Geochemistry and petrogenesis of lamproites,late cretaceous age,Woodson County,Kansas, U.S.A.

Lamproite sills and their associated sedimentary and contact metamorphic rocks from Woodson County, Kansas have been analyzed for major elements, selected trace elements, and strontium isotopic composition. These lamproites, like lamproites elsewhere, are alkalic (molecular $\text{K}{}_2\text{O + Na}{}_2\text{O}\text{Al}{}_2\text{O}{}_3\text{= 1.6–2.6}$), are ultrapotassic $\text{(}\text{K}{}_2\text{O}\text{Na}{}_2\text{O}\text{= 9.6–150)}$, are enriched in incompatible elements (LREE or light rare-earth elements, Ba, Th, Hf, Ta, Sr, Rb), and have moderate to high initial strontium isotopic compositions (0.7042 and 0.7102). The silica-saturated magma (olivine-hypersthene normative) of the Silver City lamproite could have formed by about 2 percent melting of a phlogopite-garnet lherzolite under high $\text{H}{}_2\text{O}\text{CO}{}_2$ ratios in which the Iherzolite was enriched before melting in the incompatible elements by metasomatism. The Rose Dome lamproite probably formed in a similar fashion although the extreme alteration due to addition of carbonate presumably from the underlying limestone makes its origin less certain. Significant fractional crystallization of phases that occur as phenocrysts (diopside, olivine, K-richterite, and phlogopite) in the Silver City magma and that concentrate Co, Cr, and Sc are precluded as the magma moved from the source toward the surface due to the high abundances of Co, Cr, and Sc in the magma similar to that predicted by direct melting of the metasomatized Iherzolite.Ba and, to a lesser extent, K and Rb and have been transported from the intrusions at shallow depth into the surrounding contact metamorphic zone. The Silver City lamproite has vertical fractionation of some elements due either to volatile transport or to variations in the abundance of phenocrysts relative to groundmass most probably due to flow differentiation although multiple injection or fractional crystallization cannot be conclusively rejected.     

The role of economic sectoral structure as a policy mechanism towards more resilient peripheral regions: the case of South Africa

The role of economic sectoral structure in regional growth and development is widely acknowledged. However, there has been scarce reflection on its role as a policy instrument, particularly for peripheral regions. In reaction, this paper investigates the role of economic sectoral structure as a policy instrument towards more resilient peripheral regions. Through a multiple country policy analysis, the paper determines to what degree economic sectoral structure is reflected in regional development policies of 18 countries with predominantly rural characteristics and lagging regions. Moreover, the role of economic sectoral structure towards more resilient regions is quantified and measured for a specific peripheral region case in South Africa as developing country exhibiting poor economic resilience. The paper highlights related variety as a key ingredient for a region to reach a state of dynamic stability between adaptation and adaptability towards enhanced long-term resilience capacity of the peripheral region. The research concludes that policy focus should support the maintenance of the sectors and industries of comparative advantage on the regional scale, but strongly focus on sectoral comparative advantage within the national scale (if present) to establish a more robust region. This will establish and strengthen the identified peripheral growth centres as centres of national competitiveness and specialisation. Primary policy actions as emanated from the literature and the multiple country policy analysis will promote more efficient sectoral composition as key towards more resilient peripheral regions. It is acknowledged that these policy actions must be informed by a detailed regional economic analysis for different peripheral regions to determine inherent and latent economic potential and link with interdependent industries. This paper will highlight that regional policy should become more explicit by exploiting the role of economic and natural resources as growth engines for the peripheral regional economy in a more effective way through a multi-centred territorial structure.

     

Diagnosing drought using the downstreamness concept: the effect of reservoir networks on drought evolution

To effectively manage hydrological drought, there is an urgent need to better understand and evaluate its human drivers. Using the “downstreamness” concept, we assess the role of a reservoir network in the emergence and evolution of droughts in a river basin in Brazil. In our case study, the downstreamness concept shows the effect of a network of reservoirs on the spatial distribution of stored surface water volumes over time. We demonstrate that, as a consequence of meteorological drought and recovery, the distribution of stored volumes became spatially skewed towards upstream locations, which affected the duration and magnitude of hydrological drought both upstream (where drought was alleviated) and downstream (where drought was aggravated). The downstreamness concept thus appears to be a useful entry point for spatiotemporally explicit assessments of hydrological drought and for determining the likelihood of progression from meteorological drought to a human-modified hydrological drought in a basin.     

Optimization of water allocation in the Shatt al-Arab River under different salinity regimes and tide impact

Wastewater effluents from irrigation and the domestic and industrial sectors have serious impacts in deteriorating water quality in many rivers, particularly in areas under tidal influence. There is a need to develop an approach that considers the impact of human and natural causes of salinization. This study uses a multi-objective optimization–simulation model to investigate and describe the interactions of such impacts in the Shatt al-Arab River, Iraq. The developed model is able to reproduce the salinity distribution in the river given varying conditions. The salinity regime in the river varies according to different hydrological conditions and anthropogenic activities. Due to tidal effects, salinity caused by drainage water is seen to intrude further upstream into the river. The applied approach provides a way to obtain optimal solutions where both river salinity and deficit in water supply can be minimized. The approach is used for exploring the trade-off between these two objectives.     

