An integrated sulfur isotope model for Namibian shelf sediments

In this study the sulfur cycle in the organic-rich mud belt underlying the highly productive upwelling waters of the Namibian shelf is quantified using a 1D reaction-transport model. The model calculates vertical concentration and reaction rate profiles in the top 500 cm of sediment which are compared to a comprehensive dataset which includes carbon, sulfur, nitrogen and iron compounds as well as sulfate reduction (SR) rates and stable sulfur isotopes (³²S, ³⁴S). The sulfur dynamics in the well-mixed surface sediments are strongly influenced by the activity of the large sulfur bacteria Thiomargaritanamibiensis which oxidize sulfide (H₂S) to sulfate () using sea water nitrate () as the terminal electron acceptor. Microbial sulfide oxidation (SOx) is highly efficient, and the model predicts intense cycling between and H₂S driven by coupled SR and SOx at rates exceeding 6.0 mol S m⁻² y⁻¹. More than 96% of the SR is supported by SOx, and only 2-3% of the pool diffuses directly into the sediment from the sea water. A fraction of the produced by Thiomargarita is drawn down deeper into the sediment where it is used to oxidize methane anaerobically, thus preventing high methane concentrations close to the sediment surface. Only a small fraction of total H₂S production is trapped as sedimentary sulfide, mainly pyrite (FeS₂) and organic sulfur (S_org) (∼0.3 wt.%), with a sulfur burial efficiency which is amongst the lowest values reported for marine sediments (<1%). Yet, despite intense SR, FeS₂ and S_org show an isotope composition of ∼5 ‰ at 500 cm depth. These heavy values were simulated by assuming that a fraction of the solid phase sulfur exchanges isotopes with the dissolved sulfide pool. An enrichment in H₂S of ³⁴S towards the sediment-water interface suggests that Thiomargarita preferentially remove H₂³²S from the pore water. A fractionation of 20-30‰ was estimated for SOx (ε_SOx) with the model, along with a maximum fractionation for SR (ε_SR-max) of 100‰. These values are far higher than previous laboratory-based estimates for these processes. Mass balance calculations indicate negligible disproportionation of autochthonous elemental sulfur; an explanation routinely cited in the literature to account for the large fractionations in SR. Instead, the model indicates that repeated multi-stepped sulfide oxidation and intracellular disproportionation by Thiomargarita could, in principle, allow the measured isotope data to be simulated using much lower fractionations for ε_SOx (5‰) and ε_SR (78‰).     

Origine et évolution du soufre au sein de l'aquifère des Sables infra-molassiques du Bassin aquitainOrigin and evolution of sulphur in the Infra-Molassic Sands Aquifer from the Aquitaine Basin

New data on isotopic composition of sulphur and oxygen in dissolved sulphates are used to determine the origin of sulphate ions (SO₄^2?) in the water of the Infra-Molassic Sands Eocene aquifer. Two very distinct origins appear: one is the gypsum dissolution, from the molasse, and the second is the pyrite oxidation, present at the bottom of and within the aquifer. These isotopic analyses helped, in agreement with hydrogeology, to identify geochemical basins whose properties modify the chemical water composition. They also highlight the existence of bioreduction areas. To cite this article: L. André et al., C. R. Geoscience 334 (2002) 749–756.     

The application of an innovative inverse model for understanding and predicting landslide movements (Salazie cirque landslides,Reunion Island)

The prediction of landslide movement acceleration is a complex problem, among others identified for deep-seated landslides, and represents a crucial step for risk assessment. Within the scope of this problem, the objective of this paper is to explore a modelling method that enables the study of landslide function and facilitates displacement predictions based on a limited data set. An inverse modelling approach is proposed for predicting the temporal evolution of landslide movement based on rainfall and displacement velocities. Initially, the hydrogeology of the studied landslides was conceptualised based on correlative analyses. Subsequently, we applied an inverse model with a Gaussian-exponential transfer function to reproduce the displacements. This method was tested on the Grand Ilet (GI) and Mare-à-Poule-d’Eau (HB) landslides on Reunion Island in the Indian Ocean. We show that the behaviour of landslides can be modelled by inverse models with a bimodal transfer function using a Gaussian-exponential impulse response. The cumulative displacements over 7 years of modelling (2 years of calibration period for GI, and 4 years for HB) were reproduced with an RMSE above 0.9. The characteristics of the bimodal transfer function are directly related to the hydrogeological functioning demonstrated by the correlative analyses: the rapid reaction of a landslide can be associated with the effect of a preferential flow path on groundwater level variations. Thus, this study shows that the inverse model using a Gaussian-exponential transfer function is a powerful tool for predicting deep-seated landslide movements and for studying how they function. Beyond modelling displacements, our approach effectively demonstrates its ability to contribute relevant data for conceptualising the sliding mechanisms and hydrogeology of landslides.     

