Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

On the Correlation between Convective Plume Updrafts and Downdrafts,Lidar Reflectivity and Depolarization Ratio

We question the correlation between vertical velocity (w) on the one hand and the occurrence of convective plumes in lidar reflectivity (i.e. range corrected backscatter signal Pz ²) and depolarization ratio (Δ) on the other hand in the convective boundary layer (CBL). Thermal vertical motion is directly investigated using vertical velocities measured by a ground-based Doppler lidar operating at 2 μm. This lidar provides also simultaneous measurements of lidar reflectivity. In addition, a second lidar 200 m away provides reflectivities at 0.53 and 1 μm and depolarization ratio at 0.53 μm. The time series from the two lidars are analyzed in terms of linear correlation coefficient (ρ). The main result is that the plume-like structures provided by lidar reflectivity within the CBL as well as the CBL height are not a clear signature of updrafts. It is shown that the lidar reflectivity within the CBL is frequently anti-correlated (ρ (w, Pz ² )) with the vertical velocity. On the contrary, the correlation coefficient between the depolarization ratio and the vertical velocity ρ (w, Δ ) is always positive, showing that the depolarization ratio is a fair tracer of updrafts. The importance of relative humidity on the correlation coefficient is discussed. An erratum to this article can be found at     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.     

Biaxial test simulations using a packing of polygonal particles

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.     

Ecohydrographic constraints on biodiversity and distribution of phytoplankton and zooplankton in coral reefs of the Red Sea,Saudi Arabia

An integral concept of ecological research is the constraint of biodiversity along latitudinal and environmental gradients. The Red Sea features a natural example of a latitudinal gradient of salinity, temperature and nutrient richness. Coral reefs along the Red Sea coasts are supported with allochthonous resources such as oceanic and neritic phytoplankton and zooplankton; however, relatively little is known about how the ecohydrography correlates with plankton biodiversity and abundance. In this article we present the biodiversity of phytoplankton and zooplankton in Red Sea coral reefs. Oceanographic data (temperature, salinity), water samples for nutrient analysis, particulate organic matter, phytoplankton and zooplankton, the latter with special reference to Copepoda (Crustacea), were collected at nine coral reefs over ~1500 km distance along the Red Sea coast of Saudi Arabia. The trophic state of ambient waters [as indicated by chlorophyll a (Chl a)] changed from strong oligotrophy in the north to mesotrophy in the south and was associated with increasing biomasses of Bacillariophyceae, picoeukaryotes and Synechococcus as indicated by pigment fingerprinting (CHEMTAX) and flow cytometry. Net‐phytoplankton microscopy revealed a Trichodesmium erythraeum (Cyanobacteria) bloom north of the Farasan Islands. Several potentially harmful algae, including Dinophysis miles and Gonyaulax spinifera (Dinophyceae), were encountered in larger numbers in the vicinity of the aquaculture facilities at Al Lith. Changes in zooplankton abundance were mainly correlated to the phytoplankton biomass following the latitudinal gradient. The largest zooplankton abundance was observed at the Farasan Archipelago, despite high abundances of copepodites, veligers (Gastropoda larvae) and Chaetognatha at Al Lith. Although the community composition changed over latitude, biodiversity indices of phytoplankton and zooplankton did not exhibit a systematic pattern. As this study constitutes the first current account of the plankton biodiversity in Red Sea coral reefs at a large spatial scale, the results will be informative for ecosystem‐based management along the coastline of Saudi Arabia.     

Oxygen and organic carbon fluxes in sediments of the Bay of Biscay

The relationship between particulate organic carbon (POC) concentrations measured in modern sediment and fluxes of exported POC to the sediment surface needs to be understood in order to use POC content as a proxy of paleo-environmental conditions. The objective of our study was to compare POC concentrations, POC mineralization rates calculated from O₂ consumption and POC burial rates. Benthic O₂ distributions were determined in 58 fine-grained sediment cores collected at different periods at 14 stations in the southeastern part of the Bay of Biscay with depths ranging from 140 to 2800 m. Depth-dependent volume-specific oxygen consumption rates were used to assess rates of aerobic oxidation of organic matter (OM), assuming that O₂ consumption solely was related to heterotrophic activity at the sediment–water interface. Heterogeneity of benthic O₂ fluxes denoted changes in time and space of fresh organic material sedimentation. The most labile fraction of exported POC engendered a steep decrease in concentration in the upper 5 mm of vertical O₂ profiles. The rupture in the gradient of O₂ microprofile may be related to the bioturbation-induced mixing depth of fast-decaying carbon. Average diffusive O₂ fluxes showed that this fast-decaying OM flux was much higher than buried POC, although diffusive O₂ fluxes underestimated the total sediment oxygen demand, and thus the fast-decaying OM flux to the sediment surface. Sedimentary POC burial was calculated from sediment mass accumulation rate and the organic carbon content measured at the top of the sediment. The proportion of buried POC relative to total exported POC ranged at the most between 50% and 10%, depending on station location. Therefore, for a narrow geographic area like the Bay of Biscay, burial efficiency of POC was variable. A fraction of buried POC consisted of slow-decaying OM that was mineralized within the upper decimetres of sediment through oxic and anoxic processes. This fraction was deduced from the decrease with depth in POC concentration. At sites located below 500 m water depth, where the fast-decaying carbon did not reach the anoxic sediment, the slow-decaying pool may control the O₂ penetration depth. Only refractory organic material was fossilized in sedimentary records at locations where labile OM did not reach the anoxic portion of the sediment.     

