Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Steady- and transient-state inversion in hydrogeology by successive flux estimation

A calibration method to solve the groundwater inverse problem under steady- and transient-state conditions is presented. The method compares kriged and numerical head field gradients to modify hydraulic conductivity without the use of non-linear optimization techniques. The process is repeated iteratively until a close match with piezometric data is reached. The approach includes a damping factor to avoid divergence and oscillation of the solution in areas of low hydraulic gradient and a weighting factor to account for temporal head variation in transient simulations. The efficiency of the method in terms of computing time and calibration results is demonstrated with a synthetic field. It is shown that the proposed method provides parameter fields that reproduce both hydraulic conductivity and piezometric data in few forward model solutions. Stochastic numerical experiments are conducted to evaluate the sensitivity of the method to the damping function and to the head field estimation errors.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

琼西抱板群变质沉积岩地球化学研究

琼西中元古代抱板群变质沉积岩可分为白云母石英片岩组和石英二云母片岩组,其原岩为砂岩质泥质沉积岩夹火山物质。白云母石英片岩组和石英二云母片岩组在地球化学成分上的差异是原始沉积化学分异作用的结果。对主元素、微量元素（含稀土元素）及Sm-Nd同位素的综合研究表明,海南岛存在古元古代或更早的古老基底,抱板群变质沉积岩一部分来源于成熟度较低的古老地壳物质,另一部分来源于含地幔火山物质较多的初生地壳,或与研究区大规模造山运动、构造－岩浆活动所伴生的地幔物质加入有关。初步研究显示,琼西抱板群变质沉积岩可能是造山带岛弧和活动大陆边缘区（扩张弧后或弧间盆地）大地构造环境下的沉积产物。     

The hard solar X-ray burst of 18 September 1963

A hard solar X-ray burst was observed by J-P. Legrand on 18 September 1963, 13:56 UT, at balloon altitude. It lasted a few minutes; a steep increase was followed by an exponential decay. During its declining phase a weak radio burst was observed on 3 and 10 cm, not on longer wavelengths.Maximum radio intensity occurred two minutes after that of the X-ray burst. The X-ray and radio bursts ended almost simultaneously. Optically a small shortlived (some minutes) flare point occurred simultaneously with the X-ray burst in a magnetically interesting part of the active region of September 1963. The X-burst photons seem to have had an energy of about 0.5 MeV. The burst was therefore of a fairly rare type, since very few other bursts with similar photon energies have been detected up to now.It is suggested that a mass of gas, magnetically confined to a volume of about 5·10²⁵ cm³ in the low corona, containing about 3·10³⁵ electrons was accelerated to energies of about 0.5 MeV. The gas gradually expanded, partly also to higher levels. The gyro-synchrotron radiation, emitted by the plasma became observable after about two minutes. At the lower radio frequencies the radiation was absorbed by overlying undisturbed coronal matter. Quantitative computations justify this model. A detailed summary of the events, and some numerical data are given in the concluding Section 8 and in Table V.     

海洋细菌抑菌活性菌株的筛选

从不同海区的海洋底质，生物样，水样中分离到480株海洋细菌，其中包括150株芽孢细菌和108株粪大肠杆菌，利用纸片法对其抑菌活性进行检测，结果表明：117株海洋细菌具有抑菌活性，占总分离菌株的24.4%；一般细菌，芽孢细菌，粪大肠杆菌的抑菌活性菌株分别占各供测菌株的17.1%,27.3%,35.2%；抑菌活性菌株的比例与样品来源密切相关，且各类海洋细菌的抗菌谱有很大的不同。     

Iodine chemistry in deep anoxic basins and overlying waters of the Mediterranean Sea

Iodate (IO₃⁻) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I⁻) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I⁻ (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO₄³⁻) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis.     

新疆经济增长特征与驱动力分析

分析了新疆经济增长的特征以及影响经济增长的因素,选取可能对经济增长有影响的几个指标,通过灰色系统的关联分析法,对这些因素进行定量分析,从分析结果我们可以得出投资与消费是目前新疆经济增长的第一驱动力,科学技术是新疆未来经济增长的主要驱动力,传统要素自然资源、交通、人力资本等仍然是新疆经济增长的基础驱动力,政府行政体制的作用正在慢慢下降,城市化是经济增长潜在的驱动力,环境也越来越成为新疆经济增长的制约因素,并对这些结论进行分析,剖析新疆经济增长的内在原因,对今后新疆经济的发展有一定的理论和现实意义。     

Study of the air-sea interactions at the mesoscale: the SEMAPHORE experiment

The SEMAPHORE (Structure des Echanges Mer-Atmosphère, Propriétés des Hétérogénéités Océaniques: Recherche Expérimentale) experiment has been conducted from June to November 1993 in the Northeast Atlantic between the Azores and Madeira. It was centered on the study of the mesoscale ocean circulation and air-sea interactions. The experimental investigation was achieved at the mesoscale using moorings, floats, and ship hydrological survey, and at a smaller scale by one dedicated ship, two instrumented aircraft, and surface drifting buoys, for one and a half month in October-November (IOP: intense observing period). Observations from meteorological operational satellites as well as spaceborne microwave sensors were used in complement. The main studies undertaken concern the mesoscale ocean, the upper ocean, the atmospheric boundary layer, and the sea surface, and first results are presented for the various topics. From data analysis and model simulations, the main characteristics of the ocean circulation were deduced, showing the close relationship between the Azores front meander and the occurrence of Mediterranean water lenses (meddies), and the shift between the Azores current frontal signature at the surface and within the thermocline. Using drifting buoys and ship data in the upper ocean, the gap between the scales of the atmospheric forcing and the oceanic variability was made evident. A 2 °C decrease and a 40-m deepening of the mixed layer were measured within the IOP, associated with a heating loss of about 100 W m⁻². This evolution was shown to be strongly connected to the occurrence of storms at the beginning and the end of October. Above the surface, turbulent measurements from ship and aircraft were analyzed across the surface thermal front, showing a 30% difference in heat fluxes between both sides during a 4-day period, and the respective contributions of the wind and the surface temperature were evaluated. The classical momentum flux bulk parameterization was found to fail in low wind and unstable conditions. Finally, the sea surface was investigated using airborne and satellite radars and wave buoys. A wave model, operationally used, was found to get better results compared with radar and wave-buoy measurements, when initialized using an improved wind field, obtained by assimilating satellite and buoy wind data in a meteorological model. A detailed analysis of a 2-day period showed that the swell component, propagating from a far source area, is underestimated in the wave model. A data base has been created, containing all experimental measurements. It will allow us to pursue the interpretation of observations and to test model simulations in the ocean, at the surface and in the atmospheric boundary layer, and to investigate the ocean-atmosphere coupling at the local and mesoscales.