Paleolimnology of McNearney lake: an acidic lake in northern Michigan

McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L^-1) and high SO _inf4 ^sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO _inf4 ^sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical     

Red-light districts and Toleration Zones: geographies of female street prostitution in England and Wales

Summary Although female street prostitution is widely acknowledged to occur in specific spaces, characteristically referred to as 'red-light' districts, geographers have been remarkably reticent in examining the nature and location of these spaces. Against a backdrop of mounting debate surrounding the legal status of prostitution in England and Wales, this paper considers the importance of such areas in the regulation and containment of street prostitution, and speculates as to how changing social and legal attitudes might result in very different geographies of prostitution.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.     

Formal definition and dating of the GSSP (Global Stratotype Section and Point) for the base of the Holocene using the Greenland NGRIP ice core,and selected auxiliary records

The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in δ¹⁸O, dust concentration, a range of chemical species, and annual layer thickness. A timescale based on multi‐parameter annual layer counting provides an age of 11 700 calendar yr b2 k (before AD 2000) for the base of the Holocene, with a maximum counting error of 99 yr. A proposal that an archived core from this unique sequence should constitute the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period) has been ratified by the International Union of Geological Sciences. Five auxiliary stratotypes for the Pleistocene–Holocene boundary have also been recognised. Copyright © 2008 John Wiley & Sons, Ltd.     

Doppler Lidar Measurements of Vertical Velocity Spectra in the Convective Planetary Boundary Layer

We utilized a Doppler lidar to measure spectra of vertical velocity w from 390m above the surface to the top of the daytime convective boundary layer (CBL). The high resolution 2μm wavelength Doppler lidar developed by the NOAA Environmental Technology Laboratory was used to detect the mean radial velocity of aerosol particles. It operated continuously during the daytime in the zenith-pointing mode for several days in summer 1996 during the Lidars-in-Flat-Terrain experiment over level farmland in central Illinois, U.S.A. The temporal resolution of the lidar was about 1 s, and the range-gate resolution was about 30m. The vertical cross-sections were used to calculate spectra as a function of height with unprecedented vertical resolution throughout much of the CBL, and, in general, we find continuity of the spectral peaks throughout the depth of the CBL. We compare the observed spectra with previous formulations based on both measurements and numerical simulations, and discuss the considerable differences, both on an averaged and a case-by-case basis. We fit the observed spectra to a model that takes into account the wavelength of the spectral peak and the curvature of the spectra across the transition from low wavenumbers to the inertial subrange. The curvature generally is as large or larger than the von Kármán spectra. There is large case-to-case variability, some of which can be linked to the mean structure of the CBL, especially the mean wind and the convective instability. We also find a large case-to-case variability in our estimates of normalized turbulent kinetic energy dissipation deduced from the spectra, likely due for the most part to a varying ratio of entrainment flux to surface flux. Finally, we find a relatively larger contribution to the low wavenumber region of the spectra in cases with smaller shear across the capping inversion, and suggest that this may be due partly to gravity waves in the inversion and overlying free atmosphere.     

Engineering characterisation of Norwegian glaciomarine silt

Guidance is provided for geotechnical engineers designing civil engineering works in silty soils based on a detailed characterisation of a glaciomarine silt from Os in western Norway. It was found that these soils are susceptible to disturbance by good quality fixed piston tube sampling and care needs to be taken when using laboratory derived design parameters, particularly for consolidation and shear strength properties. A technique for assessing sample disturbance using shear wave velocity and suction measurements proved promising. Conventional techniques for determining soil strength from triaxial tests in silt are inappropriate due to the dilational nature of the material and more reliable and logical strength estimates can be made from a limiting strain criterion. Field vane data should be used with caution as measured strength, particularly remoulded values, may be high and it seems more reliable parameters can be derived from CPTU tests. One dimensional consolidation and creep of these silts can be modelled successfully by the well-known Janbu formulation. The behaviour of the Os silts does not fit easily into classical soil mechanics and published frameworks for soft soils. It seems the material is of “transitional” type and this work adds to the database of such soils which includes other natural silts and gap graded soils. For future work it is recommended that larger sample tubes (say 75 mm) with a very sharp cutting edge should be used in parallel with in situ CPTU testing.     

Insights into silicic melt generation using plagioclase, quartz and melt inclusions from the caldera-forming Rotoiti eruption, Taupo volcanic zone, New Zealand

The Rotoiti (~120 km³) and Earthquake Flat (~10 km³) eruptions occurred in close succession from the Okataina Volcanic Centre at ~50 ka. While accessory mineral geochronology points to long periods of crystallization prior to eruption (10⁴–10⁵ years) and separate thermal histories for the magmas, little was known about the rates and processes of the final melt production and eruption. Crystal zoning patterns in plagioclase and quartz reveal the thermal and compositional history of the magmatic system leading up to the eruption. The dominant modal phase, plagioclase, displays considerable within-crystal zonation: An_37–74, ~40–227 ppm MgO, 45–227 ppm TiO₂, 416–910 ppm Sr and 168–1164 ppm Ba. Resorption horizons in the crystals are marked by sharp increases (10–30%) in Sr, MgO and X_An that reflect changes in melt composition and are consistent with open system processes. Melt inclusions display further evidence for open system behaviour, some are depleted in Sr and Ba relative to accompanying matrix glass not consistent with crystallization of modal assemblage. MI also display a wide range in XH₂O that is consistent with volatile fluxing. Quartz CL images reveal zoning that is truncated by resorption, and accompanied by abrupt increases in Ti concentration (30–80 ppm) that reflect temperature increases ~50–110°C. Diffusion across these resorption horizons is restricted to zones of <20 μm, suggesting most crystallization within the magma occurred in <2000 years. These episodes are brief compared to the longevity (10⁴–10⁵ year) of the crystal mush zones. All textural and compositional features observed within the quartz and plagioclase crystals are best explained by periodic mafic intrusions repeatedly melting parts of a crystal-rich zone and recharging the system with silicic melt. These periodic influxes of silicic melt would have accumulated to form the large volume of magma that fed the caldera-forming Rotoiti eruption.