Lead analysis of sediment cores from seven Connecticut lakes

Lead analyses were performed on sediment cores from seven Connecticut lakes by dilute acid leaching. The absolute concentrations of lead varied from core to core, but the lead profiles were similar in all of the cores, and each depicted a point where the concentration of lead sharply increased above background levels. The background lead concentrations observed in the bottom portions of the cores ranged from 12-54 g Pb/g sediment with a mean of 30 g Pb/g, and increased to a mean maximum of 310 g Pb/g. In six of the lakes significant increases above background levels were not noted until between 1924 and 1952, suggesting that, at least for Connecticut lakes, the point in a lake sediment core where the concentration of lead began to increase was after ca. 1924, and on average about 1930. Lead concentrations declined in the surface sediments of only three of the lakes, mostly since the 1980's, and presumably in response to the phasing out of leaded gasoline. However, significant declines in lead concentrations were not observed in the remaining cores, possibly due to increased motor vehicle use within the airshed of the lakes and/or changes in the export of lead to the lakes from their watersheds.     

Experimental determination of photostability and fluorescence‐based detection of PAHs on the Martian surface

Abstract– Even in the absence of any biosphere on Mars, organic molecules, including polycyclic aromatic hydrocarbons (PAHs), are expected on its surface due to delivery by comets and meteorites of extraterrestrial organics synthesized by astrochemistry, or perhaps in situ synthesis in ancient prebiotic chemistry. Any organic compounds exposed to the unfiltered solar ultraviolet spectrum or oxidizing surface conditions would have been readily destroyed, but discoverable caches of Martian organics may remain shielded in the subsurface or within surface rocks. We have studied the stability of three representative polycyclic aromatic hydrocarbons (PAHs) in a Mars chamber, emulating the ultraviolet spectrum of unfiltered sunlight under temperature and pressure conditions of the Martian surface. Fluorescence spectroscopy is used as a sensitive indicator of remaining PAH concentration for laboratory quantification of molecular degradation rates once exposed on the Martian surface. Fluorescence‐based instrumentation has also been proposed as an effective surveying method for prebiotic organics on the Martian surface. We find the representative PAHs, anthracene, pyrene, and perylene, to have persistence half‐lives once exposed on the Martian surface of between 25 and 60 h of noontime summer UV irradiation, as measured by fluorescence at their peak excitation wavelength. This equates to between 4 and 9.6 sols when the diurnal cycle of UV light intensity on the Martian surface is taken into account, giving a substantial window of opportunity for detection of organic fluorescence before photodegradation. This study thus supports the use of fluorescence‐based instrumentation for surveying recently exposed material (such as from cores or drill tailings) for native Martian organic molecules in rover missions.     

The palaeolimnology of Lake Fidler, a meromictic lake in south-west Tasmania and the significance of recent human impact

Three meromictic lakes in the World Heritage Area of south-west Tasmania possess unusual microbiological communities. Their meromixis is maintained by periodic incursions of brackish water from the nearby Gordon River which, in its lower reaches, is a salt-wedge estuary. In 1977 the construction of a dam in the middle reaches of the river restricted penetration of the salt-wedge and meromixis rapidly declined in all three lakes. A palaeolimnological study was carried out on one of the lakes, Lake Fidler, firstly to determine the history of meromixis and its associated microbiological communities, and secondly to assess whether the recent and rapid decline of meromixis is inconsistent with natural rates of development of the Gordon River meromictic lakes. One part of this study included the analysis of the stratigraphy of fossil diatoms from a 17-metre sediment core dating back 8000 yrs. Detrended Correspondence Analysis and Analog Matching were used to compare diatom species assemblages in core samples with diatom samples from a reference dataset consisting of a selection of lake and river sites in the lower Gordon River valley. Five distinct stratigraphic zones were identified in the core. These zones indicated specific stages in the development of the Gordon River lakes from river backwaters to ectogenically-maintained meromictic lakes which will, finally, become terrestrialised by encroaching rainforest. The onset of a stratified water column was identified by the emergence of a dominant freshwater algal flora which suggested that the lake had developed a mixolimnion and become meromictic ca. 2070 ± 50 ¹⁴C yrs ago. In the context of this long history of meromixis, the rapid demise in meromictic stability following construction of the dam is judged to be inconsistent with natural rates of development. The palaeolimnological studies, of which this paper is one part, prompt recommendations for a management strategy to prevent the further decay of these meromictic lakes in the World Heritage Area.     

Impact of the North Atlantic Oscillation on Middle Eastern Climate and Streamflow

Interannual to decadal variations in Middle Eastern temperature, precipitationand streamflow reflect the far-field influence of the North Atlantic Oscillation (NAO), a dominant mode of Atlantic sector climate variability. Using a new sea surface temperature (SST) based index of the NAO and availablestreamflow data from five Middle Eastern rivers, we show that the first principal component of December through March streamflow variability reflects changes in the NAO. However, Middle East rivers have two primary flooding periods.The first is rainfall-driven runoff from December through March, regulated on interannual to decadal timescales by the NAO as reflected in local precipitation and temperature.The second period, from April through June, reflects spring snowmelt and contributes in excess of 50% of annual runoff.This period, known locally as the khamsin, displays no significantNAO connections and a less direct relationship with local climatic factors, suggesting that streamflow variability during this period reflects land-cover change, possibly related to agriculture and hydropower generation, and snowmelt.     

