Isotope Dilution Determinations of Lu,Hf, Zr,Ta and W,and Hf Isotope Compositions of NIST SRM 610 and 612 Glass Wafers

Isotope dilution determinations of Lu, Hf, Zr, Ta and W are reported for nine test portions (five for W) of NIST SRM 610 and 612 glass wafers. Additionally, all test portions were analysed for their Hf isotope compositions. In general, high field strength elemental (HFSE) distributions in NIST SRM 610 and 612 were reproducible to ～± 1%, except for Zr (± 5%) in NIST SRM 612, and absolute reported concentrations agreed with previously published values, but with higher precision. The slightly worse reproducibility of Zr in NIST SRM 612 compared to other HFSE is interpreted to result from analytical scatter, rather than sample inhomogeneity. The analyses demonstrated elemental homogeneity for both glass wafers for samples of 1–2 mg with respect to the precision of the method, i.e., ± 1% or better. Average Hf isotope compositions for both glass wafers agreed within uncertainty and the weighted average of all determinations yielded a mean ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282111 ± 0.000009 (95% confidence level). However, although mean values for NIST SRM 610 and 612 agreed within analytical limits, NIST SRM 610 test portions showed a tendency of systematically elevated isotope composition of ～ 0.5 _?Hf units when compared to NIST SRM 612, which may indicate a slightly more radiogenic Hf isotope composition of NIST SRM 610. The results of this study suggest that NIST SRM 610 and 612 are valuable calibrators for HFSE in situ analyses within the given uncertainties.     

草地退化杂类草入侵遥感监测方法研究进展

近年来,受全球气候变暖及日趋频繁的人类活动的共同影响,我国草地生态系统出现了不同程度的退化,成为草地生态学界的研究热点。本文较系统总结了草地退化、杂类草入侵遥感监测方法的应用进展,指出了常规草地退化遥感监测方法的不足,并展望了今后的发展方向。研究发现草地退化在群落尺度上往往表现为优质牧草种类减少,杂类草种类增加。在草地退化过程中,杂类草侵入,往往导致植被覆盖度增加,因而传统的基于植被覆盖度、生产力和产草量下降的草地退化遥感监测方法,无法反映草地退化在植被种群方面的变化特征,尤其是杂类草入侵的草地退化过程。而目前基于高光谱数据的草地退化杂类草入侵监测方法,结合地面光谱测定和对退化草地物种特征微弱光谱差异的定量分析,能有效识别群落中杂类草种类,并反演出占群落的面积比例、高度和盖度等,可为草地退化监测及其治理提供群落演替过程及其态势的重要指标,为草地退化监测提供新的遥感技术方法。     

Artificial recharge with surface water; a pilot project in Wadi Madoneh, Jordan

Artificial recharge with surface water in Jordan has been discussed at length in several reports and papers, but so far this technique has hardly been applied in the country. This article describes the site selection, design, construction and operation of four small retention structures in Wadi Madoneh during the period 2003–2009. The catchment (37 km²) is located some 20 km east of Amman in a desert region (average annual precipitation is 160 mm). The project is based on a feasibility study conducted in the 1990s. It is shown that in the previous study the retention structures have been largely overdesigned, because of absence of discharge measurements and the negligence of climate change. For this pilot an extensive hydrological study was carried out, based on historical data and contemporary measurements, to derive design parameters for small in-channel dams with a height of 3–6 m. The retention structures are designed to retain the floods in order to slowly release this water for infiltration in the Wadi bed downstream. Four retention structures were installed by a local contractor in 2007. This study shows that virtually all surface runoff from the catchment has ceased which makes the method very effective while the costs are low. Artificial recharge with small retention structures is recommended for application on a larger scale and considered a cheap alternative for other non-conventional water resources supply methods. From experience with vandalism and interaction with the local community, improvements to the design of the dams are recommended.     

Modelling the Effect of Tree Foliage on Sprayer Airflow in Orchards

The effect of tree foliage on sprayer airflow through pear trees in a fruit orchard was studied and modelled in detail. A new three-dimensional (3-D) computational fluid dynamics model that integrates the 3-D canopy architecture with a local closure model to simulate the effect of the stem and branches and leaves of trees separately on airflow was developed. The model was validated with field observations made in an experimental orchard (pcfruit, Sint-Truiden, Belgium) in spring and summer 2008 and was used to investigate the airflow from three air-assisted orchard sprayers (Condor V, Duoprop and AirJet quatt). Velocity magnitudes were measured before and behind leafless and fully-leafed pear canopies across the row while the operating sprayers are passing along the row, and were compared with the simulations. The simulation results predicted the measured values well with all the local relative errors within 20%. The effect of foliar density on airflow from the three air assisted sprayers was manifested by changing the magnitude and direction of the sprayers’ air velocity behind the canopy, especially at the denser regions of the canopy and by changing the pattern of velocity decay horizontally along the jet. The developed methodology will also allow a thorough investigation of atmospheric airflow in canopy structures.     