Compartmentalisation of fluid migration pathways in the sub-Andean Zone, Bolivia

Numerous observations indicate that faults play a major role on the migration pathways of fluids in the Bolivian sub-Andean Zone. Most oil seeps in the foothills are located on faults, but oil fields in the foredeep are closed by faults. In the foothills, analysis of cements in fractures inside and around fault zones indicates that the faults act as barriers for transversal migration but can be preferential lateral migration pathways for both hydrocarbons and water. A detailed study of these apparent contradictions suggests that the hydraulic behaviour of faults changes with depth in relation with sandstone diagenesis, but it is strain-independent. From microstructural analyses of fault zones, we suggest that the main controlling factor is temperature, which facilitates or inhibits quartz precipitation. This result implies that the same fault is a barrier for lateral and transversal migration at depths >3 km, due to sealing of fractures by authigenic quartz at T>80 °C, and is a lateral drain in its shallower parts. As a result, the various thrust sheets are isolated from a hydraulic point of view, whereas migration in the foreland may take place over long distances (>100 km).     

Kriging and Semivariogram Deconvolution in the Presence of Irregular Geographical Units

This paper presents a methodology to conduct geostatistical variography and interpolation on areal data measured over geographical units (or blocks) with different sizes and shapes, while accounting for heterogeneous weight or kernel functions within those units. The deconvolution method is iterative and seeks the point-support model that minimizes the difference between the theoretically regularized semivariogram model and the model fitted to areal data. This model is then used in area-to-point (ATP) kriging to map the spatial distribution of the attribute of interest within each geographical unit. The coherence constraint ensures that the weighted average of kriged estimates equals the areal datum.This approach is illustrated using health data (cancer rates aggregated at the county level) and population density surface as a kernel function. Simulations are conducted over two regions with contrasting county geographies: the state of Indiana and four states in the Western United States. In both regions, the deconvolution approach yields a point support semivariogram model that is reasonably close to the semivariogram of simulated point values. The use of this model in ATP kriging yields a more accurate prediction than a naïve point kriging of areal data that simply collapses each county into its geographic centroid. ATP kriging reduces the smoothing effect and is robust with respect to small differences in the point support semivariogram model. Important features of the point-support semivariogram, such as the nugget effect, can never be fully validated from areal data. The user may want to narrow down the set of solutions based on his knowledge of the phenomenon (e.g., set the nugget effect to zero). The approach presented avoids the visual bias associated with the interpretation of choropleth maps and should facilitate the analysis of relationships between variables measured over different spatial supports.     

Crustal structure beneath the Mount Cameroon region derived from recent gravity measurements

In this study, the recent update of the gravity database with new measurements has raised the opportunity of improving the knowledge of the crustal structure beneath the large volcanic system called Mount Cameroon, and its implication in the regional tectonics. The multi-scale wavelet analysis method was applied to highlight the geologic features of the area, and their depths were estimated using the logarithmic power spectrum method. The results reveal a complex crustal structure beneath Mount Cameroon with high variation in the lateral distribution of crustal densities. The upper and lower crusts are intruded by dense materials originating from the mantle with less lateral extension. The trends of Tiko and Ekona faults along the intrusion suggest tectonic activities as deep as 25 km. The difference in mantle composition or temperature between the East and the West of the studied area is clearly seen in detailed wavelet images and agrees with a mantle origin for the Cameroon Volcanic Line.     

Short‐time (<10 ka) denudation rates as a marker of active folding in the Zagros Fold Belt (Iran)

Coupling between tectonics and surface processes is usually ill‐quantified as other factors such as climate and lithology affect the later. We provide catchment‐wide ¹⁰Be denudation rates of the Mand catchment in the Zagros Fold Belt (Iran) to infer correlations between these rates and ongoing tectonic shortening in the region. Denudation rates are generally low (~0.05–0.1 mm/a) but increase to ~1 mm/a near the Halikan anticline, where changes in precipitation, lithology or hillslope gradient are insignificant. The denudation rates upstream and downstream of the Halikan anticline are consistent with the GPS convergence rates in these areas. The sharp increase in denudation rates over the Halikan anticline denotes its growth as previously detected from terrace incision. It also reveals small wavelength coupling between crustal deformation and erosion. Denudation rates are therefore a useful and sensitive tool that helps constraining non‐brittle active tectonics such as folding of a sedimentary cover.     

