Sedimentary inputs and oxygen uptake by the sediment in Lake Geneva (Switzerland)

Sediment cores and sediment traps were collected twice a month in two 35 m deep stations of Lake Geneva (Switzerland). The organic input sedimenting to the bottom is equal to 157 g C m⁻²y⁻¹ in station 1, to 214 g C in station 2. In spite of this difference, the oxygen uptake by the sediment (OUS) is similar in both locations (46–47 g C m⁻²y⁻¹). The oxygen uptake by the matter sedimenting to the bottom (OUSM) is respectively 45 g C m⁻²y⁻¹ and 41 g C in stations 1 and 2. The equivalence between OUS and OUSM implies that most of the sedimented matter arriving to the bottom is directly oxidized at the sediment surface. In station 1, OUS is positively correlated to OUSM, and OUSM is positively correlated to chlorophyll-a concentrations in the water column (0–20 m) one week before sediment sampling. In location 2, OUS is positively correlated to the percentage of organic carbon and nitrogen in the sedimented matter, negatively to its C:N ratio. Increasing allochthonous inputs have a negative influence on benthic respiration. At both sites, OUS is not directly related to macrobenthic biomass or to temperature of bottom water.     

Magnetic transition at 30–34 Kelvin in pyrrhotite: insight into a widespread occurrence of this mineral in rocks

A characteristic magnetic transition at 30–34 K is shown to provide a powerful tool for the identification of pyrrhotite with concentration down to 10 ppm through the same low-temperature techniques as applied to magnetite and hematite, extended down to liquid helium temperature. A review of rock magnetic and petrological data on pyrrhotite suggests that this mineral should be considered as a major carrier of paleomatnetic signals. Unblocking temperature up to 350°C and extreme resistance against AF may be encountered in fine grained pyrrhotite.     

The 2 Ga peraluminous magmatism of the Jacobina — Contendas Mirante Belt (Bahia) Brazil): Major and trace-element geochemistry and metallogenic potential

The Jacobina — Contendas Mirante belt represents a Transamazonian (2 Ga), N-S, 500-km long, elongated orogenic domain in the central part of the São Francisco craton, Bahia state. Numerous syntectonic to post-tectonic peraluminous leucogranites were emplaced along the major structures of the belt. Their mineralogical and geochemical and some of their metallogenetic characteristics are very similar to their Hercynian and Himalayan equivalents. However, their average peraluminous index varies from one granitic pluton to another and biotite is, on average, slightly more magnesian in the Transamazonian leucogranites. Higher oxygen fugacity is indicated by the general occurrence of magnetite, the stability of allanite and sometimes epidote in most of the plutons and by biotite chemistry. The peraluminous magmatism of the Jacobina-Contendas Mirante belt results from crustal partial melting during a continental collision event at 2 Ga.Trace-element geochemistry implies variable source composition and/or melting conditions for the different granitic plutons and some different facies within the same plutonic unit. The scarcity of ilmenite, the general occurrence of magnetite, and the relatively low peraluminous index of some of these granites suggest that graphite-beating sediments are not a significantly source material. From their mineralogical and geochemical characteristics, acid meta-igneous rocks such as the Sete Voltas TTG suite of presumed Archaean age, seem to represent a suitable source for these granites.Sn, W, Li, F and Be enrichment of most Transamazonian leucogranites is much weaker than in the mineralized Variscan equivalents. The Caetano-Aliança and Riacho das Pedras granites represent the most specialized granitic bodies. Beryl (emerald), molybdenite and scheelite mineralizations are related to some of these granites which intrude ultrabasic formations: the Campo Formoso and the Carnaiba granites. In many of these granites, uranium content is comparable to values measured in mineralized Hercynian leucogranites. The occurrence of hexavalent uranium minerals, mineralization and episyenitic alteration are favourable criteria for finding Variscan-type uranium ore deposits.     

Ritz vectors and generation criteria for mode superposition analysis

A generation procedure of Ritz vectors to control the inclusion of static effect and the number of vectors in mode superposition dynamic analysis is presented. The original algorithm of the Ritz vectors¹⁵ is modified to improve stability in the generation procedure and to include the use of static residual. To reject unimportant Ritz vectors, cut-off criteria, which are based on the participation of mass distribution and spatial load distribution, are proposed. Numerical examples are presented to illustrate the effectiveness of the derived Ritz vectors over the eigenvectors and the performance of the cutoff criteria in the mode superposition dynamic analysis.     

