Palaeo-hydrogeological control on groundwater As levels in Red River delta,Vietnam

To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe²⁺, H₂S, NH₄, CH₄, δ¹⁸O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ¹⁸O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe²⁺ (0.03–2.0 mM), Mn (0.7–320 μM), SO₄ (<2.1 μM–0.75 mM), H₂S (<0.1–7.0 μM), NH₄ (0.03–4.4 mM), and CH₄ (0.08–14.5 mM). Generally, higher concentrations of NH₄ and CH₄ and low concentrations of SO₄ were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH₄, CH₄ and SO₄. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe²⁺ and H₂S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO₄ was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration.     

Verification of a VOF-based two-phase flow model for wave breaking and wave–structure interactions

The objective of the present study is to develop a volume of fluid (VOF)-based two-phase flow model and to discuss the applicability of the model to the simulation of wave–structure interactions. First, an overview of the development of VOF-type models for applications in the field of coastal engineering is presented. The numerical VOF-based two-phase flow model has been developed and applied to the simulations of wave interactions with a submerged breakwater as well as of wave breaking on a slope. Numerical results are then compared with laboratory experimental data in order to verify the applicability of the numerical model to the simulations of complex interactions of waves and permeable coastal structures, including the effects of wave breaking. It is concluded that the two-phase flow model with the aid of the advanced VOF technique can provide with acceptably accurate numerical results on the route to practical purposes.     

GSTA is a major glutathione S-transferase gene responsible for 4-hydroxynonenal conjugation in largemouth bass liver

We have previously shown that largemouth bass (Micropterus salmoides) has a remarkable ability to conjugate 4-hydroxy-2-nonenal (4HNE), a mutagenic and cytotoxic alpha,beta-unsaturated aldehyde produced during the peroxidation of lipids. In addition, we have isolated a glutathione S-transferase cDNA (bass GSTA) that encodes a recombinant protein which is highly active in 4HNE conjugation and structurally similar to plaice (Pleuronectes platessa) GSTA. In the present study, HPLC-GST subunit analysis revealed the presence of at least two major GST isoforms in bass liver, with one peak constituting 80% of the total bass liver GST protein. Liquid chromatography mass spectrometry (LC-MS) and electrospray ionization analysis of the major bass GST subunit yielded a molecular weight of 26,396 kDa. Endo-proteinase Lys-C digestion and Edman degradation protein sequencing of this GST peak demonstrated that this protein was encoded by bass GSTA. Analysis of genomic DNA fragments isolated by nested PCR indicated the presence of a GST gene cluster in bass liver that contained GSTA, and was similar to a GST gene cluster characterized by Leaver et al., in plaice. Collectively, our data indicates the presence of a major GST in bass liver involved in the protection against oxidative stress. This GST is part of a gene cluster that may be conserved in certain freshwater and marine fish.     

Hydrological alterations from water infrastructure development in the Mekong floodplains

The Mekong floodplains, which encompasses the region from Kratie Township in Central Cambodia to the Vietnamese East Sea, is a region of globally renown agricultural productivity and biodiversity. The construction of 135 dams across the Mekong basin and the development of delta‐based flood prevention systems have caused public concern given possible threats on the stability of agricultural and ecological systems in the floodplains. Mekong dams store water upstream and regulate flow seasonality, while in situ flood prevention systems re‐distribute water retention capacity in the floodplains. The main aim of this paper is to evaluate possible impacts of the recent development of both hydropower dams and flood prevention systems on hydrological regimes in the Mekong floodplains. An analysis of measured daily and hourly water level data for key stations in the Mekong floodplains from Kratie to the river mouth in Vietnam was conducted. Hydropower dam information was obtained from the hydropower database managed by the Mekong River Commission, and the MODIS satellite imagery was used to detect changes in flooding extent related to the operation of flood prevention systems in the Vietnam Mekong Delta. Results indicate that the upper part of the floodplains, the Cambodian floodplains, may buffer upstream dam impacts to the Vietnam Mekong Delta. Flood prevention up to date has had the greatest effect on the natural hydrological regime of the Mekong floodplains, evidenced by a significant increase of water level rise and fall rates in the upper delta and causing water levels in the middle delta to increase. The development of flood prevention systems has also effected spatial distribution of flooding as indicated via a time series analysis of satellite imagery. While this development leads to increase localized agricultural productivity, our historical data analysis indicates that development of one region detrimentally affects other regions within the delta, which could increase the risk of future conflicts among regions, economic sectors and the ecological value of these important floodplains. Copyright © 2016 John Wiley & Sons, Ltd.     