Modelling the morphodynamic impact of offshore sandpit geometries

We investigate the hydrodynamic effects and morphodynamic impact of large-scale offshore sand extraction, for a variety of pit designs. We use a process-based idealized model for flow, sediment transport and bed evolution in a tide-dominated environment. Legislation and other practical considerations motivate our assumption that sandpits are both wide (horizontal dimensions of the order of kilometres) and shallow (the ratio of pit depth to water depth being small). This results in a semi-analytical tool that, unlike previous studies, enables a quick and extensive study into the effects of varying the physical characteristics as well as the pit design parameters. These parameters include pit length, width, and orientation with respect to the tide.     

Quantifying successional land cover after clearing of tropical rainforest along forest frontiers in the Congo Basin

State-of-the-art impact-modeling studies in environmental and climatological sciences require detailed future deforestation scenarios that allow forest to be replaced by a mosaic of multiple successional land-cover types, rather than the simple conversion of forest to a single land-cover type, such as bare soil or cropland. Therefore, not only the amount and location of forest removal has to be known (as is typically provided by scenarios), but also knowledge about the successional land-cover types and their relative areal proportions is needed. The main objective of this study was to identify these successional land-cover types and quantify their areal proportions in regions deforested during the past 37 years around the city of Kisangani, D.R. Congo. The fallow vegetation continuum was categorized in different stages, adapted from existing classifications. Ground-truth points describing the present-day vegetation were obtained during a field campaign and used for supervised and validated land-cover classification of these categories, using the Landsat image of 2012. Areal proportions of successional land-cover types were then derived from the resulting land-cover map. The second objective of this study was to relate these areal proportions to time since deforestation, which is expected to influence fallow landscapes. Landsat images of 1975, 1990, and 2001 were analyzed. Present-day mature tree fallow is less abundant on areas deforested during 1975–1990. The relative areal proportions were used to refine a deforestation scenario and apply it to existing data-sets of LAI and canopy height (CH). Assuming a simple conversion of forest to cropland, the deforestation scenario projected a reduction of grid-cell-averaged CH from 25.5 to 7.5 m (within deforested cells), whereas the refined scenarios that we propose show more subtle changes, with a reduced CH of 13 m. This illustrates the importance of taking successional land cover correctly into account in environmental and climatological modeling studies.     

Systematic study of effects of pH and ionic strength on attachment of phage PRD1

Objectives of this work are to investigate effects of pH and ionic strength (IS) on virus transport in saturated soil and to develop a quantitative relationship for these effects. A series of 50-cm column experiments with clean quartz sand under saturated conditions and with pH values of 5, 6, 7, 8, and IS values of 1, 10, and 20 mM were conducted. Bacteriophage PRD1 was used as a model virus. Applying a one-site kinetic model, attachment, detachment, and inactivation rate coefficients were determined from fitting breakthrough curves using the software package Hydrus-1D. Attachment rate coefficients increased with decreasing pH and increasing IS, in agreement with DLVO theory. Sticking efficiencies were calculated from the attachment rate coefficients and used to develop an empirical formula for sticking efficiency as a function of pH and IS. This relationship is applicable under unfavorable conditions for virus attachment. We compared sticking efficiencies predicted by the empirical formula with those from field and column experiments. Within the calibrated range of pH and IS, the predicted and observed sticking efficiencies are in reasonable agreement for bacteriophages PRD1 and MS2. However, the formula significantly overestimates sticking efficiencies for IS higher than 100 mM. In addition, it performs less well for viruses with different surface reactivity than PRD1 and MS2. Effects of pH and IS on detachment and inactivation rate coefficients were also investigated but the experimental results do not allow constraining these parameters with sufficient certainty.     

Diagnosing drought using the downstreamness concept: the effect of reservoir networks on drought evolution

ABSTRACT

To effectively manage hydrological drought, there is an urgent need to better understand and evaluate its human drivers. Using the “downstreamness” concept, we assess the role of a reservoir network in the emergence and evolution of droughts in a river basin in Brazil. In our case study, the downstreamness concept shows the effect of a network of reservoirs on the spatial distribution of stored surface water volumes over time. We demonstrate that, as a consequence of meteorological drought and recovery, the distribution of stored volumes became spatially skewed towards upstream locations, which affected the duration and magnitude of hydrological drought both upstream (where drought was alleviated) and downstream (where drought was aggravated). The downstreamness concept thus appears to be a useful entry point for spatiotemporally explicit assessments of hydrological drought and for determining the likelihood of progression from meteorological drought to a human-modified hydrological drought in a basin.