Recent dynamics of subarctic dunes as determined by tree-ring analysis of white spruce, Hudson Bay, Québec

The radial-growth patterns of white spruce were studied on a number of trees growing in subarctic dunes along the eastern coast of Hudson Bay to calculate the rates of accumulation, erosion, and migration of cold-climate sand dunes. The average rate of sand accumulation in sheltered dunes (forest sites) was 2.5 to 3.3 cm/yr, which is two to three times lower than in highly exposed dunes with a rate of sedimentation of 7.65 cm/yr. The average erosion rate was 1.4–1.7 cm/yr, about two times lower than the accumulation rate. The migration rate of sheltered dunes was 18 to 30 cm/yr, three to five times lower than for an exposed dune which advanced at a speed of 74 cm/yr. This migration rate established for highly exposed dunes in the Subarctic with tree-ring methods is about 10 times lower than that established for a barchan in the Sahara with other methods.     

A critical discussion of numerical models for multiaquifer systems

Leaky aquifers constitute complicated hydrological structures, whose inclusion in numerical models of hydrological systems is difficult, because of their three-dimensional nature. Methods for treating such systems can be classified as fully three-dimensional and quasi-three-dimensional. The latter have clear numerical advantages when applicable. In this paper a critical discussion of existing quasi-three-dimensional models is presented.     

Remarques comparatives sur quelques éléments sédimentologiques et paléogéographiques liés aux gisements de fer oolithiques du Djebel Ank (Tunisie) et de Lorraine (France)

Résumé Bien que de moindre intérêt économique, le gisement de fer oolithique du Djebel Ank se rapporte au type «Lorraine».Il s'agit d'une minéralisation localisée vers le littoral d'un sillon intracratonique, en marge du domaine géosynclinal et située, comme en Lorraine, dans une séquence lithologique négative, mais à lithofaciès détritiques en Lorraine, chimiques en Tunisie. On note aussi la localisation des grands gisements de phosphates dans les mêmes faisceaux stratigraphiques et dans les mêmes types de séquences que le gisement de fer du Djebel Ank, fer et phosphate présentant une radioactivité du même ordre et étant situés sur le même linéament.

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Although the Djebel Ank deposit is of less economic value, it may be correlated to «Lorraine» type. Mineralisation of Djebel Ank is found near the ancient shore line of a intracratonic trench on the border of geosynclinal area. The mineralisations both at Djebel Ank and Lorraine occur in a lithologic negative sequence, although the lithofacies are detridal in Lorraine and chemical in Tunisia. It is important to point out that phosphates and iron in Tunisia occur in the same stratigraphic series and in an identical type of lithologic sequence. Also iron ore is rich in phosphates. It is significant that the iron and phosphate contain same amount of radioactivities. Likewise, phosphate and iron in Tunisia are localized along a common «lineament».

     

Nitrogen compound emission from biomass burning in tropical African savanna FOS/DECAFE 1991 experiment (Lamto,Ivory Coast)

Gaseous nitrogen compounds (NO _x , NO _y , NH₃, N₂O) were measured at ground level in smoke plumes of prescribed savanna fires in Lamto, in the southern Ivory Coast, during the FOS/DECAFE experiment in January 1991. During the flaming phase, the linear regression between [NO _x ] and [CO₂] (differences in concentration between smoke plumes and atmosheric background) results volumic emission ratio [NO _x ]/[CO₂]=1.37×10^–3 with only slight differences between heading and backing fires. Nearly 90% of the nitrogen oxides are emitted as NO. Average emission ratios of other compounds are: 1.91, 0.047, and 0.145×10^–3 for NO _y , NH₃ and N₂O, respectively. The emission ratios obtained during this field experiment are compred with corresponding values measured during former experiments with the same plant species in combustion chambers. An accurate determination of both the biomass actually burned and of the plant nitrogen content, allows an assessment of emission fluxes of N-compounds from Guinean savanna burns. Preliminary results dealing with the influence of fire on biogenic emissions from soils are also reported.