热带地区碳酸盐岩上覆红色风化壳的成因机理及元素演化

开展热带岩溶地区红色风化壳元素地球化学演化规律研究,有助于丰富碳酸盐岩风化成土理论的认识。在越南北部选取典型的碳酸盐岩风化剖面,分析热带气候条件下碳酸盐岩上覆红色风化壳中主量元素的物质来源和演化特征。结果表明:无论Ti/Zr的元素比值分析,Hf-Zr、Nb-Ta及Sm-Nd的元素对协变分析,还是上地壳元素平均值(UCC)标准化分析,两个剖面的上覆风化壳均显示原地残积的特征,即两个剖面是碳酸盐岩的原位风化产物。碳酸盐岩风化成土过程中,CaO、MgO淋失明显,Al_2O_3和Fe_2O_3发生富集,显示两个剖面均经历较强的风化过程,但是白云岩和灰岩剖面有一定的分异特征。越南北部白云岩风化剖面从基岩到上部土层显示出稳定的Ti-Fe元素共富集特征,而灰岩剖面中Fe的增长速率明显超过Ti。白云岩上覆风化壳经历了强烈的风化作用,其脱硅作用弱于灰岩风化剖面,而富集铝的作用强于灰岩。迁移系数的演化规律说明两个剖面中长石成分(钾长石、钠长石等)或次生矿物(伊利石等)在风化成土过程中逐渐分解,同时Al、Fe、Si等稳定元素的在风化剖面中不断富集。     

Onset of the summer monsoon over the southern Vietnam and its predictability

The summer monsoon onset over southern Vietnam is determined through a new criterion based on both in situ daily rainfall at six selected stations provided by the Institute of Meteorology and Hydrology, Vietnam, and the zonal component of the wind at 1,000 hPa from the National Center for Environmental Prediction/Department of Energy Reanalysis 2. Over the period 1979–2004, the summer monsoon onset mean date is on 12 May, with a standard deviation of 11.6 days. The temporal and spatial structures of the atmospheric conditions prevailing during the onset period are detailed. Clear changes are seen in the zonal wind (strengthened over the Bay of Bengal and changed from negative to positive over South Vietnam) and in convection (deeper), in association with an intensification of the meridional gradients of sea level pressure at 1,000 hPa and of moist static energy at 2 m over Southeast Asia. The predictability of onset dates is then assessed. Cross-validated hindcasts based upon four predictors linked to robust signals in the atmospheric dynamics are then provided. They are highly significant when compared to observations (56% of common variance). Basically, late (early) onsets are preceded in March–April by higher (lower) sea level pressure over the East China Sea, stronger (weaker) southeasterly winds over southern Vietnam, decreasing (increasing) deep convection over the Bay of Bengal, and the reverse situation over Indonesia (120–140°E, 0–10°S).     

Velocity and attenuation in partially saturated rocks: poroelastic numerical experiments

We use a poroelastic modelling algorithm to compute numerical experiments on wave propagation in a rock sample with partial saturation using realistic fluid distribution patterns from tomography scans. Frequencies are in the range 10 to 500 kHz. The rock is a homogeneous isotropic sandstone partially filled with gas and water, which are defined by their characteristic values of viscosity, compressibility and density. We assume no mixing and that the two different pore-fills occupy different macroscopic regions. The von Kármán self-similar correlation function is used, employing different fractal parameters to model uniform and patchy fluid distributions, respectively, where effective saturation is varied in steps from full gas to full water saturation. Without resorting to additional matrix–fluid interaction mechanisms, we are able to reproduce the main features of the variation in wave velocity and attenuation with effective saturation and frequency, as those of published laboratory experiments. Furthermore, the behaviour of the attenuation peaks versus water saturation and frequency is similar to that of White's model. The conversion of primary P-wave energy into dissipating slow waves at the heterogeneities is shown to be the main mechanism for attenuating the primary wavefield. Fluid/gas patches are shown to affect attenuation more than equivalent patches in the permeability or solid-grain properties.     

Reply to Comment by Z. Şen,İ. Sönmez,and H. Tatli

Mathematical Geosciences -     

Estimating Ore Production in Open-pit Mines Using Various Machine Learning Algorithms Based on a Truck-Haulage System and Support of Internet of Things

Natural Resources Research - This study aimed to develop and assess the feasibility of different machine learning algorithms for predicting ore production in open-pit mines based on a truck-haulage...