Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.     

Employment and Socio-spatial Relations in Australia's Cultural Economy

This paper examines the significance and contribution of Australian 'creative' industry activities in light of recent debates on the emergence of the 'cultural economy of cities'. First, census employment data and business location counts are used to illustrate patterns of metropolitan primacy and concentration in the cultural industries both across states and in Sydney. Second, the specificities of the locations of cultural production, and the links between cultural industry activities and wider urban-regional change are explored in more detail. A set of observations of urban-regional change is used to demonstrate how the notion of 'cultural economy' should include complex interactions between the material activities of consumers and producers, and the discursive worlds of image makers and place marketers. Urban renewal, housing market pressures and intra-regional migration all mediate Australian experiences of the 'cultural economy'. Such interactions, in addition to key quantitative data on employment and business activity, suggest important policy considerations.     

In situ tensile fracture toughness of surficial cohesive marine sediments

This study reports the first in situ measurements of tensile fracture toughness, K _IC, of soft, surficial, cohesive marine sediments. A newly developed probe continuously measures the stress required to cause tensile failure in sediments to depths of up to 1 m. Probe measurements are in agreement with standard laboratory methods of K _IC measurements in both potter’s clay and natural sediments. The data comprise in situ depth profiles from three field sites in Nova Scotia, Canada. Measured K _IC at two muddy sites (median grain size of 23–50 μm) range from near zero at the sediment surface to >1,800 Pa m^1/2 at 0.2 m depth. These profiles also appear to identify the bioturbated/mixed depth. K _IC for a sandy site (>90% sand) is an order of magnitude lower than for the muddy sediments, and reflects the lack of cohesion/adhesion. A comparison of K _IC, median grain size, and porosity in muddy sediments indicates that consolidation increases fracture strength, whereas inclusion of sand causes weakening; thus, sand-bearing layers can be easily identified in K _IC profiles. K _IC and vane-measured shear strength correlate strongly, which suggests that the vane measurements should perhaps be interpreted as shear fracture toughness, rather than shear strength. Comparison of in situ probe-measured values with K _IC of soils and gelatin shows that sediments have a K _IC range intermediate between denser compacted soils and softer, elastic gelatin.     

Seismic evaluation of an existing complex RC building

The seismic evaluation of existing buildings is a more difficult task than the seismic design of new buildings. Non-linear methods are needed if realistic results are to be obtained. However, the application to real complex structures of various evaluation procedures, which have usually been tested on highly idealized structural models, is by no means straightforward. In the paper, a practice-oriented procedure for the seismic evaluation of building structures, based on the N2 method, is presented, together with the application of this method to an existing multi-storey reinforced concrete building. This building, which is asymmetric in plan and irregular in elevation, consists of structural walls and frames. It was designed in 1962 for gravity loads and a minimum horizontal loading (2% of the total weight). The main results presented in terms of the global and local seismic demands are compared with the results of non-linear dynamic response-history analyses. As expected, the structure would fail if subjected to the design seismic action according to Eurocode 8. The shear capacity of the structural walls is the most critical. If the shear capacity of these elements was adequate, the structure would be able to survive the design ground motion according to Eurocode 8, in spite of the very low level of design horizontal forces. The applied approach proved to be a feasible tool for the seismic evaluation of complex structures. However, due to the large randomness and uncertainty which are involved in the determination of both the seismic demand and the seismic capacity, only rough estimates of the seismic behaviour of such structures can be obtained.     

Inertial oscillations near the coast of Nova Scotia during CASP

Abstract

Analysis of current, temperature and salinity records in the nearshore region of the Scotian Shelf during the Canadian Atlantic Storms Program (CASP), reveals that the inertial wave field is highly intermittent, with comparable amplitudes in the surface and deep layers. Clockwise current energy in the surface layer is concentrated at a frequency slightly below inertial, consistent with Doppler shifting by the strong mean current and/or straining by the mean flow shear, whereas the spectral peak in deep water is at the local inertial frequency. Clockwise coherence is high (γ² ≥ 0.8) horizontally over the scale of the array (60 km × 120 km) and in the vertical, with upward phase propagation rates of 0.15–0.50 × 10^?12 ms^?1, inversely proportional to the local value of the Brunt Väisälä frequency. Clockwise current energy decreases in the onshore direction and appears to be completely inhibited on the 60‐m isobath.

