The most frequent interfaces in olivine aggregates: the GBCD and its importance for grain boundary related processes

Rocks consist of crystal grains separated by grain boundaries that impact the bulk rock properties. Recent studies on metals and ceramics showed that the grain boundary plane orientation is more significant for grain boundary properties than other characteristics such as the sigma value or disorientation (in the Earth’s science community more frequently termed misorientation). We determined the grain boundary character distribution (GBCD) of synthetic and natural polycrystalline olivine, the most abundant mineral of Earth’s upper mantle. We show that grain boundaries of olivine preferentially contain low index planes, in agreement with recent findings on other oxides (e.g. MgO, TiO₂, Al₂O₃ etc.). Furthermore, we find evidence for a preferred orientation relationship of 90° disorientations about the [001] direction forming tilt and twist grain boundaries, as well as a preference for the 60° disorientation about the [100] axis. Our data indicate that the GBCD, which is an intrinsic property of any mineral aggregate, is fundamental for understanding and predicting grain boundary related processes.     

Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.     

Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.     

Turning points in black holes astrophysics

Black hole astrophysics is expected to have a major breakthrough any day. Theoretical understanding is well advanced, so the breakthrough has to come from observers. Conclusive and direct evidence of event horizons, signatures of tidal deformation of gas clouds (and eventual disappearance of matter behind horizons) could be obtained in matter of months. At this juncture, we wish to summarize how the subject came to this stage and what is the state-of-the-art flow solution around a black hole. We touch upon the most crucial issue of (un)predictability of this subject. We believe that if viscosity is roughly what MRI simulations are pointing to us, we still require very detailed knowledge of properties of the companion, especially time dependent mass transfer from the companion to the black hole.     

Progressive failure leading to the 3 December 2013 rockfall at Puigcercós scarp (Catalonia,Spain)

A detailed analysis of the pre-failure behavior of the 3 December 2013 rockfall (1,012 m³) occurred on Puigcercós pilot study area (Catalonia, Spain) is presented. The exact date of failure was obtained based on a photographic monitoring performed every 4 h. The long-term monitoring (2,217 days) of the rock slope carried out by a Terrestrial LiDAR allowed the early detection of both pre-failure deformation and precursory rockfalls preceding the final failure. By means of the analysis of the pre-failure deformation, four different deformed areas were detected and the tertiary creep phase was observed in three of them. An attempt to predict the time to failure was performed using the Fukuzono’s (1985) method. Furthermore, the temporal evolution of the precursory rockfalls occurred in those four areas during the progressive failure showed a close resemblance with the exponential pattern of the cumulated displacements at tertiary creep stage. Finally, the study of the meteorological conditions did not show any single triggering factor associated with the final failure. Reversely, the increase in the occurrence of precursory rockfalls on several areas of the slope together with the observed acceleration on the deformation pattern reinforce the role of a progressive degradation of the stability conditions, which ultimately leaded to the 3 December rockfall event.     

川北早寒武世碳酸盐岩台缘斜坡沉积特征及变形构造形成机制探讨

基于对川北米仓山西部旺苍县鼓城乡唐家河下寒武统仙女洞组露头剖面的观察与镜下分析发现,仙女洞组下段由生物碎屑泥晶灰岩(L)、粉砂质泥岩(M)、似瘤状砾屑灰岩(L')、角砾灰岩(R)、藻凝块灰岩(A)和含生屑钙质砂岩(S)组合而成,其以角砾灰岩、似瘤状砾屑灰岩和藻凝块灰岩为特征,且发育异地岩块和滑塌变形构造。进一步分析认为:L-M岩石组合为正常的斜坡环境低能沉积;L'-R岩石组合中的角砾灰岩为上斜坡生物灰泥丘崩坍滑动至下部而形成的,似瘤状砾屑灰岩可能是由于L-M岩石组合快速沉积导致沉积物失稳滑动变形、上斜坡生物灰泥丘崩落角砾致使的差异压实和滑动、以及后期物质成分差异引起的压溶作用等共同作用的结果,从而使灰质层发生破碎并被泥质包围形成断续的砾屑状,甚至轻微的位移,进而形成条带特征不明显的杂乱变形构造;微生物岩(Mb)组合为上斜坡的灰泥丘沉积;S-M岩石组合为斜坡上部的浊流沉积。根据上述分析结果建立米仓山西部仙女洞组碳酸盐岩台缘斜坡沉积模式,表明仙女洞组沉积早期米仓山西部存在台缘斜坡相沉积。     

Refractory Black Carbon Results and a Method Comparison between Solid-state Cutting and Continuous Melting Sampling of a West Antarctic Snow and Firn Core

This work presents the refractory black carbon(rBC)results of a snow and firn core drilled in West Antarctica(79°55'34.6"S,94°21'13.3"W)during the 2014?15 austral summer,collected by Brazilian researchers as part of the First Brazilian West Antarctic Ice Sheet Traverse.The core was drilled to a depth of 20 m,and we present the results of the first 8 m by comparing two subsampling methods—solid-state cutting and continuous melting—both with discrete sampling.The core was analyzed at the Department of Geological Sciences,Central Washington University(CWU),WA,USA,using a single particle soot photometer(SP2)coupled to a CETAC Marin-5 nebulizer.The continuous melting system was recently assembled at CWU and these are its first results.We also present experimental results regarding SP2 reproducibility,indicating that sample concentration has a greater influence than the analysis time on the reproducibility for low rBC concentrations,like those found in the Antarctic core.Dating was carried out using mainly the rBC variation and sulfur,sodium and strontium as secondary parameters,giving the core 17 years(1998?2014).The data show a well-defined seasonality of rBC concentrations for these first meters,with geometric mean summer/fall concentrations of 0.016μg L^?1 and geometric mean winter/spring concentrations of 0.063μg L^?1.The annual rBC concentration geometric mean was 0.029μg L^?1(the lowest of all rBC cores in Antarctica referenced in this work),while the annual rBC flux was 6.1μg m^?2 yr^?1(the lowest flux in West Antarctica records so far).     

Comparison of three methods for estimating the sea level rise effect on storm surge flooding

Two linear methods, including the simple linear addition and linear addition by expansion, and numerical simulations were employed to estimate storm surges and associated flooding caused by Hurricane Andrew for scenarios of sea level rise (SLR) from 0.15 m to 1.05 m with an interval of 0.15 m. The interaction between storm surge and SLR is almost linear at the open Atlantic Ocean outside Biscayne Bay, with slight reduction in peak storm surge heights as sea level rises. The nonlinear interaction between storm surges and SLR is weak in Biscayne Bay, leading to small differences in peak storm surge heights estimated by three methods. Therefore, it is appropriate to estimate elevated storm surges caused by SLR in these areas by adding the SLR magnitude to storm surge heights. However, the magnitude and extent of inundation at the mainland area by Biscayne Bay estimated by numerical simulations are, respectively, 22–24 % and 16–30 % larger on average than those generated by the linear addition by expansion and the simple linear addition methods, indicating a strong nonlinear interaction between storm surge and SLR. The population and property affected by the storm surge inundation estimated by numerical simulations differ up to 50–140 % from that estimated by two linear addition methods. Therefore, it is inappropriate to estimate the exacerbated magnitude and extent of storm surge flooding and affected population and property caused by SLR by using the linear addition methods. The strong nonlinear interaction between surge flooding and SLR at a specific location occurs at the initial stage of SLR when the water depth under an elevated sea level is less than 0.7 m, while the interaction becomes linear as the depth exceeds 0.7 m.