Laboratory P-wave measurements in dry and saturated sand

We measure the P-wave velocity in a clean medium sand subject to very low stress in a large-scale laboratory cross-hole experiment for frequencies less than 10 kHz. In dry sand the velocity is depth-, and therefore, stress-dependent according to a power law. The velocity in partially saturated sand is essentially the same as in dry sand, which confirms the analytical result of the Biot–Gassmann theory. At 100% saturation, the velocity largely exceeds that in dry and partially saturated sand, once again in accordance with the Biot–Gassmann theory. However, the theory under-predicts velocities by up to 12% in some cases at full saturation. The maximum attenuation determined from spectral analysis of the measured signals closely matches the characteristic frequency predicted by the Biot model.     

Comparison of methods for the estimation of pyrite oxidation rate in a waste rock pile at Mine Doyon site, Quebec, Canada

Several methods were evaluated and compared for the estimation of pyrite oxidation rates (POR) in waste rock at Mine Doyon, Quebec, Canada. Methods based on data collected in situ, such as the interpretation of temperature and oxygen concentration profiles (TOP) measured in the waste rock pile and pyrite mass balance (PMB) on solid phase samples were compared with the oxygen consumption measurements (OCM) in closed chamber in the laboratory. A 1-D analytical solution to a gas and heat transport equation used temperature and oxygen profiles (TOP) measured in the pile for the preliminary POR estimates at a site close to the slope of the pile (Site 6) and in the core of the pile (Site 7). Resulting POR values were 1.1 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1 for the slope site and the core site, respectively. Oxidation rates based on pyrite mass balance (PMB) calculations for solid samples were 2.21 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 2.03 × 10^− 9 mol(O₂) kg^− 1 s^− 1, respectively, for the same slope and core sites, but the difference between sites was within the error margin. The OCM measurements in the laboratory on fresh waste rock samples yielded higher POR values than field methods, with average oxidation rate of 6.7 × 10^− 8 mol(O₂) kg^− 1 s^− 1. However, the OCM results on weathered and decomposed material from the rock stockpile (average oxidation rate 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1) were consistent with results from the field-based estimates. When POR values based on fresh material are excluded, the remaining POR values for all methods range from 1.0 × 10^− 10 to 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1. The lowest estimated value (1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1) was based on TOP estimates in the interior of the pile where oxygen transport was limited by diffusion from the surface. These results suggest that small-scale OCM laboratory experiments may provide relatively representative values of POR in the zones of waste rock piles in which oxygen transport is not dominated by diffusion.     

Relative performance of future altimeter systems and tide gauges in constraining a model of North Sea high-frequency barotropic dynamics

We evaluate in this paper the ability of several altimeter systems, considered separately as well as together with tide gauges, to control the time evolution of a barotropic model of the North Sea shelf. This evaluation is performed in the framework of the particular model errors due to uncertainties in bathymetry. An Ensemble Kalman Filter (EnKF) data assimilation approach is adopted, and observing-systems simulation experiments (OSSEs) are carried out using ensemble spread statistics. The skill criterion for the comparison of observing networks is, therefore, not based on the misfit between two simulations, as done in classic twin experiments, but on the reduction of ensemble variance occurring as a consequence of the assimilation. Future altimeter systems, such as the Wide Swath Ocean Altimeter (WSOA) and satellite constellations, are considered in this work. A single WSOA exhibits, for instance, similar performance as two-nadir satellites in terms of sea-level correction, and is better than three satellites in terms of model velocity control. Generally speaking, the temporal resolution of observations is shown to be of major importance for controlling the model error in these experiments. This result is clearly related to the focus adopted in this study on the specific high-frequency response of the ocean to meteorological forcing. Altimeter systems lack adequate temporal sampling for properly correcting the major part of model error in this context, whereas tide gauges, which provide a much finer time resolution, lead to better global statistical performance. When looking into further detail, tide gauges and altimetry are demonstrated to exhibit an interesting complementary character over the whole shelf, as tide gauge networks make it possible to properly control model error in a ∼100-km coastal band, while high-resolution altimeter systems are more efficient farther from the coast.     

The role of groundwater in cliff instability: an example at Cape Blanc‐Nez (Pas‐de‐Calais,France)

Cliff retreat in northern Boulonnais is described. The distribution of the amount of retreat is related to structural and topographic factors. Both control the runoff–infiltration balance and therefore the mechanical behaviour of the rocks, which determines the modes of failure. The spatial variability of the retreat rate is explained, but predicting the temporal variability of the retreat rate, which is central to risk management, is much more difficult. Rainfall and piezometric surface data enhanced a ‘piston flow’ mechanism during November 2000. The result of its occurrence on the stability of the cliff and conditions of its recurrence are examined with a view to better understanding the rate of recession of coastal cliffs and wiser management of risk. Copyright © 2005 John Wiley & Sons, Ltd.     

