Membrane Interface Probe Protocol for Contaminants in Low‐Permeability Zones

Accurate characterization of contaminant mass in zones of low hydraulic conductivity (low k) is essential for site management because this difficult‐to‐treat mass can be a long‐term secondary source. This study developed a protocol for the membrane interface probe (MIP) as a low‐cost, rapid data‐acquisition tool for qualitatively evaluating the location and relative distribution of mass in low‐k zones. MIP operating parameters were varied systematically at high and low concentration locations at a contaminated site to evaluate the impact of the parameters on data quality relative to a detailed adjacent profile of soil concentrations. Evaluation of the relative location of maximum concentrations and the shape of the MIP vs. soil profiles led to a standard operating procedure (SOP) for the MIP to delineate contamination in low‐k zones. This includes recommendations for: (1) preferred detector (ECD for low concentration zones, PID or ECD for higher concentration zones); (2) combining downlogged and uplogged data to reduce carryover; and (3) higher carrier gas flow rate in high concentration zones. Linear regression indicated scatter in all MIP‐to‐soil comparisons, including R² values using the SOP of 0.32 in the low concentration boring and 0.49 in the high concentration boring. In contrast, a control dataset with soil‐to‐soil correlations from borings 1‐m apart exhibited an R² of ≥0.88, highlighting the uncertainty in predicting soil concentrations using MIP data. This study demonstrates that the MIP provides lower‐precision contaminant distribution and heterogeneity data compared to more intensive high‐resolution characterization methods. This is consistent with its use as a complementary screening tool.     

Provenance,tectonic setting and source of Archean metasedimentary rocks of the Browns Range Metamorphics,Tanami Region,Western Australia

This study combines U–Pb age and Lu–Hf isotope data for magmatic and detrital zircons, with whole-rock geochemistry of the Browns Range Metamorphics (BRM), Western Australia. The BRM are medium- to coarse-grained metasandstones that consist of angular to sub-rounded detrital quartz and feldspars with minor granitic lithic fragments. The sequence has undergone partial to extensive quartz–muscovite alteration and rare-earth-element mineralisation and has been intruded by mafic/ultramafic, syenitic and pegmatitic intrusive rock units. Uranium–Pb and Lu–Hf isotopic data on detrital zircons from the metasandstones and intruding granitic rocks yield a well-defined age of ca 3.2 to ca 3.0 Ga for all samples, with relatively radiogenic ?_Hf values (?_Hf = –1.7 to 5.1) indicating derivation from Mesoarchean granite basement of juvenile origin. This is consistent with geochemical and petrological data that support deposition from a granitic source in a continental rift basin setting. The timing of sediment deposition is constrained between the ca 3.0 Ga age of the source rocks and ca 2.5 Ga age of the granitic intrusive bodies that cross-cut the metasedimentary rocks. The ca 2.5 Ga zircons from the intrusive rocks have ?_Hf model ages of ca 3.4 to ca 3.1 Ga, which is consistent with formation via partial melting of the BRM, or the Mesoarchean granite basement. Zircons of the Gardiner Sandstone that unconformably overlies the BRM return detrital ages of ca 2.6 to ca 1.8 Ga with no trace of ca 3.1 Ga zircons, which discounts a significant contribution from the underlying BRM. The Mesoarchean age and isotopic signatures of the BRM zircons are shared by some zircon records from the Pine Creek Orogen, and the Pilbara, Yilgarn and Gawler cratons. Collectively, these records indicate that juvenile Mesoarchean crust is a more significant component of Australian cratons than is currently recognised. This work also further demonstrates that detrital minerals in Paleoproterozoic/Archean sedimentary rocks are archives to study the early crustal record of Earth.     

The effect of human activity on radiative forcing of climate change: a review of recent developments

Human activity has perturbed the Earth's energy balance by altering the properties of the atmosphere and the surface. This perturbation is of a size that would be expected to lead to significant changes in climate. In recent years, an increasing number of possible human-related climate change mechanisms have begun to be quantified. This paper reviews developments in radiative forcing that have occurred since the second assessment report of the Intergovernmental Panel on Climate Change (IPCC), and proposes modifications to the values of global-mean radiative forcings since pre-industrial times given by IPCC. The forcing mechanisms which are considered here include those due to changes in concentrations of well-mixed greenhouse gases, tropospheric and stratospheric ozone, aerosols composed of sulphate, soot, organics and mineral dust (including their direct and indirect effects), and surface albedo. For many of these mechanisms, the size, spatial pattern and, for some, even the sign of their effect remain uncertain. Studies which have attributed observed climate change to human activity have considered only a subset of these mechanisms; their conclusions may not prove to be robust when a broader set is included.     

