Carbonate and silicate weathering in two presently glaciated, crystalline catchments in the Swiss Alps

We present a weathering mass balance of the presently glaciated Rhône and Oberaar catchments, located within the crystalline Aar massif (central Switzerland). Annual chemical and physical weathering fluxes are calculated from the monthly weighted means of meltwater samples taken from July, 1999 to May, 2001 and are corrected for precipitation inputs. The meltwater composition issuing from the Oberaar and Rhône catchments is dominated by calcium, which represents 81% and 55% of the total cation flux respectively (i.e. 555 and 82-96 keq km⁻² yr⁻¹). The six to seven times higher Ca²⁺ denudation flux from the Oberaar catchment is attributed to the presence of a strongly foliated gneissic zone. The gneissic zone has an elevated calcite content (as reflected by the 4.6 times higher calcite content of the suspended sediments from Oberaar compared to Rhône) and a higher mechanical erosion rate (resulting in a higher flux of suspended sediment). The mean flux of suspended calcite of the Oberaar meltwaters during the ablation period is 7 times greater than that of the Rhône meltwaters. Taking the suspended calcite as a proxy for the total (including sub-glacial sediments) weathering calcite surface area, it appears that the available surface area is an important factor in controlling weathering rates. However, we also observe an increased supply of protons for carbonate dissolution in the Oberaar catchment, where the sulphate denudation flux is six times greater. Carbonic acid is the second important source of protons, and we calculate that three times as much atmospheric CO₂ is drawn down (short term) in the Oberaar catchment. Silica fluxes from the two catchments are comparable with each other, but are 100 kmol km² yr⁻¹ lower than fluxes from physically comparable, non-glaciated basins.     

Geochemistry of Peruvian near-surface sediments

Sixteen short sediment cores were recovered from the upper edge (UEO), within (WO) and below (BO) the oxygen minimum zone (OMZ) off Peru during cruise 147 of R/V Sonne. Solids were analyzed for major/trace elements, total organic carbon, total inorganic carbon, total sulfur, the stable sulfur isotope composition (δ³⁴S) of pyrite, and sulfate reduction rates (SRR). Pore waters were analyzed for dissolved sulfate/sulfide and δ³⁴S of sulfate. In all cores highest SRR were observed in the top 5 cm where pore water sulfate concentrations varied little due to resupply of sulfate by sulfide oxidation and/or diffusion of sulfate from bottom water. δ³⁴S of dissolved sulfate showed only minor downcore increases. Strong ³²S enrichments in sedimentary pyrite (to −48‰ vs. V-CDT) are due to processes in the oxidative part of the sulfur cycle in addition to sulfate reduction. Manganese and Co are significantly depleted in Peruvian upwelling sediments most likely due to mobilization from particles settling through the OMZ, whereas release of both elements from reducing sediments only seems to occur in near-coastal sites. Cadmium, Mo and Re are exceptionally enriched in WO sediments (<600 m water depth). High Re and moderate Cd and Mo enrichments are seen in BO sediments (>600 m water depth). Re/Mo ratios indicate anoxic and suboxic conditions for WO and BO sediments, respectively. Cadmium and Mo downcore profiles suggest considerable contribution to UEO/WO sediments by a biodetrital phase, whereas Re presumably accumulates via diffusion across the sediment-water interface to precipitation depth. Uranium is distinctly enriched in WO sediments (due to sulfidic conditions) and in some BO sediments (due to phosphorites). Silver transfer to suboxic BO sediments is likely governed by diatomaceous matter input, whereas in anoxic WO sediments Ag is presumably trapped due to sulfide precipitation. Cadmium, Cu, Zn, Ni, Cr, Ag, and T1 predominantly accumulate via biogenic pre-concentration in plankton remains. Rhenium, Sb, As, V, U and Mo are enriched in accordance with seawater TE availability. Lead and Bi enrichment in UEO surface sediments is likely contributed by anthropogenic activity (mining). Accumulation rates of TOC, Cd, Mo, U, and V from Peruvian and Namibian sediments exceed those from the Oman Margin and Gulf of California due to enhanced preservation off Peru and Namibia.     

