Ab initio calculated electron densities for tetrahedral sheet [H2Si2O5]∞ in phyllosilicates

Periodic ab initio Hartree-Fock LCAO calculations have been carried out on the two dimensional sheet of SiO₄ tetrahedra, representing one of the basic constituting units of layer silicates, using Huzinaga's DZP basis sets. The influence of the basis set on the chemical bonding picture is characterized by Mulliken atomic charges and by electron density maps. Silicon atomic charges +1.6 ¦e¦ are more realistic than those +2.4 ¦e¦ reported for smaller basis sets. The silicon d orbital population is found to be 0.6 in close agreement with molecular data. Electron density maps indicate the absence of charge density in the center of the ditrigonal cavity. The charge buildup of nonbonding basal oxygen orbitals is directed mainly downwards perpendicular to the sheet plane.     

Geomagnetic activity as a possible cause of changes in the middle atmosphere and troposphere; observations made in Prague in the years 1932–1987

Summary A possible relation between the 10-day, 1-month, and 2-month geomagnetic as well as solar activity, characterized by Kp and Wolf's number R, and temperatures measured at the Prague-Klementinum meteorological station in January–February of the years 1932–1987 was sought. It was found that:1) Kp correlates with the temperature in Prague better than Wolf's number R.2) If the QBO phase is taken into account, the correlations improve.3) Even if the correlations improves with increasing length of the subintervals into which the individual winter periods (January-February) were derived, their statistical significance declines.     

Magnetic properties,self-reversal remanence and thermal alteration products of smythite

Summary This study is a follow up of the investigation of some magnetic properties and metastability of greigite in samples obtained from Miocene claystones in the Kruné hory (Erzgebirge) Piedmont basins (Bohemia). Three different methods of upgrading the smythite were applied; the magnetic properties of the concentrates are compared. The thermal conversion of smythite sets in at 200°C while greigite converts at 250°C. The first intermediate products to be formed are iron sulphides, marcasite clearly dominating over pyrite and pyrrhotite. Apart from a Fe³⁺ sulphate with a composition of Fe₂(SO₄)₃, oxidation of these sulphides gives rise to -Fe₂O₃. The result of the subsequent decomposition of the mentioned sulphate is the formation of -Fe₂O₃, which retains the sulphate structure. The final product of the thermal decomposition at 800°C is -Fe₂O₃. In the smythite concentrate the conversion to Fe³⁺ sulphate and -Fe₂O₃ is about twice as intensive as in greigite. No direct conversion to -Fe₂O₃ was found. During the thermal process self-reversals of remanence were observed, in various samples as many as four reversals in the temperature interval from 340 to 590°C. The occurrences of self-reversals of remanence were only observed at high degrees of thermal demagnetization, of the order of 10^–2 down to 10^–3 in the temperature interval of sulphide origin (below 400°C), and of the order of 10^–4 down to 10^–6 in the temperature interval of Fe-oxides origin (above 400°C).Presented at the 3rd Conference on New Trends in Geomagnetism, Castle of Smolenice, Czechoslovakia, June 22–29, 1992     

Dust particle and solar radiation

Influence of the solar radiation (electromagnetic and corpuscular - solar wind) on the motion of the interplanetary dust particle is investigated. The ratio time of inspiralling toward the Sun: time of inspiralling neglecting the change of mass of the particle is presented as a function of initial eccentricities.     

An analysis of close binaries (CB) based on photometric measurements (VII)

The paper is devoted to the actual problematics in the determination of orbital and physical parameters of active CB on the basis of the interpretation of photometric observations. One solves the problem in two stages: by obtaining a synthetic light curve in the case when the parameters of the corresponding CB model (Djuraevi, 1992a) are given a priori (direct problem) and by determining the parameters of the given model for which the best fit between the synthetic light curve and the observations is achieved (inverse problem) (Djuraevi, 1992b). In this paper, the above procedure is applied to a particular case of an interpretation of CB light curves AU Ser and RV Corvi.     

An analysis of close binaries (CB) based on photometric measurements (V)

The author considers the current problematics in the determination of the orbital and physical parameters for active close binaries (CB) of W Ser type based on the interpretation of photometric observations. In the particular case one analyses the light curves of CB RX Cas in the framework of the accretion-disc model explained in the second paper of this series (Djuraevi, 1992a). The change of the light curves with that of the system's physical-activity phase is analysed and the orbital and physical parameters of the system are determined for the maximum, minimum and the transition regime of the physical activity by applying the inverse-problem method described in the third paper of the series (Djuraevi, 1992b). In the paper a graphical illustration of the solutions obtained is also given.     

The Solar Corona 530.3 nm in the 20th cycle

The paper presents an analysis of the coronal data of emission line 530.3 nm. The analysis was carried out with data recorded at the coronal station of Lomnický tít for the period 1965–1976. Up till now the observed time and latitudal changes of the shape of the corona as well as the existence of two maxima have been fully proved. The development of intensities has, in many cases, different characters in the southern and northern hemispheres. Apart from this, the third increase of intensities in the course of the cycle was observed nearly at all latitudes in the coincidence with sunspot numbers in 1974–1975 years. The maximum of intensities of this impulse of activity was observed at latitudes around 60° in both hemispheres.     

Containment of an adiabatic plasma on magnetic lines of force by a self-generated electrostatic field

One component of a three-fluid adiabatic plasma is under certain conditions contained in a restricted region of space by a large-scale electrostatic field generated within the plasma. The containment is discussed here for plasma consisting of ions and two populations of electrons characterized by different pitch angle distribution functions.The bouncing motion of electrons along open fieldlines between a magnetic mirror and an electrostatic mirror produces a velocity distribution function similar to that generated by bouncing particles on closed fieldlines.     

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.