Evolution of the fogwater composition in Strasbourg (France) from 1990 to 1999

The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO_2(g) and the resulting SO₄²⁻. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.     

Why GPS makes distances bigger than they are

Global navigation satellite systems such as the Global Positioning System (GPS) is one of the most important sensors for movement analysis. GPS is widely used to record the trajectories of vehicles, animals and human beings. However, all GPS movement data are affected by both measurement and interpolation errors. In this article we show that measurement error causes a systematic bias in distances recorded with a GPS; the distance between two points recorded with a GPS is – on average – bigger than the true distance between these points. This systematic ‘overestimation of distance’ becomes relevant if the influence of interpolation error can be neglected, which in practice is the case for movement sampled at high frequencies. We provide a mathematical explanation of this phenomenon and illustrate that it functionally depends on the autocorrelation of GPS measurement error (C). We argue that C can be interpreted as a quality measure for movement data recorded with a GPS. If there is a strong autocorrelation between any two consecutive position estimates, they have very similar error. This error cancels out when average speed, distance or direction is calculated along the trajectory. Based on our theoretical findings we introduce a novel approach to determine C in real-world GPS movement data sampled at high frequencies. We apply our approach to pedestrian trajectories and car trajectories. We found that the measurement error in the data was strongly spatially and temporally autocorrelated and give a quality estimate of the data. Most importantly, our findings are not limited to GPS alone. The systematic bias and its implications are bound to occur in any movement data collected with absolute positioning if interpolation error can be neglected.     

Paleohydrology and paleoclimate records in a saline prairie lake core: mineral,isotope and organic indicators

This pilot study examines the potential of obtaining a sedimentary record of paleoenvironmental/climatic/hydrologic conditions for saline Redberry Lake in southern Saskatchewan, Canada. The tools are mineralogy, stable isotopes and pigments. The upper meter of an offshore sediment core contains 10 to 20% by weight aragonite (CaCO₃), which apparently precipitated in the water column. The ¹⁸O and ¹³C of the bulk aragonite (corrected for content of detrital calcite) vary by 4 to 5. Enrichment in ¹⁸O in aragonite is significantly correlated with pigment concentrations (chlorophyll a, phaeophytin). The ¹⁸O and pigment data provide evidence for relatively dry and/or warm conditions and high limnetic productivity for the period 2500 to 1500 yrs B.P. After 1500 B.P., the climate was apparently similar to the present, with two episodes of relatively enhanced productivity, dryness and/or warmth, at around 1000 to 900 and 500 to 200 B.P. During the past century, Redberry Lake has decreased approximately 8 m in depth and its salinity has doubled. No clear sedimentary signal was observed in response to these recent hydrologic trends. These changes have not been associated with a significant climate trend in the region, but may have been induced by land use changes in the catchment.This publication is the third of a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor for this series.     

Radiation from an impulsive line source in an unbounded homogeneous anisotropic medium

Summary. The space-time elastic wave motion generated by an impulsive line source in a homogeneous anisotropic medium is calculated with the aid of the Cagniard-de Hoop method. Two types of sources are considered in detail, viz. a line source of expansion (model for an explosive source) and a line force (model for a mechanical vibrator). Numerical results are presented for the radiated particle velocity in the medium including those regions of space where shear-wave triplication occurs. There is a marked difference in the time response observed for the two types of sources and for the different positions of the receiver with respect to the source position. These waveform differences are important when the radiated wave is used to determine experimentally the elastic properties of the medium. As compared with the traditional Fourier-integral transform method to handle this problem, the computation time with the present method is considerably less.     

Stratigraphic architecture of Solander Basin records Southern Ocean currents and subduction initiation beneath southwest New Zealand

Solander Basin is characterized by subduction initiation at the Pacific‐Australia plate boundary, where high biological productivity is found at the northern edge of the Antarctic Circumpolar Current. Sedimentary architecture results from tectonic influences on accommodation space, sediment supply and ocean currents (via physiography); and climate influence on ocean currents and biological productivity. We present the first seismic‐stratigraphic analysis of Solander Basin based on high‐fold seismic‐reflection data (voyage MGL1803, SISIE). Solander Trough physiography formed by Eocene rifting, but basinal strata are mostly younger than ca. 17 Ma, when we infer Puysegur Ridge formed and sheltered Solander Basin from bottom currents, and mountain growth onshore increased sediment supply. Initial inversion on the Tauru Fault started at ca. 15 Ma, but reverse faulting from 12 to ca. 8 Ma on both the Tauru and Parara Faults was likely associated with reorganization and formation of the subduction thrust. The new seabed topography forced sediment pathways to become channelized at low points or antecedent gorges. Since 5 Ma, southern Puysegur Ridge and Fiordland mountains spread out towards the east and Solander Anticline grew in response to ongoing subduction and growth of a slab. Solander Basin had high sedimentation rates because (1) it is sheltered from bottom currents by Puysegur Ridge; and (2) it has a mountainous land area that supplies sediment to its northern end. Sedimentary architecture is asymmetric due to the Subtropical Front, which moves pelagic and hemi‐pelagic sediment, including dilute parts of gravity flows, eastward and accretes contourites to the shelf south of Stewart Island. Levees, scours, drifts and ridges of folded sediment characterize western Solander Basin, whereas hemi‐pelagic drape and secondary gravity flows are found east of the meandering axial Solander Channel. The high‐resolution record of climate and tectonics that Solander Basin contains may yield excellent sites for future scientific ocean drilling.     

