Die fazielle und paläogeographische Entwicklung der infrakambrischen bis ordovizischen Sedimente im Mittleren Antiatlas um Agdz (S-Marokko)

Zusammenfassung Die Entwicklung des Adoudounien (Infrakambrium) und Géorgien (Unterkambrium) ist im Mittleren Antiatlas durch einen Wechsel von marinen und kontinentalen Sedimenten gekennzeichnet. Wildbachablagerungen an der Basis und an den Beckenrändern werden von marin-marginalen stromatolithischen Karbonaten abgelöst. Ignimbrite belegen wiederholte terrestrische Sedimentation.Mit fluviatilen Sanden und wiederum Stromatolithen und lagunären Karbonaten (mit ersten Trilobiten!) setzt ein zweiter transgressiver Großzyklus ein, der an der Wende Infra-/Unter-Kambrium einen ersten Höhepunkt erreicht. Durch regressive Kleinzyklen charakterisierte Abfolgen leiten zu Sandsteinen über, die als Ablagerungen eines Deltas gedeutet werden.Vom Mittelkambrium bis Ordovizium dominiert marine Schelfsedimentation.

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The formations of Adoudounien (Infra Cambrian) and Géorgien (Lower Cambrian) of the middle Anti-Atlas are characterized by an alternation of marine and continental sediments. Torrent conglomerates at the base and the margins of the basin took turns to marine-marginal stromatolitic carbonates. Ignimbrites prove repeated terrestrial sedimentation.A second transgressiv megasequence begins with fluviatil sands and goes on with stromatolites and lagoon carbonates (first Trilobites). This transgression reachs his first culmination at the Infra-/Lower-Cambrian boundary. Typical regressiv cycles form a transition to sandstones, which are interpreted as sediments of a delta.Marine shelf environment dominates from Middle Cambrian to Ordovician beds.

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Résumé Dans le moyen Anti-Atlas, l'évolution de l'Adoudounien et du Géorgien est caractérisée par un changement des sédiments marins et continentaux. Les dépôts des torrents à la base et dans la bordure du bassin font place à des carbonates marins marginaux stromatolithiques. Les ignimbrites marquent le retour fréquent à la sédimentation terrestre.Une deuxième mégaséquence transgressive débute avec des sables fluviatiles, des stromatolithes et des carbonates lagunaires (premiers trilobites). La transgression atteint une première phase culminante à la transition de l'Adoudounien au Géorgien. Des séquences caractérisées par de petits cycles régressifs conduisent à des grès qui pourraient être interpré tés comme des sédiments deltaïques.A partir du Cambrien moyen jusqu'à l'Ordovicien prédomine un milieu de plate-forme externe.

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Adoudounien — — Géorgien — — . — — . , - , , . , , . .

     

Rapid change in early Holocene environments inferred from Lake Pupuke,Auckland City,New Zealand

Sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high‐resolution millennial to centennial‐scale record of changing climate and catchment hydrology spanning the past ca. 10 000 years. Here, we focus on the period between 9500 ± 25 and 7000 ± 155 cal. yr BP during which grain size, diatom palaeoecology, biogenic silica concentrations, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions, with a significant event commencing at ca. 8240 cal. yr BP, commensurate with a lowering of lake level, faster erosion rates and increased sediment influx with a duration of ca. 360 yrs. However, the changes in the lake are not reflected in the terrestrial vegetation, where the pollen record indicates that podocarp forest dominated the Auckland region, with apparent environmental stability during this part of the early Holocene. The synchronous change in most of the proxies between ca. 8240 and 7880 cal. yr BP at Lake Pupuke indicates the presence of a sustained episode of relatively low lake level and concomitant increased rate of erosion in the early Holocene that appears to be at least partly coeval with the 8200 cal. yr BP meltwater event proposed for the North Atlantic region. Copyright © 2008 John Wiley & Sons, Ltd.     