A case study of the response to the CASP IOP 14 storm indicates that the inertial waves may be generated by a strong wind shift propagating onshore at a speed of 10 ms^?1. On the eastern side of the array (Liscomb line), clockwise current oscillations propagate onshore in the surface layer at a rate (8.1 ± 0.9 m s^?1) comparable with the speed of the atmospheric front, while waves in the pycnocline move offshore at a lower (internal wave) speed (1.8 m s^?1). Furthermore the temperature and salinity fluctuations are in (out) of phase with longshore current in the deep (surface) layer. However, on the western side of the array (Halifax line), the inertial waves are more complex. A sharp steepening of phase lines at the coast indicates that the phase speed of clockwise current oscillations is considerably reduced and the evidence for offshore propagation of internal waves is less clear. The discrepancies between observations on the two lines suggest that the internal wave field is three‐dimensional.

Results of simple mixed‐layer models indicate that the inertial response near the surface is sensitive to the accurate definition of the local wind field, but not to certain model physics, such as the form of the decay term. The observations also show some qualitative similarities with models for two‐dimensional response to a moving front (e.g. Kundu, 1986), but the actual forcing terms are more complicated, based on IOP 14 wind measurements.     

Possible impact melt and debris flows at Tooting Crater, Mars

Candidate examples of impact melt flows and debris flows have been identified at Tooting crater, an extremely young (<2 Myr), 29 km diameter impact crater in Amazonis Planitia, Mars. Using HiRISE and CTX images, and stereo-derived digital elevation models derived from these images, we have studied the rim and interior wall of Tooting crater to document the morphology and topography of several flow features in order to constrain the potential flow formation mechanisms. Four flow types have been identified; including possible impact melt sheets and three types of debris flows. The flow features are all located within 2 km of the rim crest on the southern rim or lie on the southern interior wall of the crater ∼1500 m below the rim crest. Extensive structural failure has modified the northern half of the crater inner wall and we interpret this to have resulted in the destruction of any impact melt emplaced, as well as volatile-rich wall rock. The impact melt flows are fractured on the meter to decameter scale, have ridged, leveed lobes and flow fronts, and cover an area >6 km × 5 km on the southern rim. The debris flows are found on both the inner wall and rim of the crater, are ∼1-2 km in length, and vary from a few tens of meters to >300 m in width. These flows exhibit varying morphologies, from a channelized, leveed flow with arcuate ridges in the channel, to a rubbly flow with a central channel but no obvious levees. The flows indicate that water existed within the target rocks at the time of crater formation, and that both melt and fluidized sediment was generated during this event.     

Morphological relationships in the chromospheric Hα fine structure

A continuous relationship is proposed between the basic elements of the dark fine structure of the quiet and active chromosphere. A progression from chromospheric bushes to fibrils, then to chromospheric threads and active region filaments, and finally to diffuse quiescent filaments, is described. It is shown that the horizontal component of the field on opposite sides of an active region quiescent filament can be in the same direction and closely parallel to the filament axis. Consequently, it is unnecessary to postulate twisted or otherwise complex field configurations to reconcile the support mechanism of filaments with the observed motion along their axis.     

