Palaeosecular variation over the past 5 Myr based on a new generalized database

A generalized database of global palaeomagnetic data from 3719 lava flows and thin dykes of age 0–5 Ma has been constructed for use with a relational database management system. The database includes all data whose virtual geomagnetic poles (VGP) lie within 45 of the spin axis and can be used for studies of palaeosecular variation and for geomagnetic field modelling. Because many of these data were collected and processed more than 15–20 years ago, each result has been characterized according to the demagnetization procedures carried out. Analysis of these data in terms of the latitude variation of the angular dispersion of VGPs (palaeosecular variation from lavas) strongly suggests that careful data selection is required and that many of the older studies may need to be redone using more modern methods. Differences between the angular dispersions for separate normal- and reverse-polarity data sets confirm that many older studies have not been adequately cleaned magnetically. Therefore, the use of the database for geomagnetic field modelling should be carried out with some caution. Using a VGP cut-off angle that varies with latitude, the best data set consists of 2636 results that show a smooth increase of VGP angular dispersion with latitude. Model G for palaeosecular variation, which is based on modelling of the antisymmetric (dipole) and symmetric (quadrupole) dynamo families, provides a good fit to these results.     

Water source dynamics of high Arctic river basins

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Hydrographic Vertical Separation Surfaces (HyVSEPs) for the Tidal Waters of Canada

Since the advent of Global Navigation Satellite Systems, it has been possible to perform hydrographic survey reductions through the ellipsoid, which has the potential to simplify operations and improve bathymetric products. This technique requires a spatially continuous separation surface connecting chart datum (CD) to a geodetic ellipsoid. The Canadian Hydrographic Service (CHS), with support from the Canadian Geodetic Survey, has developed a new suite of such surfaces, termed Hydrographic Vertical Separations Surfaces, or HyVSEPs, for CD and seven tidal levels. They capture the spatial variability of the tidal datum and levels between tide gauges and offshore using semiempirical models coupling observations at tide stations with relative sea-level rise estimates, dynamic ocean model solutions, satellite altimetry, and a geoid model. HyVSEPs are available for all tidal waters of Canada, covering over seven million square kilometers of ocean and more than 200,000 kilometers of shoreline. This document provides an overview of the CHS's modeling approach, tools, methods, and procedures.

The HyVSEP for CD defines the new hydrographic datum for the tidal waters of Canada. HyVSEPs for other tidal levels are fundamental for coastal studies, climate change adaptation and the definition of the Canadian shoreline and offshore boundaries. HyVSEPs for inland waters are not discussed.     

A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.     

Experimental formation of massive hydrate deposits from accumulation of CH4 gas bubbles within synthetic and natural sediments

In order for methane to be economically produced from the seafloor, prediction and detection of massive hydrate deposits will be necessary. In many cases, hydrate samples recovered from seafloor sediments appear as veins or nodules, suggesting that there are strong geologic controls on where hydrate is likely to accumulate. Experiments have been conducted examining massive hydrate accumulation from methane gas bubbles within natural and synthetic sediments in a large volume pressure vessel through temperature and pressure data, as well as visual observations. Observations of hydrate growth suggest that accumulation of gas bubbles within void spaces and at sediment interfaces likely results in the formation of massive hydrate deposits. Methane hydrate was first observed as a thin film forming at the gas/water interface of methane bubbles trapped within sediment void spaces. As bubbles accumulated, massive hydrate growth occurred. These experiments suggest that in systems containing free methane gas, bubble pathways and accumulation points likely control the location and habit of massive hydrate deposits.     

The karst contagion model: Synopsis and environmental implications

The contagion model of karst terrane evolution focuses on the environmental implications for a large karst depression population on the Pennyroyal Plain (southern Kentucky) and the adjacent Western Highland Rim (Tennessee) immediately south of the Mammoth Cave Plateau. In karst terranes where the contagion model applies, there is a well-defined infrastructure comprised of hydrologic, structural geologic and geomorphic interacting elements that result in clustered depressions underlain by a radial conduit system. Clusters tend to be randomly distributed and typically contain a parent depression surrounded by numerous daughters.Groundwater flow is assumed to be turbulent and confined largely to conduits that are 3-dimensionally configured between clusters in a dendritic to trellis network. Parent depressions serve as conduit nodes for collecting groundwater migrating from beneath daughter depressions.Flow velocities in the 3-dimensional cluster-cell conduits exceed those in granular media by several orders of magnitude making pathogen and chemical contaminant migration rapid. Groundwater quality assessment in karst conduit hydrogeologic settings is difficult because monitoring wells are inappropriate. Monitoring wells may have a low probability of intercepting a major conduit and therefore the sampling regime must take into consideration the pulse discharge of pollutants in karst conduits. Representative water quality data must come from springs located near the local base level.