Petrography of alluvial sands as a past and present environmental indicator: Case of the Loire River (France)

Four sample sets of the Upper and Middle Loire river sands were analyzed in order to study the impact of natural and anthropogenic factors on their petrographic composition in space (on an 800 km stretch) and time. Composition was determined by modal analysis of three sand-size fractions using a polarizing optical microscope and calculated for each sample (“standard sand” = Sst). The watershed is composed mainly of endogenic (Massif Central) and sedimentary (southern Parisian Basin) rocks. B-set sands collected in channels for different water flows in 1996 show that Sst compositions vary by only 5 %. Present-day sands in the Upper Loire and Middle Loire have very high petrographic immaturity comparing to others worldwide fluvial sands, although bio-climatic conditions favor sand maturation by source-rock weathering in the watershed. This shows the strong impact of the Massif Central on sediment yield due to relief rejuvenation as a consequence of the formation of the Alps during the Quaternary. Fluvial sands stored during the Weichselian and the Holocene in the Middle Loire floodplain, although partly weathered since their deposition, show higher inputs from the endogenic rocks of the Massif Central than present-day deposits. This can be explained by Weichselian periglacial conditions and the development of crop farming since the Neolithic, which favored mechanical erosion, particularly in the Massif Central which is characterized by a cold, humid climate and steep slopes. The upstream-downstream change in the composition of presently deposited sand is low in the diked area. It shows however that basalt and some heavy mineral grains are vulnerable to abrasion during transport and indicates a marked sediment yield from ancient sediment stored in the floodplain. This is in line with the high incision of the river bed over the last 150 years partly due to dam construction and aggregate mining.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Flood‐based analysis of high‐magnitude sediment transport using a non‐parametric method

Upland erosion and the resulting reservoir siltation is a serious issue in the Isábena catchment (445 km² Central Spanish Pyrenees). During a three‐month period, water and sediment fluxes have been monitored at the catchment outlet (Capella), two adjacent subcatchments (Villacarli, 41 km²; Cabecera, 145 km²) and the elementary badland catchment Torrelaribera (8 ha). This paper presents the results of the monitoring, a method for the calculation of a sedigraph from intermittent measurements and the derived sediment yields at the monitored locations. The observed suspended sediment concentrations (SSCs) demonstrate the role of badlands as sediment sources: SSCs of up to 280 g l^?1 were encountered for Villacarli, which includes large badland areas. SSCs at the Cabecera catchment, with great areas of woodland, barely exceeded 30 g l^?1. SSCs directly at the sediment source (Torrelaribera) were comparable to those at Villacarli, suggesting a close connection within this subcatchment. At Capella, SSCs of up to 99 g l^?1 were observed. For all sites, SSC displayed only a loose correlation with discharge, inhibiting the application of a simple sediment rating curve. Instead, ancillary variables acting as driving forces or proxies for the processes (rainfall energy, cumulative discharge, rising/falling limb data) were included in a quantile regression forest model to explain the variability in SSC. The variables with most predictive power vary between the sites, suggesting the predominance of different processes. The subsequent flood‐based calculation of sediment yields attests high specific sediment yields for Torrelaribera and Villacarli (6277 and 1971 t km^?2) and medium to high yields for Cabecera and Capella (139 and 410 t km^?2) during the observation period. In all catchments, most of the sediment was exported during intense storms of late summer. Later flood events yield successively less sediment. Relating upland sediment production to yield at the outlet suggests considerable effects of sediment storage within the river channel. Copyright © 2008 John Wiley & Sons, Ltd.     

Joint patterns and their relationship to regional trends

An analysis of joint patterns in the Grampians Group rocks o£ Western Victoria has established that the dominant directions are north‐north‐west, east‐north‐east, west‐north‐west, north‐north‐east and north. The master joints are steeply‐dipping structures which formed after the sediments were lithified and folded. The joint‐formation is not genetically related to the folding and post‐dates the emplacement of the igneous intrusions. Joint orientation is independent of lithology and the sediments have reacted as a uniform mass to an applied stress.

The joint pattern conforms with the regional tectonic pattern of faults and lineaments which includes directions of the regmatic shear pattern of Sonder (1947). The jointing and major faulting took place during the Kanimblan Orogeny. The faulting and joint‐formation may have been contemporaneous, the faults being directions along which displacement occurred; conversely the actual movements along faults may have induced the jointing into the sediments.