Dynamic controls on wind erosion and dust generation on west‐central Free State agricultural land,South Africa

The west‐central part of South Africa's Free State Province falls within the transition zone between South Africa's sub‐humid, temperate grasslands to the east, and the semi‐arid Karoo and arid Kalahari to the south and west, respectively. The area is characterized by low rainfall (typically 500 mm or less) with high variability, but environmental conditions allow widespread dryland commercial agriculture (maize, sunflowers and stock farming). However, human activity promotes wind erosion and the area is susceptible to dust emissions. This study is the first to quantify the degree of wind erosion on the agricultural soils in the region under prevailing winter to spring climatic conditions and land management practices. Using arrays of cup anemometers, dust deposition traps and saltation impact sensors (Safires), measurements were made of the key erosivity and erodibility drivers that control the degree of wind erosion. Results demonstrate that significant quantities of dust are mobilized, particularly during the months of September and October. Thresholds of wind erosion are shown to respond particularly closely to changes in surface and aerodynamic roughness (z₀) with the amount of collected dust correlating well with measures of wind erosivity that weight the impact of higher wind speeds. Given the importance of surface roughness in controlling erosion thresholds, results show that the opportunity exists for well designed farming practices to control wind erosion. However, it is likely that climatically driven environmental change will impact on some of the identified controls on erosion (wind power, moisture availability) with the result that the wind erosion hazard is likely to increase within this marginal environment. Copyright © 2010 John Wiley & Sons, Ltd.     

Mercury transformations and fluxes in sediments of a riverine wetland

Porewater samples were obtained on five occasions during spring, summer and fall by in situ dialysis from three sites of a large freshwater wetland situated along the St. Lawrence River. These samples were analysed for total dissolved mercury ([Hg]_T) and methylmercury ([MeHg]) concentrations and for complementary variables including dissolved sulfate, sulfide and elemental sulfur concentrations. Sediment cores were obtained on three occasions from one of these sites for the determination of total mercury ({Hg}_T) and methylmercury ({MeHg}) concentration as well as mercury methyltransferase (HgMT) activity profiles. {MeHg} and HgMT activity varied with time and sediment depth. The porewater [Hg]_T and [MeHg] depth profiles varied with time and among sites. Modeling the porewater [MeHg] profiles with a one-dimensional reaction-transport equation allowed identification of the sediment depths where MeHg is produced or consumed, as well as an estimate of the net in situ MeHg production rates in the sediments. The model-predicted depths of MeHg production, as well as the sulfate concentration and the HgMT activity depth distributions are all consistent with the involvement of sulfate reducing bacteria in the production of MeHg.     

Apatite and scapolite as petrogenetic indicators in granolites of Milford Sound,New Zealand

A network of 5 cm wide subplanar zones of garnet-granolite with accessory apatite as the dominant hydrous mineral, is overprinted on basic hornblende-granolites in an area of present and past tectonic uplift. Fracturing and the garnet forming reactions appear to be caused by destabilisation of hornblende, as a hydrous phase, through a critical drop in the PT ratio. Whereas the apatites from the hornblende-granolite have normal compositions, apatites from the garnet-granolite zones are among the most chlorine enriched hydroxyfluorapatites known. A later amphibolite facies event has depleted hydrous minerals of fluorine and chlorine, affecting hornblende more strongly than apatite. Based on literature data on F and Cl in coexisting minerals, original hornblende compositions are tentatively restored. It is then possible to derive all the chlorine of the garnet zone apatites from the original rock, with differential loss of H₂O and HF over chlorine during the dehydration reaction. Diffusion coefficients would have been larger for H₂O and HF than for the large chloride ion, and if the gas phase was in contact with even minor anatectic melts, activity gradients would also have been relatively small for chlorine. Low-Cl scapolite is present in quartz-free pegmatoid veins. Field evidence for a genetic tie between the garnet zones and these veins is inconclusive, but liberation of H₂O and HF under granolite facies conditions is likely to have caused limited fusion of the plagioclase. Since many garnet zones do not contain even small pegmatoid veins, melts related to their formation could have collected in veins only after initial diffusion or infiltration over a distance, and without leaving segregated mafic residues.     

The Middle Pleistocene terraces of the central Waveney valley,Earsham, south Norfolk,UK

Although substantial work has been done on the pre-glacial terraces of East Anglia, very little systematic work has been done to understand the origin of river terraces in East Anglia that have formed since ice last covered the region. This paper records the results of studies of exposures and borehole records in ‘classical’ Quaternary terrace landforms that are considered to have formed since the Anglian (MIS 12) Glaciation, in the middle Waveney Valley. These features have been examined in terms of their morphological and sedimentological properties, in order to provide a detailed record of their form and composition, understand their processes of formation, and identify their stratigraphical status. The results show that the main body of the highest terrace (Homersfield Terrace, Terrace 3) is not composed of river sediments, but of shallow marine sediments, and is a remnant of early Middle Pleistocene Wroxham Crag. River sediments, in the form of Anglian age (MIS 12) glaciofluvial Aldeby Sands and Gravels also exist in the area as a channel fill, cut through the Wroxham Crag, and reflect outwash erosion and sedimentation from a relatively proximal ice margin to the west. The results mean that the interpretations previously presented for the terrace landforms of the middle Waveney valley are not applicable. The issue of why the terrace stratigraphy, hitherto identified in East Anglia cannot be related to that for the River Thames to the south and the rivers of Midland England to the west, still requires further research.     