An adaptive finite element model for wellbore breakout simulation

A finite element formulation is proposed and implemented for analysing the stability of excavated wells using the DiMaggio-Sandler constitutive elastoplastic model with a typical carbonate reservoir configuration. The quality of the finite element approximation is ensured by applying smooth curved elements adapted to the wellbore geometry, and h − p adaptive finite element meshes in the plastic zone. General purpose procedures are defined to transfer the elastoplastic deformation history to newly created integration points. A breakout damage criterion is proposed based on the second invariant of the deviatoric plastic deformation tensor. This damage criterion is used to apply a mesh movement algorithm to represent material collapse. The automatic successive application of the breakout damage criterion results in elliptical realistically looking geometries obtained in experiments reported in the literature.     

Meteoric fluid‐rock interaction in Variscan shear zones

Variscan shear zones in the Armorican Massif represent sites of strong fluid‐rock interaction. The hydrogen isotope composition of muscovite (δD_Ms) from syntectonic leucogranite allows to determine the source of fluids that infiltrated the footwall of three detachment zones and the South Armorican Shear Zone. Using temperatures of hydrogen isotope exchange estimated from microstructural data, we calculate the hydrogen isotope ratios of water (δD_water) present within the shear zones during high‐temperature deformation. A ~40‰ difference in δD_water values from deep to shallow crustal level reveals a mixing relationship between deep crustal fluids with higher δD values that range from ?34 to ?33‰, and meteoric fluids with δD values as low as ?74‰ in the upper part of detachment footwalls.     

Biomarker distributions in asphaltenes and kerogens analysed by flash pyrolysis-gas chromatography-mass spectrometry

Biomarker distributions in a suite of asphaltenes and kerogens have been analysed by flash pyrolysis directly coupled to a GCMS system. Attention has been focussed on biomarkers of the sterane and triterpane types. The sample suite under investigation consists of sediments with different kerogen types and some crude oils. Biomarker distributions in the pyrolysates have been compared with the “free” biomarkers in the corresponding saturated hydrocarbon fractions.The analyses show significant differences between the distributions of the free biomarkers and those in the pyrolysates. The latter have lower amounts of steranes while diasteranes are absent or present at low concentrations only. In the triterpane traces a shift of maximum intensity from C₃₀ (free compounds) to C₂₇/C₂₉ is observed. Furthermore, the pyrolysates contain a set of triterpenes (not present among the free compounds), and there is a selective loss of “non-regular” triterpanes that are present in the saturated hydrocarbon fractions. The observed differences between pyrolysates and free hydrocarbons can be explained partly by the processes occurring during pyrolysis such as bond rupture and subsequent stabilisation of primary pyrolysis products. To a certain extent these differences also show that maturation processes occurring in sediments have effects on free biomarker molecules different from those on molecules that are enclosed in a macromolecular matrix (kerogen or asphaltenes).Differences between biomarker distributions of asphaltene and kerogen pyrolysates are relatively small. A comparison with the pyrolysates from extracted whole sediments suggests that these differences are mainly caused by interactions between the organic material and the mineral matrix during pyrolysis.Oil asphaltenes behave differently from sediment asphaltenes as their pyrolysates are more similar to the corresponding saturated hydrocarbon fractions, i.e. the differences described above are observed to a much smaller extent. This different behaviour appears to be the result of coprecipitation of a part of the maltene fraction with the oil asphaltenes.     

Defect structures in naturally deformed clinoamphiboles—a TEM study

Naturally deformed clinoamphiboles from the Selbu-Tydal and Forsbäck-Tärnaby areas of the Scandinavian Caledonides exhibit a well defined subgrain microstructure. From a transmission electron microscopy study (TEM), the subgrain boundaries are shown to consist of arrays of positive and negative screw dislocations with Burgers vector . Locally expanded loops are present having long screw segments. The subgrain boundaries are parallel to rational crystallographic planes of the type (hk0). The density of isolated dislocations within the subgrains is low. In addition planar defect structures parallel to (010) and bounded by screw dislocations with are observed. Based on metamorphic criteria the P−T values at the time of the amphibole growth have been estimated at 450°–600°C and 4–6 kbar, and these represent maximum conditions for the deformation. The present results indicate that slip on (hk0) [001] is an operative deformation mechanism in naturally deformed clinoamphiboles.     

Lateglacial palaeoenvironments and palaeoclimates from Conty and Houdancourt, northern France, reconstructed from Beetle remains

Two Lateglacial insect sequences are described (a) from Conty, in the Selle valley and (b) from Houdancourt in the Oise valley, both in northern France. These investigations are part of a multidisciplinary investigation involving archaeology, sedimentology, geomorphology, geochronology and palaeontology (pollen, macroscopic plant remains, vertebrates, molluscs and insect fossils). The sequences of insect assemblages date from the latter part of the Bølling to the end of the Allerød periods. Environmental analysis of these faunas shows that rivers with riffles and pools meandered across flood plains. The river was extensively fringed with reedy vegetation. The only trees growing close to the river were of Salix and/or Populus. All the insect assemblages indicate that the thermal climates during the Bølling and Allerød periods were similar to one another and during both periods were very nearly as warm as that of the present day. No insect fossils were recovered from the sediments attributed to the Older Dryas interval though other evidence from these sites suggests that this event was decidedly colder than those immediately preceding and succeeding it. Comparisons are made between Lateglacial climatic patterns in northern France with those elsewhere in Europe.