Ultra‐high temperature metamorphism recorded in Fe‐rich olivine‐bearing migmatite from the Khondalite Belt,North China Craton

We document the first occurrence of Fe‐rich olivine‐bearing migmatitic metapelite in the Khondalite Belt, North China Craton. Petrological analyses revealed two exotic assemblages of orthopyroxene+spinel+olivine and orthopyroxene+spinel+cordierite. Phase relation modelling suggests that these assemblages are diagnostic of ultra‐high temperature (UHT) metamorphism in the Fe‐rich system, with temperatures from 1,000 to 1,050°C at 0.6 GPa. U–Th–Pb SIMS analyses on zircon reveal a similar age of c. 1.92 Ga for the olivine‐bearing migmatite and an adjacent gabbronoritic intrusion that is therefore identified as the heat source for the UHT metamorphism. These results, coupled with additional analysis of the famous Tuguiwula sapphirine‐bearing granulite, lead to a re‐appraisal of the P–T path shape and heat source for the UHT metamorphism. We suggest that UHT metamorphism, dated between 1.92 and 1.88 Ga, across the whole Khondalite belt, proceeded from a clockwise P–T evolution with an initial near‐isobaric heating path at ~0.6–0.8 GPa, and a maximum temperature of 1,050°C followed by a cooling path with minor decompression to ~0.5 GPa. Considering our results and previous works, we propose that the orogenic crust underwent partial melting at temperature reaching 850°C and depth of ~20 to ~30 km during a period of c. 30 Ma, between 1.93 and 1.90 Ga. During this time span, the partially molten crust was continuously intruded by mafic magma pulses responsible for local greater heat supply and UHT metamorphism above 1,000°C. We propose that the UHT metamorphism in the Khondalite belt is not related to an extensional post‐collisional event, but is rather syn‐orogenic and associated with mafic magma supplies.     

Determination of Mercury in One Hundred and Sixteen Geological and Environmental Reference Materials Using a Direct Mercury Analyser

The mercury content of 116 reference materials (RMs) from ten international organisations was determined in this study, which focused on variability within and between batches of RMs. Direct mercury analysis (DMA) was applied to RMs having Hg contents between 1 and 6300 ng g^?1 and provided good precision and accuracy. Accuracy was demonstrated by the agreement of our results with certified values, while replicates were made to establish the precision. Low within‐batch variability was noted, with precision from 0.1 to 23% (n = 3–5) apparently depending on Hg content and homogeneity, whereas systematic offsets were detected among several batches. Thanks to the analysis of different batches; the homogeneity or heterogeneity of several RMs was shown, and thus, suitable RMs for quality control for Hg determinations could be recommended.     

Sur trois principes généraux de la Métallogénie et de la recherche minérale

Des publications récentes conduisent à insister sur trois démarches, ou trois principes fondamentaux sans lesquels la Métallogénie (comme la Pétrologie) et la recherche minérale ne peuvent progresser. 1. Sortons des «types» connus et posons en principe que tout élément chimique peut se concentrer à diverses étapes du cycle géologique et géochimique; recherchons donc ces concentrations et traquons les par tous les moyens minéralogiques et géochimiques à notre disposition. 2. Récusons la confusion des concepts chronologiques et des concepts spatiaux, et en particulier la superposition totalement erronée d'«épigénétique» et d'«étranger». 3. Tout est hérité d'un passé plus ou moins lointain; principe qui rejoint le premier et nous conduira, dans certains cas favorables, vers des concentrations antérieures.

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Recent publications lead to three steps without which metallogenic and thus petrologic investigations are impossible: 1. We should depart from known types in ore genesis and assume that any element can be enriched during various stages of the geological and geochemical cicle. These enrichments should thus be investigated with all possible methods of mineralogy and geochemistry. 2. We should reject the confusion of terms referring to time and space of ore genesis, especially the completely confused superposition of the terms epigenetic and introduced from the outside. 3. All deposits show signs of inheritance; this leads us back to point one which involves economic accumulations under certain favorable conditions.

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Neuere Veröffentlichungen zeigen die Notwendigkeit, drei Umstände anzuerkennen, ohne die eine petrologische Forschung nicht mehr möglich ist: 1. Wir müssen davon Abstand nehmen, von den bekannten Lagerstätten-Typen zu reden. Richtig ist vielmehr, daß jedes chemische Element in den verschiedenen Etappen des geologischen und geochemischen Geschehens angereichert werden kann; forschen wir also nach diesen Anreicherungen und verfolgen wir sie mit allen mineralogischen und geochemischen Mitteln, die uns zur Verfügung stehen. 2. Wir müssen die Verwirrung der chronologischen und räumlichen Vorstellungen vermeiden, vor allem die vollkommen falsche Überlagerung von epigenetisch und fremd. 3. Alles was wir beobachten, ist das Erbe einer mehr oder weniger fernen Vergangenheit. Nur wenn wir uns ständig über dieses Faktum klar sind, dann können wir unter günstigen Umständen zu frühen Anreicherungen hingeführt werden.