Food availability and the feeding ecology of ichthyofauna of a Ria Formosa (South Portugal) water reservoir

The feeding habits of several fish species in a water reservoir of the Ria Formosa, Portugal, that has similar ecological characteristics to the outside tidal channels, were studied and compared with food availability. The gilthead seabream (Sparus aurata), the most abundant fish species, mainly selected gastropods and bivalves, although occasionally fish and small crustaceans such as tanaids, ostracods, and cumaceans were also selected. Polychaetes, although abundant in the environment, were not particularly selected by any of the fish species studied. The diets of all the species studied were characterized by a large variety of prey, allowing them to survive in environments of low diversity and poor stability, such as coastal lagoons. These fish are largely benthic feeders, essentially eating the epimacroinvertebrates and endomacroinvertebrates and, occasionally, fish.Diplodus vulgaris andDiplodus annularis preferentially selected gastropods and small crustaceans.Spondyliosoma cantharus generally preyed on crustaceans, including the highly mobile epifauma, the mysids, and decapods.Halobatrachus didactylus andAnguilla anguilla, had very diversified diets that included fish.Mullus barbatus were found to have selected all groups of crustaceans and also bivalves. Wrasses, gobies, andDiplodus sargus, all small-sized fish, singled out small crustaceans, gastropods, and bivalves. The Sparids were the least specialized predators, with broader niches than the other species. They preferentially selected molluscs, which were abundant in the environment. A large overlap of diets was observed and competition may be important when fish biomass is high.     

Ozone Weekend Effect Analysis in Three European Urban Areas

This paper aims to apply statistical procedures to analyse the ozone weekend effect (OWE) in three European urban areas: Lisbon, Oporto and London. Seasonal variations of surface ozone (O₃) and total oxidant species (O_x) concentrations are presented. The studied period was from January 2007 to December 2009. The O₃ annual average profile in London was significantly different from the ones achieved for Lisbon and Oporto, due to the high emissions of nitrogen oxides and low temperatures (associated with low solar radiations). The influence of nitrogen oxides in atmospheric chemistry of London was analysed by linear correlations between O₃ concentrations and NO₂/NO ratio. High values during almost all period showed that O₃ concentrations are mainly influenced by NO? NO₂? O₃ chemical reaction. On the other hand, the linear correlations between O₃ and NO₂ concentrations only presented positive values in Lisbon and Oporto. This behaviour is associated with photo‐dissociation of NO₂, producing O₃ during the spring and summer periods. Additionally, cluster analysis was applied to group the days of week according the correspondent O₃ behaviour. The weekend and some weekdays (immediately after or before) were grouped in the same cluster, showing that OWE occurs in all urban areas selected in this study. These findings suggest that the applied statistical procedures should be used to analyse the OWE and that the causes for the different O₃ behaviours during the week may be influenced by meteorological variables.     

In situ experimental study of reed leaf decomposition along a full salinity gradient

An experimental study on Phragmites australis leaf litter decomposition was conducted in the estuarine environment, Ria de Aveiro, Western Portugal, using the leaf-bag technique, with fine- (1 mm) and coarse-mesh (5 mm) bags. The leaf bags were placed in the field sites at day 0, covering a complete salinity gradient, and replicates were collected over time, at days 3 (leaching), 7, 15, 30 and 60. The biomass loss through the leaching phase, about 20% of the initial leaf mass, was independent of both the salinity and the bag mesh size. The biomass decay pattern along the salinity gradient varied through time and presented strong similarities between the two mesh sizes, with the remaining biomass always lower in the 5 mm mesh-size bags. At days 7 and 15, the lowest remaining biomass was observed at the head of the estuary, the preferential distribution area of P. australis. At day 30, the remaining biomass was higher in the marine area and diminished under a direct relationship with salinity, reaching the lowest value in the freshwater environment, with values ranging from 66% to 44% of the initial weight in 5 mm bags, and from 79% to 51% in 1 mm bags. The largest heterogeneity in the remaining biomass among the study areas positioned along the salinity gradient was found close to days 30 (5 mm) and 40 (1 mm). The overall results indicate that the relationship between leaf decay rate and salinity depends on the decay time considered (k₁₅, k₃₀ or k₆₀) and, for the later stages (k₆₀), also on the leaf-bag mesh size. This implies that the use of leaf litter decay rates as a functional indicator in transitional waters will need to take into consideration the factor location in the salinity gradient and leaf litter stage at which the decay rate is determined. The differences between the decay rates with the mesh size acted mainly at the level of the absolute k value and not at the level of the pattern along the salinity gradient. Even so, the data obtained at the mouth of the estuary, in the area closest to a fully marine environment, indicated that after the initial biomass loss through leaching, P. australis decayed either very slowly, in the 5 mm, or not at all, in the 1 mm mesh bags.     

Measuring proper motions of isolated neutron stars with Chandra

The excellent spatial resolution of the Chandra observatory offers the unprecedented possibility to measure proper motions at X-ray wavelength with relatively high accuracy using as reference the background of extragalactic or remote galactic X-ray sources. We took advantage of this capability to constrain the proper motion of RX J0806.4-4123 and RX J0420.0-5022, two X-ray bright and radio quiet isolated neutron stars (INSs) discovered by ROSAT and lacking an optical counterpart. In this paper, we present results from a preliminary analysis from which we derive 2σ upper limits of 76 mas/yr and 138 mas/yr on the proper motions of RX J0806.4-4123 and RX J0420.0-5022 respectively. We use these values together with those of other ROSAT discovered INSs to constrain the origin, distance and evolutionary status of this particular group of objects. We find that the tangential velocities of radio quiet ROSAT neutron stars are probably consistent with those of ‘normal’ pulsars. Their distribution on the sky and, for those having accurate proper motion vectors, their possible birth places, all point to a local population, probably created in the part of the Gould Belt nearest to the earth.      

The heterogeneous formation of N2O over bulk condensed phases in the presence of SO2 at high humidities

In view of the uncertainty of the origin of the secular increase of N₂O, we studied heterogeneous processes that contribute to formation of N₂O in an environment that comes as close as possible to exhaust conditions containing NO and SO₂, among other constituents. The N₂O formation was followed using electron capture gas chromatography (ECD-GC). The other reactants and intermediates (SO₂, NO, NO₂ and HONO) were monitored using gas phase UV-VIS absorption spectroscopy. Experiments were conducted at 298 and 368 K as well as at dry and high humidity (approaching 100% rh) conditions. There is a significant heterogeneous rate of N ₂ O formation at conditions that mimic an exhaust plume from combustion processes.The simultaneous presence of NO, SO₂, O₂ in the gas phase and condensed phase water, either in the bulk liquid or adsorbed state has been confirmed to be necessary for the production of significant levels of N₂O. The stoichiometry of the overall reaction is: 2 NO+SO₂+H₂O N₂O+H₂SO₄. The maximum rate of N₂O formation occurred at the beginning of the reaction and scales with the surface area of the condensed phase and is independent of its volume. A significant rate of N₂O formation at 368 K at 100% rh was also observed in the absence of a bulk substrate. The diffusion of both gas and liquid phase reactants is not rate limiting as the reaction kenetics is dominated by the rate ofN₂O formation under the experimental conditions used in this work. The simultaneous presence of high humidity (90–100% rh at 368 K) and bulk condensed phase results in the maximum rate and final yield of N₂O approaching 60% and 100% conversion after one hour in the presence of amorphous carbon and fly-ash, respectively.Work performed in partial fulfillment of the requirements of Dr ès Sciences at EPFL.