2008,253(3-4):102-113
We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical. 相似文献
995.
Using ALSM to map sinkholes in the urbanized covered karst of Pinellas County,Florida—1, methodological considerations 总被引:1,自引:0,他引:1
Larry D. Seale Lee J. Florea H. L. Vacher Robert Brinkmann 《Environmental Geology》2008,54(5):995-1005
Comparison of a database of interpreted sinkholes made using airborne laser swath mapping (ALSM) with databases of sinkholes
made from interpretation of aerial photographs reveals substantial disagreement. The discrepancies involve the location, number,
areas, and circularity of interpreted sinkholes. Methodological factors that contribute to the discrepancies include blockage
of ALSM laser returns in thick vegetation, multi-path reflections, and misrepresentation of the true extent of sinkholes.
Comparison of two ALSM-derived databases made (1) independently from versus (2) in combination with earlier air photo analysis
in undeveloped regions had the following result: one-fourth of the sinkholes interpreted by using the composite method were
missed by the independent analysis, and one-third of the sinkholes that were interpreted from the independent analysis were
not interpreted as sinkholes using the composite method. Subjective interpretation leads to a high level of uncertainty such
that the results of the remote sensing studies are suspect, if not invalid. 相似文献
996.
Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis 总被引:1,自引:0,他引:1
Konstadinos N. Moutsopoulos Alexandra Gemitzi Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090
The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection
zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the
present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying
a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a
wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield
delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem. 相似文献
997.
The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters
and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption
were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the
metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary.
As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of
estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important
in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals
remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L−1). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto
SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated
using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during
mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary
can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural
SPM as a simple surfaced molecule. 相似文献
998.
The carbonate-rock aquifer in the Great Valley, West Virginia, USA, was evaluated using a database of 687 sinkholes and 350
specific capacity tests to assess structural, lithologic, and topographic influences on the groundwater flow system. The enhanced
permeability of the aquifer is characterized in part by the many sinkholes, springs, and solutionally enlarged fractures throughout
the valley. Yet, vertical components of subsurface flow in this highly heterogeneous aquifer are currently not well understood.
To address this problem, this study examines the apparent relation between geologic features of the aquifer and two spatial
indices of enhanced permeability attributed to aquifer karstification: (1) the distribution of sinkholes and (2) the occurrence
of wells with relatively high specific capacity. Statistical results indicate that sinkholes (funnel and collapse) occur primarily
along cleavage and bedding planes parallel to subparallel to strike where lateral or downward vertical gradients are highest.
Conversely, high specific capacity values are common along prominent joints perpendicular or oblique to strike. The similarity
of the latter distribution to that of springs suggests these fractures are areas of upward-convergent flow. These differences
between sinkhole and high specific capacity distributions suggest vertical flow components are primarily controlled by the
orientation of geologic structure and associated subsurface fracturing. 相似文献
999.
In an attempt to delineate heavy metal contamination precincts and to evaluate the extent and degree of toxic levels, besides
their possible sources, 38 water samples from Ankaleshwar Industrial Estate, south Gujarat, India were analyzed. By clutching
geochemical analyses and GIS-based colour composites areas depicting anomalously high concentration of heavy metals (Mo, Zn,
Pb, Ni, Co, Cd, etc.) in the groundwater were revealed. The multicomponent overlays in grey-scale facilitated in identifying
situates of heavy metal ‘hot spots’, and lateral protuberances of the contamination plume around defile stretch of the main
stream Amla Khadi flowing through the area. The multiple pollution plumes emerging from other parts of the area further coincide
with effluent laden streams and small channels indicating industrial establishments as major sources of groundwater contamination.
Influent nature of the streams, accelerated infiltration process, high mass influx and shallow groundwater table are the factors
conducive for easy access of heavy metals to the phreatic aquifers affecting over 20 km2 area. On the basis of P/U ratios (concentration of metals in polluted water to unpolluted water), geogenic and anthropogenic sources have been identified.
Very high levels of technogenic elements present in the ground water raise concerns about possible migration into food crops,
as the area is an important horticultural locale and is highly cultivated. 相似文献
1000.
Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain) 总被引:1,自引:0,他引:1
J. Martínez J. F. Llamas E. de Miguel J. Rey M. C. Hidalgo 《Environmental Geology》2008,54(4):669-677
The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and
the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669
soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations
could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition,
we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four
factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb,
As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn,
As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels. 相似文献