Assessment of hormonal activity of UV filters in tadpoles of frog Xenopus laevis at environmental concentrations

Residues of UV filters used as ultraviolet absorbers in sunscreens, cosmetics and in light protection have been found in surface water and fish. Recently some of them were shown bearing estrogenic activity, however, very little is known about possible adverse effects to aquatic life. Here we investigate whether two UV filters, 4-methylbenzylidene camphor (4-MBC) and 3-benzylidene camphor (3-BC), interfere with the thyroid and sex hormone system during frog metamorphosis. Xenopus laevis tadpoles were exposed to 1, 5 and 50 μg/L of 4-MBC and 3-BC, respectively, for 35 days (NF stage 52–66). The rate of metamorphosis was not affected, and no obvious differences in body and tail length compared to controls were observed. Neither 4-MBC, nor 3-BC led to effects on the sex ratio or gross gonad morphology of X. laevis at stage 66. Our results indicate that these UV filters do not negatively affect the thyroid system and sex ratio of frogs at environmental concentrations.     

The Pfitsch-Mörchner Basin,an example of the post-Variscan sedimentary evolution in the Tauern Window (Eastern Alps)

A review of post-Variscan metasedimentary and metavolcanic successions in the western Tauern Window is presented. U/Pb – datations of zircons in metavolcanic rocks reveal ages between 309 and 280 Ma. Deposition of grey conglomerates and black pelites started before 309 Ma in the northernmost basin of the Tauern, the Riffler-Schönach basin. In the more central Pfitsch-Mörchner basin, the onset of conglomerate sedimentation can be dated into the time span between 293 and 280 Ma. The Pfitsch and Windtal Formations are newly defined. The basins were filled with up to 1 km of mainly continental clastics until Early Triassic. Short marine ingressions in Middle- and Late Triassic times flooded only basinal parts of the area where we suppose a more or less continuous sedimentation until the Late Jurassic. Only the Hochstegen Marble documents a nearly complete submergence in the area of the Tauern Window. In spite of the metamorphic overprint, the tentative interpretations of the sedimentary facies give a reasonable picture and allow correlations to nonmetamorphic areas in South Germany or the External Massifs of Eastern Switzerland.     

Natural and anthropogenic forcing of Holocene lake ecosystem development at Lake Uddelermeer (The Netherlands)

Lake Uddelermeer (The Netherlands) is characterized by turbid conditions and annual blooms of toxic cyanobacteria, which are supposed to be the result of increased agricultural activity in the twentieth century AD. We applied a combination of classic palaeoecological proxies and novel geochemical proxies to the Holocene sediment record of Lake Uddelermeer (The Netherlands) in order to reconstruct the natural variability of the lake ecosystem and to identify the drivers of the change to the turbid conditions that currently characterize this lake. We show that the lake ecosystem was characterized by a mix of aquatic macrophytes and abundant phytoplankton between 11,500 and 6000 cal year BP. A transition to a lake ecosystem with clear-water conditions and relatively high abundances of ‘isoetids’ coincides with the first signs of human impact on the landscape around Lake Uddelermeer during the Early Neolithic (ca. 6000 cal year BP). An abrupt and dramatic ecosystem shift can be seen at ca. 1030 cal year BP when increases in the abundance of algal microfossils and concentrations of sedimentary pigments indicate a transition to a turbid phytoplankton-dominated state. Finally, a strong increase in concentrations of plant and faecal biomarkers is observed around 1950 AD. Canonical Correspondence Analysis suggests that reconstructed lake ecosystem changes are best explained by environmental drivers that show long-term gradual changes (sediment age, water depth). These combined results document the long-term anthropogenic impact on the ecosystem of Lake Uddelermeer and provide evidence for pre-Industrial Era signs of eutrophication.     