A Multiple Flare Scenario where the Classic Long-Duration Flare Was Not the Source of a CME

A series of flares (GOES class M, M and C) and a CME were observed in close succession on 20 January 2004 in NOAA 10540. Radio observations, which took the form of types II, III and N bursts, were associated with these events. We use the combined observations from TRACE, EIT, Hα images from Kwasan, MDI magnetograms and GOES to understand the complex development of this event. Contrary to a standard interpretation, we conclude that the first two impulsive flares are part of the CME launch process while the following long-duration event flare represents simply the recovery phase. Observations show that the flare ribbons not only separate but also shift along the magnetic inversion line so that magnetic reconnection progresses stepwise to neighboring flux tubes. We conclude that “tether cutting” reconnection in the sheared arcade progressively transforms it to a twisted flux tube, which becomes unstable, leading to a CME. We interpret the third flare, a long-duration event, as a combination of the classical two-ribbon flare with the relaxation process following forced reconnection between the expanding CME structure and neighboring magnetic fields. Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.     

Shock‐induced changes in density and porosity in shock‐metamorphosed crystalline rocks,Haughton impact structure,Canada

Abstract– Shock metamorphism can occur at transient pressures that reach tens of GPa and well over 1000 °C, altering the target material on both megascopic and microscopic scales. This study explores the effects of shock metamorphism on crystalline, quartzofeldspathic basement material from the Haughton impact structure on Devon Island, Arctic Canada. Shock levels were assigned to samples based on petrographic examination of main mineral phases. Conventional shock classification schemes proved to incompletely describe the Haughton samples so a modified shock classification system is presented. Fifty‐two crystalline bedrock samples from the clast‐rich impact melt rocks in the crater, and one reference site outside of the crater, were classified using this system. The shock levels range from 0 to 7 (according to the new shock stage classification proposed here, i.e., stages 0–IV after the Stöffler classification), indicating shock pressures ranging from 0 to approximately 80 GPa. The second aspect of this study involved measuring bulk physical characteristics of the shocked samples. The bulk density, grain density, and porosity were determined using a water displacement method, a bead displacement method, and a Hepycnometer. Results suggest a nonlinear, negative correlation between density and shock level such that densities of crystalline rocks with original densities of approximately 3 g cm^?3 are reduced to <1.0 g cm^?3 at high shock levels. The results also show a positive nonlinear correlation between porosity and shock level. These data illustrate the effect of shock on the bulk physical characteristics of crystalline rocks, and has implications for assessing the habitability of shocked rocks.     

Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity

Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations.     

Study of mango biomass (Mangifera indica L) as a cationic biosorbent

Unfertilizable fruiting buds of mango plant Mangifera Indica L, an agrowaste, is used as a biomass in this study. The efficacy of the biosorbent was tested for the removal of lead, copper, zinc and nickel metal ions using batch experiments in single and binary metal solution under controlled experimental conditions. It is found that metal sorption increases when the equilibrium metal concentration rises. At highest experimental solution concentration used (150 mg/L), the removal of metal ions were 82.76 % for lead, 76.60 % for copper, 63.35 % for zinc and 59.35 % for nickel while at lowest experimental solution concentration (25 mg/L), the removal of metal ions were 92.00% for lead, 86.84 % for copper, 83.96 % for zinc and 82.29 % for nickel. Biosorption equilibrium isotherms were plotted for metal uptake capacity (q) against residual metal concentrations (C_f) in solution. The q versus C_f sorption isotherm relationship was mathematically expressed by Langmuir and Freundlich models. The values of separation factor were between zero and one indicating favourable sorption for four tested metals on the biosorbent. The surface coverage values were approaching unity with increasing solution concentration indicating effectiveness of biosorbent under investigation. The non-living biomass of Mangifera indica L present comparable biosorption capacity for lead, copper, zinc and nickel metal ions with other types of biosorbent materials found in literature and is effective to remove metal ions from single metal solutions as well as in the presence of other co-ions with the main metal of solution.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.