Late Triassic tectonic inversion in the upper Yangtze Block: Insights from detrital zircon U–Pb geochronology from south‐western Sichuan Basin

The Sichuan Basin and the Songpan‐Ganze terrane, separated by the Longmen Shan fold‐and‐thrust belt (the eastern margin of the Tibetan Plateau), are two main Triassic depositional centres, south of the Qinling‐Dabie orogen. During the Middle–Late Triassic closure of the Paleo‐Tethys Ocean, the Sichuan Basin region, located at the western margin of the Yangtze Block, transitioned from a passive continental margin into a foreland basin. In the meantime, the Songpan‐Granze terrane evolved from a marine turbidite basin into a fold‐and‐thrust belt. To understand if and how the regional sediment routing system adjusted to these tectonic changes, we monitored sediment provenance primarily by using detrital zircon U‐Pb analyses of representative stratigraphic samples from the south‐western edge of the Sichuan Basin. Integration of the results with paleocurrent, sandstone petrology and published detrital zircon data from other parts of the basin identified a marked change in provenance. Early–Middle Triassic samples were dominated by Neoproterozoic (~700–900 Ma) zircons sourced mainly from the northern Kangdian basement, whereas Late Triassic sandstones that contain a more diverse range of zircon ages sourced from the Qinling, Longmen Shan and Songpan‐Ganze terrane. This change reflects a major drainage adjustment in response to the Late Triassic closure of the Paleo‐Tethys Ocean and significant shortening in the Longmen Shan thrust belt and the eastern Songpan‐Ganze terrane. Furthermore, by Late Triassic time, the uplifted northern Kangdian basement had subsided. Considering the eastward paleocurrent and depocenter geometry of the Upper Triassic deposits, subsidence of the northern Kangdian basement probably resulted from eastward shortening and loading of the Songpan‐Ganze terrane over the western margin of the Yangtze Block in response to the Late Triassic collision among Yangtze Block, Yidun arc and Qiangtang terrane along the Ganze‐Litang and Jinshajiang sutures.     

Processes of carbonate precipitation in modern microbial mats

Microbial mats are ecosystems that arguably greatly affected the conditions of the biosphere on Earth through geological time. These laminated organosedimentary systems, which date back to > 3.4 Ga bp, are characterized by high metabolic rates, and coupled to this, rapid cycling of major elements on very small (mm-µm) scales. The activity of the mat communities has changed Earth's redox conditions (i.e. oxidation state) through oxygen and hydrogen production. Interpretation of fossil microbial mats and their potential role in alteration of the Earth's geochemical environment is challenging because these mats are generally not well preserved.Preservation of microbial mats in the fossil record can be enhanced through carbonate precipitation, resulting in the formation of lithified mats, or microbialites. Several types of microbially-mediated mineralization can be distinguished, including biologically-induced and biologically influenced mineralization. Biologically-induced mineralization results from the interaction between biological activity and the environment. Biologically-influenced mineralization is defined as passive mineralization of organic matter (biogenic or abiogenic in origin), whose properties influence crystal morphology and composition. We propose to use the term organomineralization sensu lato as an umbrella term encompassing biologically influenced and biologically induced mineralization. Key components of organomineralization sensu lato are the “alkalinity” engine (microbial metabolism and environmental conditions impacting the calcium carbonate saturation index) and an organic matrix comprised of extracellular polymeric substances (EPS), which may provide a template for carbonate nucleation. Here we review the specific role of microbes and the EPS matrix in various mineralization processes and discuss examples of modern aquatic (freshwater, marine and hypersaline) and terrestrial microbialites.     

Benefits and hurdles of using brackish groundwater as a drinking water source in the Netherlands

The production of fresh drinking water from brackish groundwater by reverse osmosis (BWRO) is becoming more attractive, even in temperate climates. For successful application of BWRO, the following approach is advocated: (1) select brackish source groundwater with a large volume and a composition that will yield a concentrate (waste water) with low mineral saturation; (2) maintain the feed water salinity at a constant level by pumping several wells with different salinities; (3) keep the permeate-to-concentrate ratio low, to avoid supersaturation in the concentrate; (4) keep the system anoxic (to avoid oxidation reactions) and pressurized (to prevent formation of gas bubbles); and (5) select a confined aquifer for deep well injection where groundwater quality is inferior to the membrane concentrate. This approach is being tested at two BWRO pilot plants in the Netherlands. Research issues are the pumping of a stable brackish source water, the reverse osmosis system performance, membrane fouling, quality changes in the target aquifer as a result of concentrate disposal, and clogging of the injection well. First evaluations of the membrane concentrate indicate that it is crucial to understand the kinetics of mineral precipitation on the membranes, in the injection wells, and in the target aquifer.     

Isotope Dilution Determinations of Lu,Hf, Zr,Ta and W,and Hf Isotope Compositions of NIST SRM 610 and 612 Glass Wafers

Isotope dilution determinations of Lu, Hf, Zr, Ta and W are reported for nine test portions (five for W) of NIST SRM 610 and 612 glass wafers. Additionally, all test portions were analysed for their Hf isotope compositions. In general, high field strength elemental (HFSE) distributions in NIST SRM 610 and 612 were reproducible to ～± 1%, except for Zr (± 5%) in NIST SRM 612, and absolute reported concentrations agreed with previously published values, but with higher precision. The slightly worse reproducibility of Zr in NIST SRM 612 compared to other HFSE is interpreted to result from analytical scatter, rather than sample inhomogeneity. The analyses demonstrated elemental homogeneity for both glass wafers for samples of 1–2 mg with respect to the precision of the method, i.e., ± 1% or better. Average Hf isotope compositions for both glass wafers agreed within uncertainty and the weighted average of all determinations yielded a mean ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282111 ± 0.000009 (95% confidence level). However, although mean values for NIST SRM 610 and 612 agreed within analytical limits, NIST SRM 610 test portions showed a tendency of systematically elevated isotope composition of ～ 0.5 _?Hf units when compared to NIST SRM 612, which may indicate a slightly more radiogenic Hf isotope composition of NIST SRM 610. The results of this study suggest that NIST SRM 610 and 612 are valuable calibrators for HFSE in situ analyses within the given uncertainties.