Morphostratigraphy and provenance of Plio‐Pleistocene terraces in the south‐eastern Alpine foreland: the Mislinja and Upper Savinja valleys,northern Slovenia

This study focuses on the Plio‐Pleistocene fluvial deposits preserved in the terrace staircases in the south‐eastern Alpine foreland of the Mislinja (MV) and Upper Savinja valleys (USV) in northern Slovenia. The area is located at the north‐eastern margin of the Adria microplate, where neotectonic activity is the prevailing driving force for the terrace formation. The aim of this study is to determine the morphostratigraphy and provenance of the Pliocene to Early Pleistocene gravels using geomorphic and clast lithological analysis. The established morphostratigraphic framework encompasses three terraces in the MV and five terraces in the USV. Due to the lack of age‐relevant data, the morphostratigraphy of the MV and USV is based on the results of geomorphic analysis, clast petrography and data from the literature. Low‐level, middle‐level and high‐level terrace groups were tentatively attributed to the Late and Middle Pleistocene, Early Pleistocene–Pliocene and Pliocene, and compared with the traditional Quaternary stratigraphy of the Alpine foreland. The results of the clast lithological analysis revealed major provenance areas. Moreover, the evolution of long‐term drainage from the Miocene onward was inferred, which suggests that the system reached conformity with the present‐day drainage pattern at the Miocene to Plio‐Pleistocene transition. Copyright © 2019 John Wiley & Sons, Ltd.     

Palaeolimnology of Lake Sapanca and identification of historic earthquake signals,Northern Anatolian Fault Zone (Turkey)

Lake Sapanca is located on a strand of the Northern Anatolian Fault Zone (NAFZ, Turkey), where a series of strong earthquakes (Ms >6.0) have occurred over the past hundred years. Identifying prehistoric earthquakes in and around Lake Sapanca is key to a better understanding of plate movements along the NAFZ. This study contributes to the development of palaeolimnological tools to identify past earthquakes in Lake Sapanca. To this end several promising proxies were investigated, specifically lithology, magnetic susceptibility, grain size (thin-section and laser analysis), geochemistry, pollen concentration, diatom assemblages, ¹³⁷Cs and ²¹⁰Pb. Sedimentological indicators provided evidence for reworked, turbidite-like or homogeneous facies (event layers) in several short cores (<45 cm). Other indicators of sediment input and the historical chronicles available for the area suggest that three of these event layers likely originated from the AD 1957, 1967 and 1999 earthquakes. Recent changes in sediment deposition and nutrient levels have also been identified, but are probably not related to earthquakes. This study demonstrates that a combination of indicators can be used to recognize earthquake-related event layers in cores that encompass a longer period of time.     

A 40 ka record of temperature and permafrost conditions in northwestern Europe from noble gases in the Ledo‐Paniselian Aquifer (Belgium)

The Ledo‐Paniselian Aquifer in Belgium offers unique opportunities to study periglacial groundwater recharge during the Last Glacial Maximum (LGM), as it was located close to the southern boundary of the ice sheets at that time. Groundwater residence times determined by ¹⁴C and ⁴He reveal a sequence of Holocene and Pleistocene groundwaters and a gap between about 14 and 21 ka, indicating permafrost conditions which inhibited groundwater recharge. In this paper, a dataset of noble gas measurements is used to study the climatic evolution of the region. The derived recharge temperatures indicate that soil temperatures in the periods just before and after the recharge gap were only slightly above freezing, supporting the hypothesis that permafrost caused the recharge gap. The inferred glacial cooling of 9.5°C is the largest found so far by the noble gas method. Yet, compared to other palaeoclimate reconstructions for the region, recharge temperatures deduced from noble gases for the cold periods tend to be rather high. Most likely, this is due to soil temperatures being several degrees higher than air temperatures during periods with extended snow cover. Thus the noble‐gas‐derived glacial cooling of 9.5°C is only a lower limit of the maximum cooling during the LGM. Some samples younger than the recharge gap are affected by degassing, possibly related to gas production during recharge in part of the recharge area, especially during times of melting permafrost. The findings of this study, such as the occurrence of a recharge gap and degassing related to permafrost and its melting, are significant for groundwater dynamics and geochemistry in periglacial areas. Copyright © 2010 John Wiley & Sons, Ltd.