Book Reviews

Books reviewed:
MARSHA ALIBRANDI, GIS in the Classroom: Using Geographic Information Systems in Social Studies and Environmental Science
JO WOOD, Java Programming for Spatial Sciences     

Studying the migration behaviour of selenate in Boom Clay by electromigration

For the disposal of high-level waste (HLW) in a deep geological formation as Boom Clay, safety assessment studies have shown that long lived ⁷⁹Se is one of the more critical fission products. Therefore, the knowledge of its migration properties (diffusion, retention) through the geological barrier (Boom Clay) is of paramount importance. The migration behaviour of selenium strongly depends on its speciation. Under reducing conditions, selenide would be the dominant species and selenium migration would mainly be controlled by the low solubility of Se(−II)-bearing minerals. However Se species are often found in redox disequilibrium and more oxidized species might also coexist. Therefore, the study of selenate migration requires attention, as it might be the most mobile selenium species in the host rock. Electromigration experiments performed with a ⁷⁵Se-labeled selenate in Boom Clay indicate a high mobility for this species. The apparent diffusion coefficient (D_app) of selenate in Boom Clay is estimated from electromigration experiments performed under different electric fields. Using two independent approaches, the value of D_app for selenate is shown to fall in the range from 1.7×10⁻¹¹ to 6.2×10⁻¹¹ m² s⁻¹. Moreover, no reduction of selenate in Boom Clay was observed.     

2: Hydrothermal ore deposits related to post-orogenic extensional magmatism and core complex formation: The Rhodope Massif of Bulgaria and Greece

The Rhodope Massif in southern Bulgaria and northern Greece hosts a range of Pb–Zn–Ag, Cu–Mo and Au–Ag deposits in high-grade metamorphic, continental sedimentary and igneous rocks. Following a protracted thrusting history as part of the Alpine–Himalayan collision, major late orogenic extension led to the formation of metamorphic core complexes, block faulting, sedimentary basin formation, acid to basic magmatism and hydrothermal activity within a relatively short period of time during the Early Tertiary. Large vein and carbonate replacement Pb–Zn deposits hosted by high-grade metamorphic rocks in the Central Rhodopean Dome (e.g., the Madan ore field) are spatially associated with low-angle detachment faults as well as local silicic dyke swarms and/or ignimbrites. Ore formation is essentially synchronous with post-extensional dome uplift and magmatism, which has a dominant crustal magma component according to Pb and Sr isotope data. Intermediate- and high-sulphidation Pb–Zn–Ag–Au deposits and minor porphyry Cu–Mo mineralization in the Eastern Rhodopes are predominantly hosted by veins in shoshonitic to high-K calc-alkaline volcanic rocks of closely similar age. Base-metal-poor, high-grade gold deposits of low sulphidation character occurring in continental sedimentary rocks of synextensional basins (e.g., Ada Tepe) show a close spatial and temporal relation to detachment faulting prior and during metamorphic core complex formation. Their formation predates local magmatism but may involve fluids from deep mantle magmas.The change in geochemical signatures of Palaeogene magmatic rocks, from predominantly silicic types in the Central Rhodopes to strongly fractionated shoshonitic (Bulgaria) to calc-alkaline and high-K calc-alkaline (Greece) magmas in the Eastern Rhodopes, coincides with the enrichment in Cu and Au relative to Pb and Zn of the associated ore deposits. This trend also correlates with a decrease in the radiogenic Pb and Sr isotope components of the magmatic rocks from west to east, reflecting a reduced crustal contamination of mantle magmas, which in turn correlates with a decreasing crustal thickness that can be observed today. Hydrogen and oxygen isotopic compositions of the related hydrothermal systems show a concomitant increase of magmatic relative to meteoric fluids, from the Pb–Zn–Ag deposits of the Central Rhodopes to the magmatic rock-hosted polymetallic gold deposits of the Eastern Rhodopes.     

GeoReM: A New Geochemical Database for Reference Materials and Isotopic Standards

We have developed a new database named GeoReM ( http://georem.mpch-mainz.gwdg.de ) for reference materials and isotopic standards of geochemical and mineralogical interest. Reference samples include rock powders originating from the USGS, GSJ, GIT-IWG, synthetic and natural reference glasses originating from NIST, USGS, MPI-DING, as well as mineral (e.g., 91500 zircon), isotopic (e.g., La Jolla, E&A, NIST SRM 981), river water and seawater reference materials. GeoReM is a relational database, which strongly follows the concept of the three EARTHCHEM databases. It contains published analytical and compilation values (major and trace element concentrations, radiogenic and stable isotope ratios), important metadata about the analytical values, such as uncertainty, uncertainty type, method and laboratory. Sample information and references are also included. Three different ways of interrogating the database are possible: (1) sample names or material types, (2) chemical criteria and (3) bibliography. Some typical applications are described. GeoReM currently (October 2005) contains more than 750 geological reference materials, 6000 individual sets of results and references to 650 publications.