Imaging buried Quaternary valleys using the transient electromagnetic method

Buried Quaternary valleys in Denmark are complex structures filled with various deposits consisting primarily of glacio-lacustrine clay, till and meltwater sand, and gravel. The valleys are important geophysical targets, because they often contain significant volumes of groundwater used for public water supply. About 700 km of buried valley structures have been imaged in the western part of Denmark by the transient electromagnetic (TEM) method. The ability to map the valleys depends primarily on valley geometry, infill architecture and the resistivity of the fill sediments as well as the substratum. One-dimensional (1-D) inversion models of the TEM soundings have been used to construct contour maps of 20 m average resistivities and depth to a good conductor, which provide images for geological interpretation. Images of buried valley morphology, fill properties, infill architecture, such as cut-and-fill structures, valley distribution and valley generations, are characterized for case studies from Hornsyld, Holstebro and the Vonsild/Agtrup areas of Denmark.     

Economic assessment of production of flour from Prosopis alba and P. pallida pods for human food applications.

This paper presents a detailed cost accounting of the processes involved in the production of flours from the mesocarps of the fruits of Prosopis alba and P. pallida to be used in human foods. The flours from both species are similar and contain 7–8% protein, 0·8–2% fat, 26–32% total dietary fiber and 48–59% sucrose. The data were based on actual production rates in use at the Universidad de Piura pilot plant using simple machinery. Machinery hourly charges were based on equivalent rental costs in order to avoid interest charge calculations. As opposed to other analyses which only included processing costs delivered to the plant, our analysis ascribed value to the owner of the trees in order to provide incentives to plant and care for the trees. The sensitivity analyses showed that the most economically important factor was the conversion efficiency of pods into flour. When a 40% conversion efficiency, such as that which has been obtained in both Peru and Argentina was obtained, and by-product credits for high fiber containing fraction were assumed, the wholesale selling price with a 5% marketing cost and a 40% profit direct costs was estimated to be $0·66 kg⁻¹ for Peru (using a $0·40 h⁻¹ labor rate ) and $1·76 kg⁻¹ for Argentina (using a $1·5 h⁻¹ labor rate).     

Landscape for change? International climate policy and energy transitions: evidence from sub-Saharan Africa

What is the role of the climate regime in facilitating rapid decarbonization of the world’s energy systems? We examine how core assumptions concerning the roles of the nation state, carbon markets and finance and technology in international climate policy are being challenged by the realities of how transitions in the energy systems are unfolding. Drawing on the critical region of sub-Saharan Africa, we examine the potential for international climate policy to foster new trajectories towards decarbonization.

Policy relevance

The international regime for climate policy has been in place for some twenty years. Despite significant changes in the landscape of energy systems and drivers of global GHG emissions over this time, the core principles and tools remain relatively stable – national governments, carbon markets, project-based climate finance and the transfer of technological hardware. Given the diversity of actors and drivers and the limited direct reach and influence of international climate policy, however, there is an urgent need to consider how the climate regime can best support the embryonic transitions that are slowly taking form around the world. To do this effectively requires a more nuanced understanding of the role of the state in governing these transitions beyond the notion of a cohesive state serving as rule-enforcer and transition manager. It also requires a broader view of technology, not just as hardware that is transferred, but as a set of practices and networks of expertise and enabling actors. Likewise, though markets have an important role to play as vehicles for achieving broader ends, they are not an end in themselves. Finally on finance, while acknowledging the important role of climate aid, often as a multiplier or facilitator of more ambitious private flows, it is critical to differentiate between the types of finance required for different transitions, many of which will not be counted under, or directed by, the climate regime. In sum, the (low-) carbon economy is being built in ways and in numerous sites that the climate regime needs to be cognizant of and engage with productively, and this may require fundamental reconsideration of the building blocks of the international climate regime.     

Emplacement mechanisms of the South Kona slide complex,Hawaii Island: sampling and observations by remotely operated vehicle Kaiko

Emplacement of a giant submarine slide complex, offshore of South Kona, Hawaii Island, was investigated in 2001 by visual observation and in-situ sampling on the bench scarp and a megablock, during two dives utilizing the Remotely Operated Vehicle (ROV) Kaiko and its mother ship R/V Kairei. Topography of the bench scarp and megablocks were defined in 3-D perspective, using high-resolution digital bathymetric data acquired during the cruise. Compositions of 34 rock samples provide constraints on the landslide source regions and emplacement mechanisms. The bench scarp consists mainly of highly fractured, vesiculated, and oxidized aa lavas that slumped from the subaerial flank of ancestral Mauna Loa. The megablock contains three units: block facies, matrix facies, and draped sediment. The block facies contains hyaloclastite interbedded with massive lava, which slid from the shallow submarine flank of ancestral Mauna Loa, as indicated by glassy groundmass of the hyaloclastite, low oxidation state, and low sulfur content. The matrix facies, which directly overlies the block facies and is similar to a lahar deposit, is thought to have been deposited from the water column immediately after the South Kona slide event. The draped sediment is a thin high-density turbidite layer that may be a distal facies of the Alika-2 debris-avalanche deposit; its composition overlaps with rocks from subaerial Mauna Loa. The deposits generated by the South Kona slide vary from debris avalanche deposit to turbidite. Spatial distribution of the deposits is consistent with deposits related to large landslides adjacent to other Hawaiian volcanoes and the Canary Islands.