Shock‐induced changes in density and porosity in shock‐metamorphosed crystalline rocks,Haughton impact structure,Canada

Abstract– Shock metamorphism can occur at transient pressures that reach tens of GPa and well over 1000 °C, altering the target material on both megascopic and microscopic scales. This study explores the effects of shock metamorphism on crystalline, quartzofeldspathic basement material from the Haughton impact structure on Devon Island, Arctic Canada. Shock levels were assigned to samples based on petrographic examination of main mineral phases. Conventional shock classification schemes proved to incompletely describe the Haughton samples so a modified shock classification system is presented. Fifty‐two crystalline bedrock samples from the clast‐rich impact melt rocks in the crater, and one reference site outside of the crater, were classified using this system. The shock levels range from 0 to 7 (according to the new shock stage classification proposed here, i.e., stages 0–IV after the Stöffler classification), indicating shock pressures ranging from 0 to approximately 80 GPa. The second aspect of this study involved measuring bulk physical characteristics of the shocked samples. The bulk density, grain density, and porosity were determined using a water displacement method, a bead displacement method, and a Hepycnometer. Results suggest a nonlinear, negative correlation between density and shock level such that densities of crystalline rocks with original densities of approximately 3 g cm^?3 are reduced to <1.0 g cm^?3 at high shock levels. The results also show a positive nonlinear correlation between porosity and shock level. These data illustrate the effect of shock on the bulk physical characteristics of crystalline rocks, and has implications for assessing the habitability of shocked rocks.     

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.     

Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity

Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations.     

Mapping block-and-ash flow hazards based on Titan 2D simulations: a case study from Mt. Taranaki,NZ

Numerical models for simulation of mass flows are typically focussed upon accurately predicting the paths, travel times and inundation from a single flow or collapse event. When considering catchment-based hazards from a volcano, this is complicated by often being faced with several possible scenarios. Over the last 800 years at Mt. Taranaki/Egmont, a number of dome growth and collapse events have resulted in the genesis and emplacement of block-and-ash flows (BAFs). Each BAF was directed northwestward by a breach in the crater rim. The latest dome collapse events in the AD 1880s and AD 1755 inundated the northwestern flank and had run-out lengths 10 km from source. Future activity of this type could have a devastating effect on the Taranaki region’s communities, infrastructure and economy. Hazard planning has involved constructing volcanic hazard maps based upon the areas inundated by past volcanic flows, with little consideration of present-day topography. Here, a numerical geophysical mass flow modelling approach is used to forecast the hazards of future comparable BAF events on NW Mt. Taranaki. The Titan2D programme encompasses a “shallow water”, continuum solution-based, granular flow model. Flow mechanical properties needed for this approach include estimates of internal and basal friction as well as the physical dimensions of the initial collapse. Before this model can be applied to Taranaki BAFs, the input parameters must be calibrated by simulating a range of past collapse events. By using AD 1860 and AD 1755 scenarios, initial collapse volumes can be well constrained and internal and basal friction angles can be evaluated through an iterative approach from previous run-out lengths. A range of possible input parameters was, therefore, determined to produce a suite of potentially inundated areas under present-day terrain. A suite of 10 forecasts from a uniformly distributed range were combined to create a map of relative probabilities of inundation by future BAF events. These results were combined in a GIS package to produce hazard zones related to user-specified hazard thresholds. Using these input parameter constraints, future hazard forecasts for this scale and type of event can also take into account changing summit and topographic configurations following future eruptive or collapse events.     

Study of mango biomass (Mangifera indica L) as a cationic biosorbent

Unfertilizable fruiting buds of mango plant Mangifera Indica L, an agrowaste, is used as a biomass in this study. The efficacy of the biosorbent was tested for the removal of lead, copper, zinc and nickel metal ions using batch experiments in single and binary metal solution under controlled experimental conditions. It is found that metal sorption increases when the equilibrium metal concentration rises. At highest experimental solution concentration used (150 mg/L), the removal of metal ions were 82.76 % for lead, 76.60 % for copper, 63.35 % for zinc and 59.35 % for nickel while at lowest experimental solution concentration (25 mg/L), the removal of metal ions were 92.00% for lead, 86.84 % for copper, 83.96 % for zinc and 82.29 % for nickel. Biosorption equilibrium isotherms were plotted for metal uptake capacity (q) against residual metal concentrations (C_f) in solution. The q versus C_f sorption isotherm relationship was mathematically expressed by Langmuir and Freundlich models. The values of separation factor were between zero and one indicating favourable sorption for four tested metals on the biosorbent. The surface coverage values were approaching unity with increasing solution concentration indicating effectiveness of biosorbent under investigation. The non-living biomass of Mangifera indica L present comparable biosorption capacity for lead, copper, zinc and nickel metal ions with other types of biosorbent materials found in literature and is effective to remove metal ions from single metal solutions as well as in the presence of other co-ions with the main metal of solution.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.     

Fabric analysis of Allende matrix using EBSD

Abstract— Fabric analysis of the interstitial matrix material in primitive meteorites offers a novel window on asteroid formation and evolution. Electron backscatter diffraction (EBSD) has allowed fabrics in these fine‐grained materials to be visualized in detail for the first time. Our data reveal that Allende, a CV3 chondrite, possesses a uniform, planar, short‐axis alignment fabric that is pervasive on a broad scale and is probably the result of deformational shortening related to impact or gravitational compaction. Interference between this matrix fabric and the larger, more rigid components, such as dark inclusions (DIs) and calcium‐aluminium‐rich inclusions (CAIs), has lead to the development of locally oriented and intensified matrix fabrics. In addition, DIs possess fabrics that are conformable with the broader matrix fabric. These results suggest that DIs were in situ prior to the deformational shortening event responsible for these fabrics, thus providing an argument against dark inclusions being fragments from another lithified part of the asteroid (Kojima and Tomeoka 1996; Fruland et al. 1978). Moreover, both DIs and Allende matrix are highly porous (?25%) (Corrigan et al. 1997). Mobilizing a highly porous DI during impact‐induced brecciation without imposing a fabric and incorporating it into a highly porous matrix without significantly compacting these materials is improbable. We favor a model that involves Allende DIs, CAIs, and matrix accreting together and experiencing the same deformation events.