Mineralogy of New Caledonian metamorphic rocks

Variations in chemistry and related physical properties of sheet silicates in the Ouégoa district with metamorphic grade are investigated. Weakly metamorphosed rocks prior to the crystallization of lawsonite contain phengite (d ₀₀₆=3.317–3.323 Å), chlorite and occasionally paragonite while interstratified basaltic sills contain chlorite, minor phengite and stilpnomelane. Pyrophyllite crystallizes before lawsonite in some metamorphosed acid tuffs and is also stable in the lawsonite zone. Paragonite, phengite and chlorite appear to be stable through the sequence from weakly metamorphosed rocks into high-grade “eclogitic” schists and gneisses. Optical, chemical and some X-ray diffraction data is given for representative sheet silicates. Electron probe analyses of 55 phengites, 21 paragonites, 57 chlorites, 12 vermiculites, 2 stilpnomelanes, and 2 chloritoids are presented in graphical form. All K-micas analysed are consistently phengitic (3.29–3.55 Si^iv ions per formula unit) and show limited solid solution with paragonite (4 to 13% Pa). The K∶Na ratio of the phengite is strongly dependant on the assemblage in which it occurs; the amount of phengite component and its Fe∶Mg ratio depends on bulk-rock composition. Phengites from acid volcanics have the highest Fe∶Mg ratio, highest phengite component and β refractive indices. Phengites from basic volcanics and metasediments of the epidote zone have the lowest Fe∶Mg ratio. Phengites from lawsonite-zone metasediments have intermediate Fe∶Mg ratios. The phengites show a small decrease in phengite component with increasing metamorphic grade. d ₀₀₆ for phengites varied from 3.302 to 3.323 Å but at least in the lawsonite and epidote zones appears to reflect composition and had little systematic variation with metamorphic grade; phengites from very low-grade rocks showed the longest values of d ₀₀₆. Paragonite shows almost no phengite-type substitution and only limited solid solution (4–12%) with muscovite. All paragonites (6) and most phengites (20) which have been examined are 2M₁ polymorphs; one Fe²⁺-phengite appears to be a 1M polymorph. The chemistry of chlorites closely reflects parent-rock chemistry. Chlorites from metasediments have distinctly higher Fe/(Fe+Mg) ratios than chlorites from basic igneous rocks; chlorites from the lawsonite and lawsonite-epidote transitional zone metasediments have the highest Fe/(Fe+Mg) ratios. In metabasalts Fe/(Fe+Mg) ratios appear to reflect individual variations in bulk-rock chemistry and show no direct correlation with metamorphic grade. There is little difference in Al/(Si+Al) ratio between chlorites from sediments and basic igneous rocks although in both lithologies the chlorites from the epidote zone appear to be slightly more aluminous. Fe-rich chlorites of the lawsonite zone metasediments have been altered by a process involving leaching of Fe and Mg and introduction of alkalies to a brown pleochroic Fe-vermiculite. Chemical and physical data for this vermiculite are given. The decrease in Fe/(Fe+Mg) ratio in chlorites and phengites on passing from the lawsonite to the epidote zone can be correlated with the crystallization of Fe-rich epidote and almandine in the epidote zone. Elemental partitioning between coexisting minerals has shown Ti to be partitioned into phengite, while Fe and Mn are strongly partitioned into chlorite. When either stilpnomelane or chloritoid coexists with phengite or chlorite, Fe and Mn are slightly enriched in the stilpnomelane or chloritoid relative to the chlorite.     

Diatom–environment relationships and a transfer function for conductivity in lakes of the Badain Jaran Desert, Inner Mongolia, China

We describe a dataset of 26 modern diatom samples and associated environmental variables from the Badain Jaran Desert, northwest China. The influence of electrical conductivity (EC) and other variables on diatom distribution was explored using multivariate analyses and generalized additive modeling of species response curves. A transfer function was derived for EC, the variable with the largest unique effect on diatom variance, as shown by partial canonical correspondence analysis. Weighted-averaging partial least squares regression and calibration provided the best model, with a high coefficient of determination ( $ {\text{r}}_{\text{boot}}^{2} $  = 0.91) and low prediction error (RMSEP_boot = 0.136 log₁₀ μS cm^?1). To assess its potential for palaeosalinity and palaeoclimate reconstructions, the EC transfer function was applied to fossil diatom assemblages from ²¹⁰Pb-dated short sediment cores collected from two subsaline lakes of the Badain Jaran Desert. The diatom-inferred (DI) EC reconstructions were compared with meteorological data for the past 50 years and with remote sensing data for the period AD 1990–2012. Changes in DI–EC were small and their relationship with climate was weak. Moreover, remote sensing data indicate that the surface areas and water depths of these lakes did not change, which suggests that water loss by evaporation is compensated by groundwater inflow. These results suggest that the response of these lakes to climate change is mediated by non-climatic factors such as the hydrogeological setting, which control recharge from groundwater, and may be non-linear and non-stationary.     