Climate change, powerlessness and the commons dilemma: Assessing New Zealanders’ preparedness to act

Mitigating climate change is recognized as an increasingly urgent task that requires understanding a range of different strategies, including voluntary behavior change. Among the psychological barriers to behavior change are perceptions of powerlessness and the commons dilemma. This paper examines the association between these factors in a sample of New Zealand citizens and clarifies their importance in relation to other barriers to action to mitigate climate change, including uncertainty and perceived risk. Stronger perceptions of powerlessness and the commons dilemma were related to lower levels of action to mitigate climate change and lesser importance being placed upon climate change as an influence on individual actions. The perceived risk of climate change and the perception that humans influence climate change were the strongest predictors of mitigation action.     

The utilization of North sea hydrocarbons as raw materials for petro-chemical manufacture

The oil and gas reserves of the North Sea have principally been regarded as sources of energy and little attention has been paid to their potential as raw materials for chemical manufacture. This paper reviews the technical and economic possibilities presented by the North Sea hydrocarbons as petro-chemical feedstocks. In particular, an attempt is made to predict changes which may occur in the geography of petro-chemical production in North West Europe if full advantage is taken of these possibilities.     

A Study of AR 9144; A Fast-Growing EFR

This paper is a study of NOAA region 9144, an emerging flux region (EFR) which grew rapidly beginning 25 August 2000. This region was visible in SOHO data at 0 UT on 25 August 2000 as a small, isolated spot. It was recognizable as an active region with multiple spots by 06:00 UT on the 25th and was a fully developed AR by 24^h UT on the 26th of August. Data are presented from the Michelson Doppler Imager (MDI) experiment on the Solar and Heliospheric Observatory satellite (SOHO), from Big Bear Solar Observatory (BBSO) and from the San Fernando Observatory (SFO). The MDI data are Dopplergrams, magnetograms, and continuum images. The BBSO data are high-resolution Hα filtergrams. The SFO data are Dopplergrams, magnetograms and continuum images from the Video SpectraSpectroHeliograph (VSSHG). MDI Doppler images show that during the rapid growth of this EFR during the day of 26 August, the most obvious feature in area and lifetime is a red-shifted area in the trailing part of the region. SFO Doppler images show a more complex pattern, but still dominated by red shifts in the trailing part of the region near the end of the day of 26 August.     

Ponded deposits on asteroid 433 Eros

Abstract— In late January 2001 the NEAR—Shoemaker spacecraft performed low‐altitude passes over the surface of 433 Eros. Coordinated observations of the asteroid surface were obtained at submeter resolution by the NEAR laser rangefinder and the multispectral imager. This paper presents three independent, coordinated observations of a 90 m pond adjacent to a granular debris flow, including the highest resolution altimetric measurements of ponded deposits on Eros. The ponded deposits appear to have been emplaced by fluid‐like motion of dry asteroidal regolith. A simple model of seismic agitation from impacts is developed to account for pond formation on Eros. The model predicts that ponds should form readily on Eros but not on the Moon, where ponds are not observed. The model also suggests that the absence of observable ponds in the largest craters of Eros, as well as on Phobos and Deimos, may be related to regolith depth.     

Generalized Radon transforms and slant stacks

Summary. The Radon transform or slant stack is becoming a widely used technique for analysing high-quality reflection and refraction data. The transform normally used is applicable to data from a line source in a plane model, that is, one Cartesian coordinate. The theoretical basis for the Radon transform pair for one Cartesian coordinate has appeared in the seismological literature. For a point source in plane or spherical geometry, or a line source in cylindrical geometry only the Radon transform for the direct problem (computation of synthetic seismograms) has been published. To analyse data an approximate inverse transform has been used. In this research note, the exact forms of the generalized Radon transform pairs are completed for a point source in plane or spherical geometry, and for a line source in cylindrical geometry. The differences will be important if the waveforms are being interpreted, and are most significant for near-vertical reflections—the type of data most commonly slant stacked.