Earthquakes in Switzerland and surrounding regions during 2015 and 2016

This report summarizes the seismicity in Switzerland and surrounding regions in the years 2015 and 2016. In 2015, the Swiss Seismological Service detected and located 735 earthquakes in the region under consideration. With a total of 20 earthquakes of magnitude M_L ≥ 2.5, the seismic activity of potentially felt events in 2015 was close to the average of 23 earthquakes over the previous 40 years. Seismic activity was above average in 2016 with 872 located earthquakes of which 31 events had M_L ≥ 2.5. The strongest event in the analyzed period was the M_L 4.1 Salgesch earthquake, which occurred northeast of Sierre (VS) in October 2016. The event was felt in large parts of Switzerland and had a maximum intensity of V. Derived focal mechanisms and relative hypocenter relocations of aftershocks image a SSE dipping reverse fault, which likely also hosted an M_L 3.9 earthquake in 2003. Another remarkable earthquake sequence in the Valais occurred close to Sion with four felt events (M_L 2.7–3.2) in 2015/16. We associate this sequence with a system of WNW-ESE striking fault segments north of the Rhône valley. Similarities with a sequence in 2011, which was located about 10 km to the NE, suggest the existence of an en-echelon system of basement faults accommodating dextral slip along the Rhône-Simplon line in this area. Another exceptional earthquake sequence occurred close to Singen (Germany) in November 2016. Relocated hypocenters and focal mechanisms image a SW dipping transtensional fault segment, which is likely associated with a branch of the Hegau-Bodensee Graben. On the western boundary of this graben, micro-earthquakes close to Schlattingen (TG) in 2015/16 are possibly related to a NE dipping branch of the Neuhausen Fault. Other cases of earthquakes felt by the public during 2015/16 include earthquakes in the region of Biel, Vallorcine, Solothurn, and Savognin.     

Sedimentology of a Late Quaternary lacustrine record from the south-eastern Carpathian Basin

The Upper Pleistocene geoarchives in the south-eastern Carpathian Basin are represented predominantly by loess–palaeosol records. In 2015, a 10 m sediment core composed of clay-rich lacustrine sediments was recovered by vibracoring a dry lake basin located between the Vršac Mountains (Serbia) and the Banat Sands in the south-eastern Carpathian Basin; a location relevant for placing regional archaeological results in a palaeoenvironmental context. Here, we present results from geoelectrical prospection and a lithostratigraphic interpretation of this sequence supported by a detailed granulometric study supplemented by ostracod analysis. An age model based on luminescence dating is discussed against sedimentological proxy data and its implication for palaeoenvironmental change. The cores show a stratigraphy of lighter ochre-coloured and darker greyish sediment, related to the deposition of clay and silt trapped in an aquatic environment. Geophysical measurements show ~20 m thick lacustrine sediments. The grain-size distributions including the variability in fine clay are indicative of a lacustrine environment. Fine particles were brought into the depositional environments by aquatic input and settled from suspension; also, direct dust input is constrained by grain-size results. Riverine input and aeolian dust input interplayed at the locality.     

Tonian to early Cryogenian synorogenic basin of the São Gabriel Terrane,Dom Feliciano Belt,southernmost Brazil