A high-resolution Holocene ostracod record from the Sahel zone of Northeastern Nigeria

The ostracod record from Kajemarum Oasis in the Sahel zone of Northeastern Nigeria covers the last c. 4000 cal. years of a 5500 cal. year lake-sediment sequence. The first appearance of ostracods, around 4000 cal. yr BP, reflects the switch from a very dilute lake during the mid-Holocene, to slightly oligosaline conditions that favoured the occurrence and preservation of ostracods. Between 3800 and 3100 cal. yr BP, the lake remained permanent and fresh or slightly oligosaline, with a Ca-Mg-HCO3 composition. A rise in salinity c. 3100 cal. yr BP, accompanied by a change to more variable conditions on a seasonal to interannual timescale, led to the influx of more-euryhaline taxa. Oligosaline conditions continued between 3100 and 1500 cal. yr BP. Around 1500 cal. yr BP, there was a sharp rise in salinity, probably accompanied by a shift to Na-CO3-type water, with marked seasonal and interannual variability. Salinity decreased after 900 cal. yr BP, although short-term variations were marked between 900 cal. yr BP and the top of the sequence, 95 cal. yr BP. Changes in the species assemblages and ostracod abundance were a response to climate-driven variations in the seasonal and interannual stability of the lake, together with changes in its salinity and solute composition, but there is no simple relationship between ostracod faunas and salinity. Within Kajemarum, there is no evidence of ostracod assemblages typical of deep, fresh water, nor of hypersaline Na-Cl waters. The sediments associated with the freshest waters at Kajemarum did not favour ostracod preservation, and the driest climatic conditions were associated with oligosaline to mesosaline water of Na-CO3-type. The species-poor assemblages reflect the short-term instability of the lake, coupled with the limited opportunities for the colonisation of this isolated basin.     

Seasonal and Annual Fluxes of Nutrients and Organic Matter from Large Rivers to the Arctic Ocean and Surrounding Seas

River inputs of nutrients and organic matter impact the biogeochemistry of arctic estuaries and the Arctic Ocean as a whole, yet there is considerable uncertainty about the magnitude of fluvial fluxes at the pan-Arctic scale. Samples from the six largest arctic rivers, with a combined watershed area of 11.3?×?10⁶?km², have revealed strong seasonal variations in constituent concentrations and fluxes within rivers as well as large differences among the rivers. Specifically, we investigate fluxes of dissolved organic carbon, dissolved organic nitrogen, total dissolved phosphorus, dissolved inorganic nitrogen, nitrate, and silica. This is the first time that seasonal and annual constituent fluxes have been determined using consistent sampling and analytical methods at the pan-Arctic scale and consequently provide the best available estimates for constituent flux from land to the Arctic Ocean and surrounding seas. Given the large inputs of river water to the relatively small Arctic Ocean and the dramatic impacts that climate change is having in the Arctic, it is particularly urgent that we establish the contemporary river fluxes so that we will be able to detect future changes and evaluate the impact of the changes on the biogeochemistry of the receiving coastal and ocean systems.     

Cross-shore hydrodynamics within an unsaturated surf zone

This paper concerns the hydrodynamics induced by random waves incident on a steep beach. New experimental results are presented on surface elevation and kinematic probability density functions, cross-shore variation in wave heights, the fraction of broken waves and velocity moments. The surf zone is found to be unsaturated at incident wave frequencies, with a significant proportion of the incident wave energy remaining at the shoreline in the form of bores. Wave heights in both the outer and inner surf zones are best described by a full Rayleigh distribution [Thornton, E.B., Guza, R.T., 1983. Transformation of wave height distribution. J. Geophys. Res. 88, 5925–5938], rather than a truncated Rayleigh distribution as used by Battjes and Janssen (1978) [Battjes, J.A, Janssen, J.P., 1978. Energy loss and setup due to breaking of random waves. Proc. 16th Int. Conf. Coastal Eng. ASCE, New York, pp. 569–588]. A new parametric wave transformation model is outlined which provides explicit expressions for the fraction of broken waves and the energy dissipation rate within the surf zone. On steep beaches, the model appears to offer improved predictive capabilities over the original Battjes and Janssen model. Cross-shore variations in the velocity variance and velocity moments are best described using Linear Gaussian wave theory, with less than 20% of the velocity variance in the inner surf zone due to low frequency energy.