The effects of climate and landscape position on chemical denudation and mineral transformation in the Santa Catalina mountain critical zone observatory

Understanding the interactions of climate, physical erosion, chemical weathering and pedogenic processes is essential when considering the evolution of critical zone systems. Interactions among these components are particularly important to predicting how semiarid landscapes will respond to forecasted changes in precipitation and temperature under future climate change. The primary goal of this study was to understand how climate and landscape structure interact to control chemical denudation and mineral transformation across a range of semiarid ecosystems in southern Arizona. The research was conducted along the steep environmental gradient encompassed by the Santa Catalina Mountains Critical Zone Observatory (SCM-CZO). The gradient is dominated by granitic parent materials and spans significant range in both mean annual temperature (>10 °C) and precipitation (>50 cm a^?1), with concomitant shift in vegetation communities from desert scrub to mixed conifer forest. Regolith profiles were sampled from divergent and convergent landscape positions in five different ecosystems to quantify how climate-landscape position interactions control regolith development. Regolith development was quantified as depth to paralithic contact and degree of chemical weathering and mineral transformation using a combination of quantitative and semi-quantitative X-ray diffraction (XRD) analyses of bulk soils and specific particle size classes. Depth to paralithic contact was found to increase systematically with elevation for divergent positions at approximately 28 cm per 1000 m elevation, but varied inconsistently for convergent positions. The relative differences in depth between convergent and divergent landscape positions was greatest at the low and high elevation sites and is hypothesized to be a product of changes in physical erosion rates across the gradient. Quartz/Plagioclase (Q/P) ratios were used as a general proxy for bulk regolith chemical denudation. Q/P was generally higher in divergent landscape positions compared to the adjacent convergent hollows. Convergent landscape positions appear to be collecting solute-rich soil–waters from divergent positions thereby inhibiting chemical denudation. Clay mineral assemblage of the low elevation sites was dominated by smectite and partially dehydrated halloysite whereas vermiculite and kaolinite were predominant in the high elevation sites. The increased depth to paralithic contact, chemical denudation and mineral transformation are likely functions of greater water availability and increased primary productivity. Landscape position within a given ecosystem exerts strong control on chemical denudation as a result of the redistribution of water and solutes across the landscape surface. The combined data from this research demonstrates a strong interactive control of climate, landscape position and erosion on the development of soil and regolith.     

Resistivity of reservoir sandstones and organic rich shales on the Barents Shelf:Implications for interpreting CSEM data

Marine controlled source electromagnetic(CSEM)data have been utilized in the past decade during petroleum exploration of the Barents Shelf,particularly for de-risking the highly porous sandstone reservoirs of the Upper Triassic to Middle Jurassic Realgrunnen Subgroup.In this contribution we compare the resistivity response from CSEM data to resistivity from wireline logs in both water-and hydrocarbon-bearing wells.We show that there is a very good match between these types of data,particularly when reservoirs are shallow.CSEM data,however,only provide information on the subsurface resistivity.Careful,geology-driven interpretation of CSEM data is required to maximize the impact on exploration success.This is particularly important when quantifying the relative re-sistivity contribution of high-saturation hydrocarbon-bearing sandstone and that of the overlying cap rock.In the presented case the cap rock comprises predominantly organic rich Upper Jurassic-Early Cretaceous shales of the Hekkingen Formation(i.e.a regional source rock).The resistivity response of the reservoir and its cap rock become merged in CSEM data due to the transverse resistance equivalence principle.As a result of this,it is imperative to understand both the relative contributions from reservoir and cap rock,and the geological sig-nificance of any lateral resistivity variation in each of the units.In this contribution,we quantify the resistivity of organic rich mudstone,i.e.source rock,and reservoir sandstones,using 131 exploration boreholes from the Barents Shelf.The highest resistivity(＞10,000 Ωm)is evident in the hydrocarbon-bearing Realgrunnen Subgroup which is reported from 48 boreholes,43 of which are used for this study.Pay zone resistivity is primarily controlled by reservoir quality(i.e.porosity and shale fraction)and fluid phase(i.e.gas,oil and water saturation).In the investigated wells,the shale dominated Hekkingen Formation exhibits enhanced resistivity compared to the background(i.e.the underlying and overlying stratigraphy),though rarely exceeds 20Ωm.Marine mudstones typically show good correlation between measured organic richness and resistivity/sonic velocity log signatures.We conclude that the resistivity contribution to the CSEM response from hydrocarbon-bearing sandstones out-weighs that of the organic rich cap rocks.