A provenance and stratigraphic study of the Neoproterozoic Pontas do Salso Complex (PSC), western portion of the Dom Feliciano Belt (DFB), was conducted with U–Pb zircon geochronological analysis of the metasediments and the host rocks. The U–Pb isotopic data from detrital zircon of the metasediments indicate the source from the latest Middle Tonian to Late Cryogenian (between 897 and 684 Ma) and maximum depositional age of 685 ± 18 Ma in an arc-related basin setting adjacent in the Sao Gabriel Arc. The metasediments of the PSC form an elongated body in the N35°E direction and occur in the central portion of the São Gabriel Terrane (SGT), which is constituted by ophiolitic complexes and arc-related rocks, generated probably during the final consolidation of Rodinia supercontinent, although this question is still open. Low- to medium-K calc-alkaline, metaluminous affinity, and trace-element geochemistry suggest that the chemical composition of the protoliths was generated from metasomatized mantle sources in subduction zones. The PSC is composed of meta-arkoses, with subordinate metaconglomerates and metapelites. The meta-arkoses are disposed in plane-parallel layers, which also internally feature small-scale cross-bedding structures. The matrix has a blastopsammitic, poorly selected, fine to coarse texture, and hexagonal quartz and plagioclase porphyroclasts with superimposed thermal metamorphism. The polymict metaconglomerates are matrix-supported, with 15–55% of clasts of metavolcanic rocks, metasediments, undeformed granites, and quartz veins. The metapelites comprise mainly muscovite phyllites with syn-tectonic garnet and chloritoid porphyroblasts. The PSC represents a sedimentary succession deposited on an arc-related basin formed during the collapse and uplift of the SGT.     

Atom probe tomography of space‐weathered lunar ilmenite grain surfaces

The surfaces of airless bodies, such as the Moon and asteroids, are subject to space weathering, which alters the mineralogy of the upper tens of nanometers of grain surfaces. Atom probe tomography (APT) has the appropriate 3‐D spatial resolution and analytical sensitivity to investigate such features at the nanometer scale. Here, we demonstrate that APT can be successfully used to characterize the composition and texture of space weathering products in ilmenite from Apollo 17 sample 71501 at near‐atomic resolution. Two of the studied nanotips sampled the top surface of the space‐weathered grain, while another nanotip sampled the ilmenite at about 50 nm below the surface. These nanotips contain small nanophase Fe particles (~3 to 10 nm diameter), with these particles becoming less frequent with depth. One of the nanotips contains a sequence of space weathering products, compositional zoning, and a void space (~15 nm in diameter) which we interpret as a vesicle generated by solar wind irradiation. No noble gases were detected in this vesicle, although there is evidence for ⁴He elsewhere in the nanotip. This lunar soil grain exhibits the same space weathering features that have been well documented in transmission electron microscope studies of lunar and Itokawa asteroidal regolith grains.     

Geochemical evidence for the nature of the crust beneath the eastern North Penninic basin of the Mesozoic Tethys ocean

The North Penninic basin was a subbasin in the northern part of the Mesozoic Tethys ocean. Its significance within the framework of this ocean is controversial because it is not clear whether it was underlain by thinned continental or oceanic crust. Remnants of the eastern North Penninic basin are preserved in the Alps of eastern Switzerland (Grisons) as low metamorphic "Bündnerschiefer" sediments and associated basaltic rocks which formed approximately 140–170 Ma ago (Misox Bündnerschiefer zone, Middle Jurassic to Early Cretaceous). Nb/U, Zr/Nb, and Y/Nb ratios, as well as Nd–Sr isotopic and REE data of most of the metabasalts point to a depleted MORB-type mantle origin. They have been contaminated by magmatic assimilation of Bündnerschiefer sediments and by exchange with seawater, but do not prove the existence of a subcontinental lithospheric mantle or continental crust beneath the North Penninic basin. This suggests that the studied part of the North Penninic realm was underlain by oceanic crust. Only the metabasalts from two melange zones (Vals and Grava melanges) show a more important contamination by crustal material. Since this type of contamination cannot be observed in the other tectonic units, we suggest that its occurrence is related to melange formation during the subduction of the North Penninic basin in the Tertiary. The North Penninic basin was probably, despite the occurrence of oceanic crust, smaller than the South Penninic ocean where the presence of oceanic crust is well established. Modern analogues for the North Penninic basin could be the transitional zone of the Red Sea or the pull-apart basins of the southernmost Gulf of California where local patches of oceanic crust with effusive volcanism have been described.